Category: 92507-97-6

Deng, Yuandan et al. published their research in Dalton Transactions in 2019 | CAS: 92507-97-6

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.Reference of 92507-97-6

Two low-dimensional metal halides: ionothermal synthesis, photoluminescence, and nonlinear optical properties was written by Deng, Yuandan;Dong, Xuehua;Yang, Meng;Zeng, Hongmei;Zou, Guohong;Lin, Zhien. And the article was included in Dalton Transactions in 2019.Reference of 92507-97-6 This article mentions the following:

Two new organic-inorganic hybrid metal halides, formulated as (C7H13N2)2MnCl4 (1) and (C6H11N2)PbBr3 (2), were prepared by a two-component ionothermal approach using multifunctional ionic liquids as solvents, charge-balancing agents, and halide sources. Compound 1 has an ionic zero-dimensional structure showing bright green luminescence with a high quantum yield of up to 70.78%. Compound 2 has a chain-like structure with a large second harmonic generation efficiency which is approx. 8脳 that of KH2PO4. In the experiment, the researchers used many compounds, for example, 1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6Reference of 92507-97-6).

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.Reference of 92507-97-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Garcia-Saiz, Abel et al. published their research in RSC Advances in 2015 | CAS: 92507-97-6

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. Imidazole is a heterocyclic compound with a five-membered planar ring. It is amphoteric and highly polar. This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Product Details of 92507-97-6

1-Ethyl-2,3-dimethylimidazolium paramagnetic ionic liquids with 3D magnetic ordering in its solid state: synthesis, structure and magneto-structural correlations was written by Garcia-Saiz, Abel;de Pedro, Imanol;Vallcorba, Oriol;Migowski, Pedro;Hernandez, Ignacio;Fernandez Barquin, Luis;Abrahams, Isaac;Motevalli, Majid;Dupont, Jairton;Gonzalez, Jesus Antonio;Fernandez, Jesus Rodriguez. And the article was included in RSC Advances in 2015.Product Details of 92507-97-6 This article mentions the following:

Two novel paramagnetic ionic liquids, comprised of a 1-ethyl-2,3-dimethylimidazolium (Edimim) cation and a tetrahaloferrate(III) (FeX4) (X = Cl and Br) anion were synthesized and characterized by thermal, structural, Raman spectroscopy and magnetic studies. The crystal structures, determined by synchrotron X-ray powder diffraction and single crystal X-ray diffraction at 100 K for Edimim[FeCl4] and Edimim[FeBr4] resp., are characterized by layers of cations (in non-planar configuration) and anions stacked upon one another in a three-dimensional (3D) manner with several non-covalent interactions: halide-halide, hydrogen bond and anion-蟺. Magnetization measurements show the presence of three-dimensional antiferromagnetic ordering below the N茅el temperature (TN) with the existence of a noticeable magneto-crystalline anisotropy in the bromide compound The corresponding magneto-structural correlations evidence that the 3D magnetic ordering mainly takes place via Fe-X路路路X-Fe (X = Cl and Br) interactions, displaying a higher superexchange magnetic interaction between the planes. Comparison with the Emim[FeX4] (X = Cl and Br) phases (Emim: 1-ethyl-3-methylimidazolium) reveals that the methylation at the C(2) position onto the imidazolium cation ring causes an increase of the m.p. and a decrease of the TN. In contrast, the comparative study with Dimim[FeX4] (X = Cl and Br) compounds (Dimim: 1,3-dimethylimidazolium) shows a lower TN in the chloride compound, Edimim[FeCl4], whereas it is higher for the bromide, Edimim[FeBr4]. This fact is attributed to the spin delocalization of iron atoms in [FeBr4]– and discards the hypothesis that a bigger imidazolium ion size causes a weaker magnetic coupling in paramagnetic ionic liquids based on tetrahaloferrate anions and imidazolium cations with 3D magnetic ordering in its solid state. In the experiment, the researchers used many compounds, for example, 1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6Product Details of 92507-97-6).

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. Imidazole is a heterocyclic compound with a five-membered planar ring. It is amphoteric and highly polar. This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Product Details of 92507-97-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Tay, Boonying et al. published their research in Industrial & Engineering Chemistry Research in 2021 | CAS: 92507-97-6

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Electric Literature of C7H13ClN2

Imidazolium-Catalyzed Formation of Bisphenol A Polycarbonate with a Reduced Level of Branching was written by Tay, Boonying;van Meurs, Martin;Tan, Jozel;Ye, Suming;Borgna, Armando;van Herk, Alexander M.;Selvaratnam, Selvasothi;Wang, Cun;Taniguchi, Shohei;Suzuki, Yousuke;Utsunomiya, Masaru;Ito, Mitsunobu;Monden, Toshiki;Shibata, Hiroki;Tomita, Shohei. And the article was included in Industrial & Engineering Chemistry Research in 2021.Electric Literature of C7H13ClN2 This article mentions the following:

The melt-phase polymerization of bisphenol A (BPA) and di-Ph carbonate (DPC) catalyzed by alk. metal catalysts produces polycarbonates with high branching, which impairs the product’s properties during weather resistance, ductility, and rheol. The use of an imidazolium-type catalyst can result in a reduced amount of branching relative to the benchmark Cs2CO3 catalyst. Modification of the imidazolium structure, especially by introducing a substitution at the C2 position, definitely improves the catalyst performance in enhancing the catalyst stability and reducing the branching level in the polycarbonate product. For the best catalyst identified (1,3-Ad2-2-Ph-Im-BPA), we have shown that at a DPC/BPA ratio of 1.075 and a catalyst loading of 7 ppm, the specifications can be met at the laboratory scale: polymerization time = 125 min, Mn = 11.0 K, OH = 660 ppm, branching = 460 ppm (鈭?5% reduction relative to the Cs2CO3 benchmark), and yellowness index = 6.3. In the experiment, the researchers used many compounds, for example, 1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6Electric Literature of C7H13ClN2).

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Electric Literature of C7H13ClN2

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Abdul-Sada, Ala’a et al. published their research in Structural Chemistry in 1990 | CAS: 92507-97-6

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Recommanded Product: 1-ethyl-2,3-dimethylimidazolium chloride

Upon the hydrogen-bonding ability of the H-4 and H-5 protons of the imidazolium cation was written by Abdul-Sada, Ala’a;Al-Juaid, Salih;Greenway, Anthony M.;Hitchcock, Peter B.;Howells, Matthew J.;Seddon, Kenneth R.;Welton, Thomas. And the article was included in Structural Chemistry in 1990.Recommanded Product: 1-ethyl-2,3-dimethylimidazolium chloride This article mentions the following:

The crystal and mol. structures of [Me2Etim]Cl, [Me2Etim]2[CoCl4], and [Me2Etim]2[NiCl4]([Me2Etim]+ = 1,2-dimethyl-3-ethylimidazolium cation) all contain evidence that the H4 and H5 protons of the imidzolium cation enter into hydrogen bonds; the implications of this observation for the interactions in room-temperature chloroaluminate(III) ionic liquids are considered. In the experiment, the researchers used many compounds, for example, 1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6Recommanded Product: 1-ethyl-2,3-dimethylimidazolium chloride).

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Recommanded Product: 1-ethyl-2,3-dimethylimidazolium chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Li, Wei et al. published their research in Chemical Physics Letters in 2012 | CAS: 92507-97-6

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3鈥揅6) is higher than in water and generally decreases with a This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Application In Synthesis of 1-ethyl-2,3-dimethylimidazolium chloride

A quantum mechanical study of alkylimidazolium halide ionic liquids was written by Li, Wei;Qi, Chuansong;Rong, Hua;Wu, Xinmin;Gong, Liangfa. And the article was included in Chemical Physics Letters in 2012.Application In Synthesis of 1-ethyl-2,3-dimethylimidazolium chloride This article mentions the following:

Thirty imidazolium (IM) halide compounds were studied using DFT methods (B3LYP, B3P86, and PBE1PBE1) methods. Geometry optimization and interaction energy calculations were performed using the B3LYP/6-311++G(d,p) method for ions composed of one alkylimidazolium cation and two or three halogen anions. The obtained structures were consistent with exptl. results. In addition, a linear correlation between m.ps. and interaction energies was obtained for the compounds studied, and this relationship was consistent with that obtained for amino acid cation based ionic liquids In the experiment, the researchers used many compounds, for example, 1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6Application In Synthesis of 1-ethyl-2,3-dimethylimidazolium chloride).

1-ethyl-2,3-dimethylimidazolium chloride (cas: 92507-97-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3鈥揅6) is higher than in water and generally decreases with a This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Application In Synthesis of 1-ethyl-2,3-dimethylimidazolium chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Continuously updated synthesis method about 92507-97-6

Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of 92507-97-6.

Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 92507-97-6, name is 1-ethyl-2,3-dimethylimidazolium chloride, This compound has unique chemical properties. The synthetic route is as follows., Application In Synthesis of 1-ethyl-2,3-dimethylimidazolium chloride

Example 181-Ethyl-2,3-dimethylimidazolium cyanodifluoropentafluoroethylborate-[C7H13N2][C2F5BF2(CN)] Potassium cyanodifluoropentafluoroethylborate K[C2F5BF2(CN)] (4.2 g, 18.0 mmol) is taken up in deionised water (2 ml), and a solution of 1-ethyl-2,3-dimethylimidazolium chloride [EDMIM]CI (3.2 g, 19.9 mmol) in 3 ml of deionised water is added. The ionic liquid obtained is washed with deionised water (4×2 ml), separated off and dried at 50 C. in vacuo. The yield of 1-ethyl-2,3-dimethylimidazolium cyanodifluoropentafluoroethylborate, which is liquid at room temperature, is 5.1 g (15.9 mmol), 88%, based on the potassium cyanodifluoropentafluoroethylborate K[C2F5BF2(CN)] employed. The product is analysed by means of ion chromatography and has low levels of contamination with halide; chloride: 7 ppm, bromide: 16 ppm, fluoride: 14 ppm. Water content (Karl Fischer titration): 161 ppm. Dynamic viscosity (20 C.): 47.2 mPa·s.Raman spectroscopy: v (CN)=2209 cm-1 1H-NMR: delta, ppm=7.60 d (CH, 1H), 3JH,H=2.15 Hz; 7.55 d (CH, 1H), 3JH,H=2.15 Hz; 4.32 q (CH2, 2H), 3JH,H=7.30 Hz; 3.90 s (CH3, 3H); 2.75 s (CH3, 3H); 1.46 t (CH3, 3H), 3JH,H=7.30 Hz.13C{1H}-NMR (cation): delta, ppm=145.32 s (Ctert, 1C); 123.30 s (CH, 1C); 121.19 s (CH, 1C); 44.20 s (CH2, 1C); 35.35 s (CH3, 1C); 15.07 s (CH3, 1C); 9.46 s (CH3, 1C).11B-NMR: delta, ppm=-2.7 tt (1B), 1JF,B=51.0 Hz, 2JF,B=25.3 Hz.19F-NMR: delta, ppm=-83.3 t (CF3, 3F), 4JF,F=5.2 Hz; -136.3 q (CF2, 2F), 2JF,B=23.3 Hz; -167.2 qq (BF2, 2F), 1JF,B=51.1 Hz, 4JF,F=5.1 HzElemental analysis: found, %, C, 37.57; H, 3.84; N, 13.10; calculated for C10H13BF7N3, %, C, 37.65; H, 4.11; N, 13.17.

Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of 92507-97-6.

Reference:
Patent; MERCK PATENT GESELLSCHAFT MIT BESCHRANKTER HAFTUNG; US2012/309981; (2012); A1;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Introduction of a new synthetic route about 1-ethyl-2,3-dimethylimidazolium chloride

At the same time, in my other blogs, there are other synthetic methods of this type of compound, 1-ethyl-2,3-dimethylimidazolium chloride, and friends who are interested can also refer to it.

Reference of 92507-97-6, As we all know, there are many different methods for the synthesis of a compound, and people can choose the synthesis method that suits their own laboratory according to the actual situation. 92507-97-6 name is 1-ethyl-2,3-dimethylimidazolium chloride, This compound is widely used in many fields, so it is necessary to find a new synthetic route. The downstream synthesis method of this compound is introduced below.

3. 1-ethyl-3-methyl-2-methylene imidazoline 5.96 g (37.12 mmol) 1-ethyl-2,3-dimethyl-imidazolium chloride and 2.98 g (74.24 mmol) KH are mixed in a 250 ml flask in a glove box. 100 ml THF is added to the solution, and this is stirred for 60 h at room temperature. The reaction mixture obtained is filtrated over celite, and all components which are volatile at room temperature are condensed from the solution. Subsequently, the product is distilled at 160 C./0.1 mbar in a Schlenk tube cooled with nitrogen. Yield: approx. 70% (colorless liquid extremely sensitive to humidity, which quickly colors yellow under partial decomposition at room temperature). 1H-NMR (C6D6, 200 MHz): delta=0.92 (t, 3H, NCH2CH3), 2.56 (s, 3H, NCH3), 2.65 (s, 2H, CCH2), 3.00 (q, 2H, NCH2CH3), 5.56 (d, 1H, EtNCH), 5.61 (d, 1H, MeNCH). 13C-NMR (C6D6, 50 MHz): delta=12.64 (NCH2CH3), 32.49 (CCH2), 39.82 (NCH3), 40.42 (NCH2CH3), 110.94 (EtNCH), 113.27 (MeNCH), 151.80 (NCN).

At the same time, in my other blogs, there are other synthetic methods of this type of compound, 1-ethyl-2,3-dimethylimidazolium chloride, and friends who are interested can also refer to it.