Category: 65039-05-6

Reference of 65039-05-6, In the chemical reaction process, reaction time, type of solvent, can easily affect the result of the reaction, thereby determining the yield and properties of the reaction product. An updated downstream synthesis route of 65039-05-6 as follows.

General procedure: 1-Butyl-3-methylimidazolidine, chloride salt (5 mmol), selenium (5 mmol), potassium carbonate (10 mmol), ethanol or acetone (5 mL) and a magnetic stirring bar were placed in a 50 mL, two-necked flask. Then the reaction mixture was vigorously stirred under reflux for the given times (see Table 2). After the reaction was complete, the resultant mixture was filtered, and the solvent evaporated under reduced pressure. Further purification by column chromatography on silica gel gave the pure product. All the products were characterised by NMR and HRMS.

According to the analysis of related databases, 65039-05-6, the application of this compound in the production field has become more and more popular.

Reference:
Article; Tian, Fengshou; Chen, Yahong; Wu, Lan; Li, Peng; Lu, Shiwei; Journal of Chemical Research; vol. 38; 6; (2014); p. 375 – 377;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Reference of 65039-05-6, The chemical industry reduces the impact on the environment during synthesis 65039-05-6, name is 1-Butyl-3-methylimidazolium iodide, I believe this compound will play a more active role in future production and life.

General procedure: Catholyte (0.10molL-1 of ionic liquid 1a-h in 5.0mL of organic solvent) and anolyte (2.0mL same solvent/electrolyte) were separated through a porous glass frit filled with methylcellulose in DMF-Et4N-BF4. The electrolysis was carried out, under N2 atmosphere at 25C, at a constant current (J=15mA·cm-2). After the consumption of 31C, the current was switched off, the anodic compartment removed and the catholyte analyzed by cyclic voltammetry at different time intervals from the end of the electrolysis

In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles, 1-Butyl-3-methylimidazolium iodide, other downstream synthetic routes, hurry up and to see.

Reference:
Article; Feroci, Marta; Chiarotto, Isabella; D’Anna, Francesca; Forte, Gianpiero; Noto, Renato; Inesi, Achille; Electrochimica Acta; vol. 153; (2015); p. 122 – 129;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Application of 65039-05-6, A common heterocyclic compound, 65039-05-6, name is 1-Butyl-3-methylimidazolium iodide, molecular formula is C8H15IN2, its traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route.

General procedure: The preparation of BiOI microspheres was carried out bysolvothermal synthesis. All reagents used were of analytical grade (AR) and used as received without additional purification. 1 mmolof bismuth nitrate pentahydrate [Bi(NO3)3.5H2O] (Sigma-Aldrich,99.0%) was dissolved in ethylene glycol (10 mL, Merck 99.5%) andpoured in a solution of 10 mL of ethylene glycol containing 1 mmolof KI (99.0% Merck). The mixture was stirred at room temperaturefor 30 min and then transferred to a 23 mL Teflon autoclave reactor.The autoclave was heated at 126 C (at autogenous pressure) for18 h andfinally cooled to room temperature. Thefinal productswere separated by vacuumfiltration and extensively washed usingdistilled water and absolute ethanol (Merck, 99.5% v/v). Thematerial obtained was dried at 60 C for 24 h. The same procedurewas used to synthesize BiOI using ionic liquid 1-butyl-3-methylimidazolium iodide ([bmim]I) as an iodide source.

The basis of chemical reaction formula synthesis, the synthesis route is composed of some specific reactions and combined according to certain logical thinking. We look forward to the emergence of more reaction modes in the future.

Reference:
Article; Mera, Adriana C.; Contreras, David; Escalona, Nestor; Mansilla, Hector D.; Journal of Photochemistry and Photobiology A: Chemistry; vol. 318; (2016); p. 71 – 76;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Researchers who often do experiments know that organic synthesis is a process of preparing more complex target molecules from simple raw materials through one or more chemical reactions. Generally, it requires fewer steps, and cheap raw materials. 65039-05-6, name is 1-Butyl-3-methylimidazolium iodide, A new synthetic method of this compound is introduced below., Safety of 1-Butyl-3-methylimidazolium iodide

(1) Take 10g of 98% purity by mass of 3-methyl-1-butyl iodide was added 25mL imidazole dissolved in distilled water, was added 50mL of 45% concentration of hydrofluoric acid, sealed and heated to 60oC with stirring;(2) reaction of starting material at least sufficient 3h, then heated to 100oC, excess hydrogen fluoride was evaporated and the product gas of hydrogen chloride gas, tail gas absorption using calcium oxide, not dehydrated to give 1-butyl-3-methylimidazolium ionic liquids fluoride ;(3) not dehydrated to 1-butyl-3-methyl-fluorinated ionic liquid was diluted with distilled water is added, not dehydrated butyl-3-methyl-fluorinated ionic liquid volume of distilled water is less than 1:50, dilution was added to the AgNO3 solution, if precipitation production, continue to add 20mL hydrofluoric acid, repeating (1) and (2) step until no precipitate was produced, purified non-dehydrated 1- butyl-3 – methyl fluoride ionic liquid;(4) The dehydrated purified non-3-methyl-1-butyl fluoride at 120oC ionic liquid was dried under high vacuum at least 48h, in addition to the depth of water, in addition to hydrogen fluoride, to give a viscous liquid, of a viscous liquid testing, viscous liquid was added to distilled water, distilled water and the volume of viscous liquid is less than 50, sealed and heated to 50oC, with hydrogen detector dilution residual amount of hydrogen fluoride, if the reading is greater than> 0.1ppm, continue at 120oC under high vacuum drying in addition to hydrogen fluoride untilInspection hydrogen fluoride concentration <0.1ppm; if detected hydrogen fluoride concentration <0.1ppm, the resulting liquid is 1-butyl-3-methyl fluoride ionic liquid, weighing 5.69g. The basis of chemical reaction formula synthesis, the synthesis route is composed of some specific reactions and combined according to certain logical thinking. We look forward to the emergence of more reaction modes in the future. Reference:
Patent; Beijing University; Li, Zhongning; Zhong, Xiongwei; Xiong, Ting; Hu, Xianwei; Xu, Junli; Wang, Zhaowen; Gao, Bingliang; Yu, Jiangyu; (27 pag.)CN103992275; (2016); B;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Adding a certain compound to certain chemical reactions, such as: 65039-05-6, name is 1-Butyl-3-methylimidazolium iodide, belongs to imidazoles-derivatives compound, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound 65039-05-6, Product Details of 65039-05-6

General procedure: 2.0mmol,0.5825gCo(NO3)2 6H2O and0.50mmol,0.0831gH2BDC wereplacedinacrystallisationvialplacedina25mLteflon-lined stainless-steelautoclavemixedwith1.005g[EMI]Cl.Themixturewaskeptinsidethe furnaceat160 C for5days,andthennaturallycooledtoambient temperature.Thebluecrystalsof 1 suitable forsinglecrystalX-raydiffractionwerecollectedaftersoakclearingwithacetone.

At the same time, in my other blogs, there are other synthetic methods of this type of compound, 1-Butyl-3-methylimidazolium iodide, and friends who are interested can also refer to it.

Reference:
Article; Zhang, Zong-Hui; Xu, Ling; Jiao, Huan; Journal of Solid State Chemistry; vol. 238; (2016); p. 217 – 222;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Adding a certain compound to certain chemical reactions, such as: 65039-05-6, name is 1-Butyl-3-methylimidazolium iodide, belongs to imidazoles-derivatives compound, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound 65039-05-6, Safety of 1-Butyl-3-methylimidazolium iodide

General procedure: Catholyte (0.10 mol L1 of ionic liquid 1a-h in 5.0 mL of organicsolvent) and anolyte (2.0 mL same solvent/electrolyte) wereseparated through a porous glass fritfilled with methylcellulosein DMF-Et4N-BF4. The electrolysis was carried out, under N2atmosphere at 25 C, at a constant current (J = 15 mA cm2). Afterthe consumption of 31 C, the current was switched off, the anodiccompartment removed and the catholyte analyzed by cyclicvoltammetry at different time intervals from the end of theelectrolysis.

If you are interested in these compounds, you can also browse my other articles.Thank you for taking the time to read this article. I hope you enjoyed it.

Reference:
Article; Feroci, Marta; Chiarotto, Isabella; D’Anna, Francesca; Forte, Gianpiero; Noto, Renato; Inesi, Achille; Electrochimica Acta; vol. 153; (2015); p. 122 – 129;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Some common heterocyclic compound, 65039-05-6, name is 1-Butyl-3-methylimidazolium iodide, molecular formula is C8H15IN2, traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route. Quality Control of 1-Butyl-3-methylimidazolium iodide

To a Schlenk flask charged with 1-butyl-3-methylimidazolium iodide (128.0mg, 0.48mmol) and Ag2O (56.0mg, 0.24mmol) was added dry CH2Cl2 (10mL), the mixture was protected from light and stirred at room temperature for 20h, before the resulting yellow solution was cannula filtered and added to a red solution of [(HMB)Ru(mu2-eta1,3-exo-syn-CH2CHCHCHO)]2(BF4)2 (200mg, 0.24mmol) in dry acetone (10mL). A solid immediately precipitated and the red suspension was stirred at room temperature protected from light for 4h, followed by filtration through a celite bed and washed with dry NO2CH3. The amber coloured solution was concentrated in vacuo to 5mL followed by addition of 20mL of dry diethyl ether and stored at-10C for 18h. The amber solution was taken to dryness resulting in a brown oil, washed with 10mL of pentane, vacuum dried and extracted with 10mL of dry toluene. Pentane (50mL) was added to the yellow toluene solution resulting in a yellow suspension which was stored at-10C for 20h, following by separation of an amber oil by decantation characterised as [(HMB)Ru(BuImMe)(eta3-CH2CHCHCOOH)](BF4) in very low yield just enough for NMR experiments. 1H NMR (CDCl3, 500MHz, ppm): 6.96 (2×d, J=1.8Hz, 1H, 4,5-Im), 4.47 (dt, J=6.7, 0.7Hz, 1H, H3-heteropentadienyl), 4.11 (m, 3H, overlap CH2-N-Im and H2-heteropentadienyl), 3.84 (s, 3H, CH3-N-Im), 3.09 (ddd, J=7.2, 1.5, 0.8Hz, 1H, H1syn-heteropentadienyl), 2.17 (s, 18H, HMB), 1.87 (dt, J=10.8, 1.1Hz, 1H, H1anti-heteropentadienyl), 1.79 (q, J=7.5Hz, 2H, CH2-CH2-N-Im), 1.34 (q, J=7.6Hz, 2H, CH2-CH2-CH2-N-Im), 0.95 (t, J=7.4Hz, 3H, CH3-(CH2)3-N-Im). 13C{1H} NMR (acetone-d6, 75MHz, ppm): 182.0 (C-Ru), 122.0 and 120.9 (C4,C5-Im), 96.0 (HMB), 92.5 (C2-heteropentadienyl), 65.7 (C3-heteropentadienyl), 52.8 (C1-heteropentadienyl), 51.7 (CH2-N-Im), 38.8 (CH2-CH2-N-Im), 33.6 (CH3-N-Im), 19.8 (CH2-CH2-CH2-N-Im), 16.4 (CH3-HMB), 13.7 (CH3-(CH2)3-N-Im). ESI-TOF-MS(+) (m/z): Calcd for [C24H37N2O2Ru]+ 487.189302, found 487.189566; error-0.540454ppm, DBE 7.5.

These compound has a wide range of applications. It is believed that with the continuous development of the source of the synthetic route 65039-05-6, its application will become more common.

Reference:
Article; Olguin, Juan; Diaz-Fernandez, Monica; de la Cruz-Cruz, Jose Ignacio; Paz-Sandoval, M. Angeles; Journal of Organometallic Chemistry; vol. 824; (2016); p. 33 – 41;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

In the chemical reaction process, reaction time, type of solvent, can easily affect the result of the reaction, thereby determining the yield and properties of the reaction product. An updated downstream synthesis route of 65039-05-6 as follows. category: imidazoles-derivatives

Add to a 100 mL round bottom flaskGlyphosate 1.69g (10mmol),Methanol (40 mL) and potassium hydroxide 0.62 g (11 mmol),Magnetic stirring at 50C,After the reaction solution is clarified,1-butyl-3-methylimidazolium iodide 2.66 g (10 mmol) was added,The reaction was stirred at room temperature for 0.75 hours.Dichloromethane (3 x 20 mL) was added for extraction.After the extraction is completed,The organic phase is washed once with saturated saline solution.Distilled and washed onceRotary evaporation,And dried in a vacuum drying oven to give a yellow oily liquid,Yield 90%.

According to the analysis of related databases, 65039-05-6, the application of this compound in the production field has become more and more popular.

Reference:
Patent; Zhejiang Academy Of Agricultural Sciences; Yu Jianzhong; He Hongmei; Zhang Changpeng; Xu Zhenlan; Wu Min; Zhang Chunrong; He Kaiyu; Zhu Yahong; Yu Ruixian; Zhao Hua; (8 pag.)CN107987104; (2018); A;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 65039-05-6, name is 1-Butyl-3-methylimidazolium iodide, This compound has unique chemical properties. The synthetic route is as follows., Product Details of 65039-05-6

General procedure: In a 50-mL, two-necked flask, 1-butyl-3-methylimidazolium chloride (5 mmol), selenium (5 mmol), Na2CO3 (10 mmol), H2O (5 mL), and a magnetic stirring bar were placed. Then, the reaction mixture was vigorous stirring under refluxing condition for 4 h. After the reaction was complete, and the resultant mixture was filtered, and the solvent evaporated under reduced pressure. Further purification by recrystallization or column chromatography on silica gel gave the pure product. All the products were characterized by NMR and HRMS. Detailed characterization of the previously known compounds from Table 2 arepresented in the Supplemental Materials.

Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of 65039-05-6.

Reference:
Article; Tian, Fengshou; Chen, Yahong; Li, Peng; Lu, Shiwei; Phosphorus, Sulfur and Silicon and the Related Elements; vol. 189; 9; (2014); p. 1391 – 1395;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 65039-05-6, name is 1-Butyl-3-methylimidazolium iodide, This compound has unique chemical properties. The synthetic route is as follows., Formula: C8H15IN2

To a stirred solution of 1-alkyl-3-methylimidazolium iodides (1 mmol) in H2O (10 ml) was added slowly a solution of AgF (1 mmol) in H2O (10 ml). After stirring at room temperature for 2 h, the mixture was filtrated and the water was evaporated under reduced pressure at room temperature. The crude residue was dissolved in anhydrous methanol. The subsequent filtration and the evaporation of the solvent under reduced pressure to give the corresponding product in quantitative yields.

According to the analysis of related databases, 65039-05-6, the application of this compound in the production field has become more and more popular.

Reference:
Article; Zhu, Zhi-Qiang; Jiang, Ming-Yue; Zheng, Chang-Ge; Xiao, Ji-Chang; Journal of Fluorine Chemistry; vol. 133; (2012); p. 160 – 162;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem