Category: 616-47-7

The author of 《Facile synthesis of nanostructured polyaniline in ionic liquids for high solubility and enhanced electrochemical properties》 were Li, Shihua; Yang, Chunying; Sarwar, Shatila; Nautiyal, Amit; Zhang, Pengfei; Du, Haishun; Liu, Na; Yin, Jialin; Deng, Kuilin; Zhang, Xinyu. And the article was published in Advanced Composites and Hybrid Materials in 2019. Recommanded Product: 616-47-7 The author mentioned the following in the article:

As one of the most investigated conducting polymers, polyaniline (PANI) is considered to be of practical use in many applications. In this study, two new ionic liquids, 1-methylimidazolium hydrogen sulfate ([Hmim]HSO4) and 1-methyl-3-n-butylimidazopersulfate ([C4mim]2S2O8), which were synthesized from 1-methylimidazole ([Hmim]), were used as solvent and dopant, oxidizer, resp., for in situ polymerization of aniline. Because of the application of the unique structure of ionic liquid, we obtained the ionic liquid-doped polyaniline (IL-PANI) with high solubility (25 mg mL-1 in DMSO (DMSO)). And by adjusting the ratio of [C4mim]2S2O8 to aniline monomer, the preferred PANI nanofibers could be controlled to form a three-dimensional porous structure. It was found that the ion/electron transport channels could be formed inside the 3D structure. Thus, the redox reactions could occur both at the surface and inside the PANI electrode. Electrochem. characterization showed that the fabricated PANI electrode exhibited a specific capacitance of 489 F g-1 at a c.d. of 0.5 A g-1. Also, the capacity retention rate reached up to 81% after 4000 cycles investigated at 2 A g-1. In addition, a high-energy d. of 80.2 Wh kg-1 was measured when [Hmim]HSO4 was used as an electrolyte. Thus, the present work suggested a new strategy for fabricating high-performance PANI electrode for supercapacitor applications. [Figure not available: see fulltext.]. The results came from multiple reactions, including the reaction of 1-Methyl-1H-imidazole(cas: 616-47-7Recommanded Product: 616-47-7)

1-Methyl-1H-imidazole(cas: 616-47-7) is used as a precursor for the synthesis of pyrrole-imidazole polyamides, ionic liquids such as 1-butyl-3-methylimidazolium hexafluorophosphate.Recommanded Product: 616-47-7

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

In 2022,Jacobi, Richard; Joerg, Florian; Steinhauser, Othmar; Schroeder, Christian published an article in Physical Chemistry Chemical Physics. The title of the article was 《Emulating proton transfer reactions in the pseudo-protic ionic liquid 1-methylimidazolium acetate》.Product Details of 616-47-7 The author mentioned the following in the article:

Proton transfer reactions can enhance conductivity in protic ionic liquids However, several proton reactions are possible in a multicomponent system of charged and neutral species, resulting in a complex reaction network. Probabilities and equilibrium concentrations of the involved species are modeled by the combination of reducible Markov chains and quantum-mech. calculations The experimental part of the paper was very detailed, including the reaction process of 1-Methyl-1H-imidazole(cas: 616-47-7Product Details of 616-47-7)

1-Methyl-1H-imidazole(cas: 616-47-7) is used as a precursor for the synthesis of pyrrole-imidazole polyamides, ionic liquids such as 1-butyl-3-methylimidazolium hexafluorophosphate.Product Details of 616-47-7

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

In 2019,Fuel Processing Technology included an article by Andevary, Hojatollah Haji; Akbari, Azam; Omidkhah, Mohammadreza. Product Details of 616-47-7. The article was titled 《High efficient and selective oxidative desulfurization of diesel fuel using dual-function [Omim]FeCl4 as catalyst/extractant》. The information in the text is summarized as follows:

Lewis acidic ionic liquid (IL) of 1-octyl-3-methylimidazolium tetrachloroferrates ([Omim]FeCl4) with an interesting structure, was synthesized and introduced as a highly effective catalyst and also as extractive solvent in oxidative desulfurization (ODS) of model and real diesel fuels with H2O2 oxidant. FT-IR, H-NMR and TG-DSC anal. were used for characterization of the prepared ILs. GC-FID, GC-PFPD and GC-MS measurements were also employed to investigate the ODS yields and mechanism. The adequate structure and acidic properties of [Omim]FeCl4 allowed removal of thiophenic compounds with high efficiency in an extraction and then oxidation process. The effects of the major processing variables on ODS performance of [Omim]FeCl4 were studied in detail. At the optimal conditions of VIL/Voil of 1/10, O/S molar ratio of 5, reaction time of 15 min and room temperature, BT and DBT were totally eliminated, and 4,6-DMDBT was removed by 99% from the model diesel. Moreover, [Omim]FeCl4 was able to desulfurize two real diesel fuels containing 590 and 2573 ppmw of sulfur with the efficiency of 85% and 61.2%, resp., at a short time of 15 min. The exptl. results also showed a remarkable selectivity of 0.919 for elimination of thiophenic compounds in competition with non-sulfur aromatic model of 2-Me naphthalene. [Omim]FeCl4 exhibited an excellent recyclability with no significant decline in activity after use in 7 reaction cycles. An overall mechanism was also suggested for desulfurization by the proposed system. In the experimental materials used by the author, we found 1-Methyl-1H-imidazole(cas: 616-47-7Product Details of 616-47-7)

1-Methyl-1H-imidazole(cas: 616-47-7) is actively involved in removing acid during the production of diethoxyphenylphosphine. It is used as an intermediate in organic synthesis.Product Details of 616-47-7

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

《Dual-Mode Fluorescence and Magnetic Resonance Imaging by Perylene Diimide-Based Gd-Containing Magnetic Ionic Liquids》 was written by Yu, Xiaoliang; Yuan, Xiaoyan; Huang, Zitan; Zhang, Wenyu; Huang, Fan; Ren, Lixia. Application of 616-47-7 And the article was included in ACS Biomaterials Science & Engineering in 2020. The article conveys some information:

Bioimaging plays a key role in the diagnosis/treatment of diseases and in scientific research studies. Compared with single imaging techniques, dual-mode and multimode imaging techniques facilitate high accuracy. In this work, a perylene diimide (PDI)-based Gd-containing magnetic ionic liquid, Per-6-Diimi[Gd(NO3)4], is reported for dual-modal imaging, in which a Gd(III) complex was used for magnetic resonance imaging (MRI), while PDI was used for fluorescence imaging. Because of the difference in the biol. microenvironment, there is a switch between dispersed and aggregated states of Per-6-Diimi[Gd(NO3)4] mols. in hydrophobic and hydrophilic media. When it was in the aqueous solution, the intensive π-π interaction of PDI cores made Per-6-Diimi[Gd(NO3)4] aggregates to form particles. The paramagnetic nanoparticles ensure prolonging the rotational correlation time, which results in a strong enhancement of MRI with a longitude relaxation coefficient of 14.94 mM-1 s-1. In an in vivo MRI experiment, the tumor site is imaged by MRI through the enhanced permeability and retention effect. However, when the mol. is present on the hydrophobic membrane of the cells, the dispersed Per-6-Diimi[Gd(NO3)4] showed good fluorescence imaging capabilities due to the high fluorescence quantum yield of PDI. Thus, the fluorescence imaging of cells can be carried out. Moreover, ex vivo fluorescence imaging of organs is performed after MRI. Per-6-Diimi[Gd(NO3)4] is enriched in the liver, kidneys, and tumors. The results came from multiple reactions, including the reaction of 1-Methyl-1H-imidazole(cas: 616-47-7Application of 616-47-7)

1-Methyl-1H-imidazole(cas: 616-47-7) is actively involved in removing acid during the production of diethoxyphenylphosphine. It is used as an intermediate in organic synthesis.Application of 616-47-7

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

《Physicochemical properties of ether-functionalized ionic liquids [CnOC2mim][Gly] (n = 1-5)》 was written by Zhang, Duo; Zhang, Shan-Shan; Hong, Mei; Yu, Ke; Tong, Jing. HPLC of Formula: 616-47-7 And the article was included in Journal of Thermal Analysis and Calorimetry in 2020. The article conveys some information:

A review. Abstract: A novel ionic liquid 1-ethoxyethyl-3-methylimidazolium glycine ([C2OC2mim][Gly]) was prepared and characterized by 1H NMR spectroscopy, 13C NMR spectroscopy, elemental anal. and thermogravimetric anal. The d., surface tension and refractive index of [C2OC2mim][Gly] were measured in T = (288.15-328.15) K using the standard addition method. Based on exptl. data, physicochem. properties molar volume, parachor, surface tension, the molar surface Gibbs energy, the molar vaporization enthalpy, thermal expansion coefficients, molar refraction and refractive index of the homologues [CnOC2mim][Gly] (n = 1-5) were predicted using semiempirical methods. The predicted values were in good agreement within an order of magnitude with the exptl. ones. Graphic Abstract: [Figure not available: see fulltext.].1-Methyl-1H-imidazole(cas: 616-47-7HPLC of Formula: 616-47-7) was used in this study.

1-Methyl-1H-imidazole(cas: 616-47-7) is actively involved in removing acid during the production of diethoxyphenylphosphine. It is used as an intermediate in organic synthesis.HPLC of Formula: 616-47-7

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

《Enhanced Menshutkin SN2 Reactivity in Mesoporous Silica: The Influence of Surface Catalysis and Confinement》 was written by Zheng, Weizhong; Yamada, Steven A.; Hung, Samantha T.; Sun, Weizhen; Zhao, Ling; Fayer, Michael D.. HPLC of Formula: 616-47-7 And the article was included in Journal of the American Chemical Society in 2020. The article conveys some information:

A significant enhancement in the Menshutkin SN2 reaction between 1-methylimidazole (MeIm) and Me thiocyanate (MeSCN) is observed when the reaction is confined in the nanoscale silica pores of MCM41 and SBA15. The experiments in the silica pores are conducted without the surrounding bulk reaction mixture The influences of temperature, pore radius, and surface chem. on the kinetics of the confined reaction are analyzed with time-dependent IR spectroscopy, mol. dynamics simulations, and ab initio calculations The rate constant of the pseudo-first order reaction increases with decreasing pore size, and the activation energy is found to decrease by 5.6 kJ/mol in the smallest pore studied (2.8 nm) relative to the bulk reaction. The rate constant dependence on pore size is accurately described by a two-state model in which mols. within the 4.6 Å interfacial layer experience a 2.4-fold rate constant increase relative to those reacting at the bulk rate further away from the interface. The removal of polar silanol groups from the silica surface via passivation with trimethylsilyl chloride results in bulk-like kinetics despite a reduction in the pore diameter, demonstrating the role of silanols as catalytic sites. Electronic structure calculations of the energy profile on a model silica surface confirm that silanol groups, particularly those of the vicinal type, can reduce the activation energy and reaction endothermicity through the donation of hydrogen bonds to the reactant, transition state, and product complexes. In the experiment, the researchers used 1-Methyl-1H-imidazole(cas: 616-47-7HPLC of Formula: 616-47-7)

1-Methyl-1H-imidazole(cas: 616-47-7) is actively involved in removing acid during the production of diethoxyphenylphosphine. It is used as an intermediate in organic synthesis.HPLC of Formula: 616-47-7

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

《Enhancing the Recyclability of a Vegetable Oil-Based Epoxy Thermoset through Initiator Influence》 was written by di Mauro, Chiara; Tran, Thi-Nguyet; Graillot, Alain; Mija, Alice. Synthetic Route of C4H6N2 And the article was included in ACS Sustainable Chemistry & Engineering in 2020. The article conveys some information:

Bisphenol A based epoxy thermosets involve both environmental and health risks. By reacting a vegetal oil-based epoxide with an aromatic diacid containing S-S bonds a thermoset is produced. Herein, reprocessable thermosets were synthesized, the recyclability being designed through a dual mechanism: that of disulfide metathesis and of transesterifications. To assess the feasibility of the reprocessing, a series of ten initiators were tested to probe their effect not only on the crosslinking reaction but also on the recyclability. This study introduces for the first time the key role of the initiator on the material performances and on their reprocessing. A very good reprocessability was obtained for thermosets prepared using as initiator the imidazole. Moreover, the thermosets exhibit complete chem. recyclability in 1N NaOH at 80°C, after 3 days, without needing addnl. chems. The reprocessed materials have similar performances with the virgin ones, even after 10 cycles of reprocessing. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazole(cas: 616-47-7Synthetic Route of C4H6N2)

1-Methyl-1H-imidazole(cas: 616-47-7) is actively involved in removing acid during the production of diethoxyphenylphosphine. It is used as an intermediate in organic synthesis.Synthetic Route of C4H6N2

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

《Effect of alkyl chain on micellization properties of dodecylbenzenesulfonate based surface active ionic liquids using conductance, surface tension, and spectroscopic techniques》 was published in Journal of Dispersion Science and Technology in 2020. These research results belong to Pal, Amalendu; Saini, Mohit. Electric Literature of C4H6N2 The article mentions the following:

Two surface active ionic liquids (ILs) having 1-alkyl-3-methylimidazolium cationic moiety and dodecylbenzenesulfonate based anionic moiety i.e. [C5mim][DBS] and [C7mim][DBS], have been synthesized. 1H-NMR, thin layer chromatog. were done for their characterization. These DBS-ILs have lower critical micelle concentration (CMC) in comparison with their conventional sodium dodecylbenzenesulfonate [Na][DBS] surfactants and hence are highly surface active. The conductance, surface tension, absorption (UV-visible) and emission (Fluorescence) techniques were used to determine the CMC values. DBS-ILs showed a remarkable absorption and emission spectra where intensity changes with variation in concentration of IL. Micelle self-assembly formation was also predicted by dynamic light scattering (DLS) technique. Conductance and surface tension techniques were employed to study the aggregation behavior in aqueous conditions. Various surface active parameters were evaluated at 298.15 K employing surface tension techniques. Conductance measurements were performed at three rising temperatures (288.15, 298.15, and 308.15) K and their thermodn. parameters were calculated From the above studies, the present synthesized ionic liquids found to have remarkable surface activity. After reading the article, we found that the author used 1-Methyl-1H-imidazole(cas: 616-47-7Electric Literature of C4H6N2)

1-Methyl-1H-imidazole(cas: 616-47-7) is actively involved in removing acid during the production of diethoxyphenylphosphine. It is used as an intermediate in organic synthesis.Electric Literature of C4H6N2

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Synthetic Route of C4H6N2In 2022 ,《Revealing the Organization of Catalytic Sequence-Defined Oligomers via Combined Molecular Dynamics Simulations and Network Analysis》 appeared in Journal of Chemical Information and Modeling. The author of the article were Kardas, Sinan; Fossepre, Mathieu; Lemaur, Vincent; Fernandes, Antony E.; Glinel, Karine; Jonas, Alain M.; Surin, Mathieu. The article conveys some information:

Similar to biol. macromols. such as DNA and proteins, the precise control over the monomer position in sequence-defined polymers is of paramount importance for tuning their structures and properties toward achieving specific functions. Here, we apply mol. network anal. on three-dimensional structures issued from mol. dynamics simulations to decipher how the chain organization of trifunctional catalytic oligomers is influenced by the oligomer sequence and the length of oligo(ethylene oxide) spacers. Our findings demonstrate that the tuning of their primary structures is crucial for favoring cooperative interactions between the catalytic units and thus higher catalytic activities. This combined approach can assist in establishing structure-property relationships, leading to a more rational design of sequence-defined catalytic oligomers via computational chem. In the part of experimental materials, we found many familiar compounds, such as 1-Methyl-1H-imidazole(cas: 616-47-7Synthetic Route of C4H6N2)

1-Methyl-1H-imidazole(cas: 616-47-7) is used as a precursor for the synthesis of pyrrole-imidazole polyamides, ionic liquids such as 1-butyl-3-methylimidazolium hexafluorophosphate.Synthetic Route of C4H6N2

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

《Biological evaluation of novel thiomaltol-based organometallic complexes as topoisomerase IIα inhibitors》 was published in JBIC, Journal of Biological Inorganic Chemistry in 2020. These research results belong to Legina, Maria S.; Nogueira, Juan J.; Kandioller, Wolfgang; Jakupec, Michael A.; Gonzalez, Leticia; Keppler, Bernhard K.. HPLC of Formula: 616-47-7 The article mentions the following:

Abstract: Topoisomerase IIα (topo2α) is an essential nuclear enzyme involved in DNA replication, transcription, recombination, chromosome condensation, and highly expressed in many tumors. Thus, topo2α-targeting has become a very efficient and well-established anticancer strategy. Herein, we investigate the cytotoxic and DNA-damaging activity of thiomaltol-containing ruthenium-, osmium-, rhodium- and iridium-based organometallic complexes in human mammary carcinoma cell lines by means of several biol. assays, including knockdown of topo2α expression levels by RNA interference. Results suggest that inhibition of topo2α is a key process in the cytotoxic mechanism for some of the compounds, whereas direct induction of DNA double-strand breaks or other DNA damage is mostly rather minor. In addition, mol. modeling studies performed for two of the compounds (with Ru(II) as the metal center) evinces that these complexes are able to access the DNA-binding pocket of the enzyme, where the hydrophilic environment favors the interaction with highly polar complexes. These findings substantiate the potential of these compounds for application as antitumor metallopharmaceuticals. Graphic abstract: [graphic not available: see fulltext] In the experiment, the researchers used 1-Methyl-1H-imidazole(cas: 616-47-7HPLC of Formula: 616-47-7)

1-Methyl-1H-imidazole(cas: 616-47-7) is actively involved in removing acid during the production of diethoxyphenylphosphine. It is used as an intermediate in organic synthesis.HPLC of Formula: 616-47-7

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem