Category: 914306-50-6

C-N-Cyclometalated Platinum(II) Complexes with Sterically Demanding 1,2-Diarylimidazole Ligands was written by Micksch, Maik;Tenne, Mario;Strassner, Thomas. And the article was included in Organometallics in 2014.Reference of 914306-50-6 The following contents are mentioned in the article:

Authors describe the synthesis, characterization, and photophys. properties of 12 neutral cyclometalated platinum(II) complexes with sterically demanding 1,2-diarylimidazole ligands and β-diketonate ancillary ligands. All complexes are photophys. active emitting in the blue-green to red region (490-590 nm) of the spectrum with quantum yields up to 58%, measured in poly(Me methacrylate) (PMMA) at room temperature The steric demand of the imidazole ligand as well as of the β-diketonate ligand shows a significant effect on the quantum yield but not on the emission wavelength. These can be tuned by changing the substituents at the C-2 Ph group of the imidazole ligand. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6Reference of 914306-50-6).

1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Imidazole is a heterocyclic compound with a five-membered planar ring. It is amphoteric and highly polar. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Reference of 914306-50-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Synthesis of 1,2-diaryl- and 1-aryl-2-alkylimidazoles with sterically demanding substituents was written by Micksch, Maik;Tenne, Mario;Strassner, Thomas. And the article was included in European Journal of Organic Chemistry in 2013.Electric Literature of C21H24N2 The following contents are mentioned in the article:

1,2-Diarylimidazoles are an important class of compounds They are frequently used as ligands for photophys. active metal complexes and also display physiol. activity. We developed a new, high-yielding procedure for the synthesis of 1,2-diaryl-substituted imidazoles with sterically demanding substituents at the resp. ortho positions by starting from com. available anilines and benzoic acids through the corresponding acid chlorides. The metal-free method provides access to a variety of different substituents on the Ph rings at N-1 and C-2 as well as at the 4,5-positions of the imidazole backbone. Our new method is also suitable for the preparation of 1-aryl-2-alkylimidazoles. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6Electric Literature of C21H24N2).

1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Electric Literature of C21H24N2

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Cyclometalated 2-Phenylimidazole Palladium Carbene Complexes in the Catalytic Suzuki-Miyaura Cross-Coupling Reaction was written by Micksch, Maik;Tenne, Mario;Strassner, Thomas. And the article was included in Organometallics in 2014.Electric Literature of C21H24N2 The following contents are mentioned in the article:

We present the syntheses of cyclometalated palladium C-N 2-phenylimidazole carbene complexes with different N-1 groups as well as different substituents at the C-2 Ph group of the cyclometalating imidazole. We investigated the influence of these substituents by comparing the catalytic performance of the complexes in the Suzuki-Miyaura cross-coupling reaction of aryl chlorides. We can show a strong dependence between the steric demand of the N-1 substituent of the cyclometalating imidazole and the catalytic activity in the cross-coupling reaction. The most active complex shows a wide substrate scope, where several aryl as well as benzyl chlorides could be coupled with different boronic acids in excellent yields using very low catalyst concentrations of 0.05 mol %. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6Electric Literature of C21H24N2).

1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Electric Literature of C21H24N2

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Homoleptic tris-cyclometalated iridium(III) complexes with phenylimidazole ligands for highly efficient sky-blue OLEDs was written by Zhuang, Jinyong;Li, Wanfei;Wu, Weichen;Song, Minshun;Su, Wenming;Zhou, Ming;Cui, Zheng. And the article was included in New Journal of Chemistry in 2015.Application of 914306-50-6 The following contents are mentioned in the article:

As an extension of the authors’ previous study, three sky-blue homoleptic Ir(III) complexes 1-3 with F-free phenylimidazole ligands were synthesized and their photophys., electrochem. and thermal properties were studied. All the complexes showed high photoluminescence quantum yields ranging from 0.50 to 0.53. The introduction of a bulky iso-Pr group at the 2,6-position of N-Ph of the phenylimidazole ligands increases the quantum yield and the decomposition temperature of the IR(III) complexes. As the conjugated system of the ligand becomes larger, a very small bathochromic-shift of 1 nm was observed in complex 3 (475 nm) compared with complexes 1 (474 nm) and 2 (474 nm). All the OLED devices showed high current efficiencies of over 20 cd A^-1 at the luminance of 1000 cd m^-2. Devices incorporated with complexes 1-3 all showed longer lifetime in comparison with that of a FIrpic-based device. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6Application of 914306-50-6).

1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Application of 914306-50-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Synthesis of 1-(2,6-diisopropylphenyl)-2-phenyl-1H-imidazole was written by Zhou, Lin-bo;Lu, Meng-meng;Xing, Lei;Chen, Guo-liang. And the article was included in Jingxi Huagong Zhongjianti in 2015.Recommanded Product: 914306-50-6 The following contents are mentioned in the article:

The target compound 1-(2,6-diisopropylphenyl)-2-phenyl-1H-imidazole was prepared in overall yield of 47.69% starting from 2,6-diisopropyl aniline via acylation by benzoyl chloride, chlorination by phosphorus oxychloride, nucleophilic substitution by aminoacetaldehyde di-Et acetal and cyclization by phosphate. The structure of target compound was characterized by ¹H NMR and ESI-MS. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6Recommanded Product: 914306-50-6).

1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Recommanded Product: 914306-50-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films was written by Huckaba, Aron J.;Senes, Alessia;Aghazada, Sadig;Babaei, Azin;Meskers, Stefan C. J.;Zimmermann, Iwan;Schouwink, Pascal;Gasilova, Natalia;Janssen, Rene A. J.;Bolink, Henk J.;Nazeeruddin, Mohammad Khaja. And the article was included in ACS Omega in 2018.Product Details of 914306-50-6 The following contents are mentioned in the article:

The straightforward synthesis and photophys. properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by NMR, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)₃. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6Product Details of 914306-50-6).

1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has become an important synthon in the development of new drugs. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Product Details of 914306-50-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Synthesis of 1-(2,6-diisopropylphenyl)-2-phenyl-1H-imidazole was written by Zhou, Lin-bo;Lu, Meng-meng;Xing, Lei;Chen, Guo-liang. And the article was included in Jingxi Huagong Zhongjianti in 2015.Recommanded Product: 914306-50-6 The following contents are mentioned in the article:

The target compound 1-(2,6-diisopropylphenyl)-2-phenyl-1H-imidazole was prepared in overall yield of 47.69% starting from 2,6-diisopropyl aniline via acylation by benzoyl chloride, chlorination by phosphorus oxychloride, nucleophilic substitution by aminoacetaldehyde di-Et acetal and cyclization by phosphate. The structure of target compound was characterized by ¹H NMR and ESI-MS. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6Recommanded Product: 914306-50-6).

1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Recommanded Product: 914306-50-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films was written by Huckaba, Aron J.;Senes, Alessia;Aghazada, Sadig;Babaei, Azin;Meskers, Stefan C. J.;Zimmermann, Iwan;Schouwink, Pascal;Gasilova, Natalia;Janssen, Rene A. J.;Bolink, Henk J.;Nazeeruddin, Mohammad Khaja. And the article was included in ACS Omega in 2018.Product Details of 914306-50-6 The following contents are mentioned in the article:

The straightforward synthesis and photophys. properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by NMR, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)₃. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6Product Details of 914306-50-6).

1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has become an important synthon in the development of new drugs. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Product Details of 914306-50-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Cationic Ir(III) Complexes Featuring Phenylimidazole-type Cyclometalated Ligands: Fluorine-Free Blue Phosphorescent Emitters for Light-Emitting Devices was written by Song, Yongjun;Yu, Renyou;Chen, Mengzhen;He, Lei. And the article was included in Inorganic Chemistry in 2021.HPLC of Formula: 914306-50-6 The following contents are mentioned in the article:

The development of blue emissive cationic Ir(III) complexes with no F substitutions but with sufficient blue-color purity and high phosphorescence efficiency has remained challenging. Here, F-free cyan to deep-blue emissive cationic Ir(III) complexes with phenylimidazole type cyclometalated ligands (CN̂) are reported, which are [Ir(dphim)₂(dmapzpy)]PF₆ (1), [Ir(ipr-dphim)₂(dmapzpy)]PF₆ (2), [Ir(ipr-dphim)₂(bipz)]PF₆ (3), and [Ir(ipr-dphim)₂(bicb)]PF₆ (4). 1,2-diphenyl-1H-imidazole (dphim) and 1-(2,6-diisopropylphenyl)-2-phenyl-1H-imidazole (ipr-dphim) are the phenylimidazole type CN̂ ligands, and 4-dimethylamino-2-(1H-pyrazol-1-yl)pyridine (dmapzpy), di(1H-pyrazol-1-yl)methane (bipz), and 3,3′-methylenebis(1-Me-1H-imidazol-3-ium-2-ide) (bicb) are the neutral ancillary ligands (AÂ). In both solution and diluted films, 1 shows cyan emission with the emission maximum at ∼472 and 495 nm, and 2–4 provide deep-blue emission with the emission maximum at ∼460 and 480 nm. While the complexes exhibit low to moderate phosphorescent efficiencies (0.05-0.35) in degassed MeCN solution, they exhibit high phosphorescent efficiencies (≤0.82) in diluted films. Theor. calculations revealed that the mixed ³π-π^* (CN̂-centered)/³MLCT (Ir → CN̂) states are responsible for the emission afforded by 1–4, which undergo nonradiative deactivations induced by different types of metal-centered states. Organic light-emitting diodes (OLEDs) with 1–4 as phosphorescent dopants are fabricated by solution-process, which afford blue-green to blue emission with the emission maximum at ∼460 and 490 nm for the blue devices and a high current-efficiency at 28.1 cd A^-1 for the blue-green device. Solid-state light-emitting electrochem. cells (LECs) are fabricated with 1–2 as phosphorescent dopants, which provide green-blue to blue emission with high luminance (up to 840 cd m^-2) and current-efficiency (≤16.8 cd A^-1) under a constant-current driving. By using phenylimidazole type CN̂ ligands and optimized AÂ ligands, blue emissive cationic Ir(III) complexes with no F substitutions but with sufficient blue-color purity and high phosphorescence efficiency can be developed. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6HPLC of Formula: 914306-50-6).

1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.HPLC of Formula: 914306-50-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem