Tag: 500-600

Structure of protic (HC_nImNTf₂, n = 0-12) and aprotic (C₁C_nImNTf₂, n = 1-12) imidazolium ionic liquids: A vibrational spectroscopic study was written by Moschovi, Anastasia Maria;Dracopoulos, Vassileios. And the article was included in Journal of Molecular Liquids in 2015.Recommanded Product: 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide This article mentions the following:

The interactions of alkyl substituted imidazolium bis(trifluoromethanesulfonyl)imide protic (PILs) HC_nImNTf₂ (n = 0-12) and aprotic ionic liquids (APILs) C₁C_nNTf₂ (n = 1-12) were studied using vibrational spectroscopy (FT-IR/ATR and FT-Raman). The effect of alkyl substituent length (n = 0-12) on both polar and non-polar regions is elucidated. A sponge like structure is proposed for both systems. The spectral characteristics show that there are certain structural differences between PILs and APILs. The well defined hydrogen bonding in PILs strongly affects the local structure of both the polar head (i.e., induction effect) and the side alkyl chain. The spectral findings tentatively suggest that nanosegregation occurs at shorter alkyl chains. In APILs the data correlated with the polar and non-polar regions are discussed on the basis of the proposed sponge like structure. The trans/cis ratio of the anion conformers is related to the dispersion of the average position of the anion over the cation. Also in the oily phase the local structure of the side chain shows certain differences compared to PIL systems. A tail coupling occurred (up to eight carbon atom alkyls) followed by decoupling in higher length tails in APILs indicating an increase of van der Waals forces between the chains. Moreover, we show that the enthalpy of conformational isomerism of the anion is also a good indicator in the case of APILs, regarding the relative magnitude of these interactions. In the experiment, the researchers used many compounds, for example, 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5Recommanded Product: 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide).

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Recommanded Product: 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Energetic Contributions from the Cation and Anion to the Stability of Carbon Dioxide Dissolved in Imidazolium-Based Ionic Liquids was written by Ishizuka, Ryosuke;Matubayasi, Nobuyuki;Tu, Kai-Min;Umebayashi, Yasuhiro. And the article was included in Journal of Physical Chemistry B in 2015.Application of 404001-48-5 This article mentions the following:

Cation and anion effects were investigated in the energetics of CO₂ solvation in room-temperature ionic liquids The solvation free energy in 1-n-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C₄mim][NTf₂]) was calculated with three types of force fields by mol. dynamics simulations combined with the energy-representation (ER) method, and the interaction responsible for the CO₂ stability was examined in terms of the average sum of the solute-solvent interaction energy and its electrostatic and van der Waals components. A key role of the van der Waals component was found for the cation contribution, and the electrostatic component was seen to be minor in the anion contribution. The solvation free energy of CO₂ was also investigated in 1-n-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C_nmim][NTf₂]) ionic liquids with n = 4, 6, 8, and 12 by the ER method. The free energy was found to depend weakly on n, in agreement with experiments, and the cation and anion contributions and the electrostatic and van der Waals interaction components acted similarly at all values of n examined The alkyl-chain length was found not to affect the local structure around CO₂ strongly, and its effect on the interaction energy with CO₂ appeared mainly through the bulk d. In the experiment, the researchers used many compounds, for example, 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5Application of 404001-48-5).

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Application of 404001-48-5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Environmental properties of phosphonium, imidazolium and ammonium cation-based ionic liquids as potential lubricant additives was written by Oulego, P.;Blanco, D.;Ramos, D.;Viesca, J. L.;Diaz, M.;Hernandez Battez, A.. And the article was included in Journal of Molecular Liquids in 2018.Application In Synthesis of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide This article mentions the following:

This research compares the environmental properties (bacterial toxicity and biodegradability) of 12 ionic liquids -ILs- (7 phosphonium, 2 imidazolium and 3 ammonium cation-based ones), potentially applicable as lubricant additive, with two types of the traditional lubricant additive ZDDP. Aquatic toxicity was determined by means of Vibrio fischeri and Escherichia coli bacteria, while biodegradability was evaluated through biol. oxygen demand (BOD₅) and COD (COD) measurements. Regarding toxicity results, [P₄₄₄₂][DEP] was the least toxic IL (acute 3 according to GHS) for both bacteria, whereas ZDDP fell into the acute 1 category (very toxic). All samples tested turned out to be poorly biodegradable, showing BOD₅/COD values below 0.1. Two ILs showed better combined tribol. and environmental properties than ZDDP. In the experiment, the researchers used many compounds, for example, 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5Application In Synthesis of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide).

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. Imidazole is a heterocyclic compound with a five-membered planar ring. It is amphoteric and highly polar. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Application In Synthesis of 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Polarisabilities of alkylimidazolium ionic liquids was written by Bica, Katharina;Deetlefs, Maggel;Schroeder, Christian;Seddon, Kenneth R.. And the article was included in Physical Chemistry Chemical Physics in 2013.Name: 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide This article mentions the following:

The molar polarizability and molar volume for 71 ionic liquids were extracted from 157 measurements of their refractive index and d., which were then further deconstructed into at. contributions by means of a Designed Regression anal. Using this approach, the d. and refractive index for any chosen ionic liquid with alkyl-substituted imidazolium cations can be predicted in good agreement with exptl. data. In the experiment, the researchers used many compounds, for example, 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5Name: 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide).

3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide (cas: 404001-48-5) belongs to imidazole derivatives. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has become an important synthon in the development of new drugs. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Name: 3-Dodecyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem