Category: 5036-48-6

On June 15, 2021, Welzen, Pascal L. W.; Martinez Ciriano, Sydney W.; Cao, Shoupeng; Mason, Alexander F.; Welzen-Pijpers, Imke A. B.; van Hest, Jan C. M. published an article.Category: imidazoles-derivatives The title of the article was Reversibly self-assembled pH-responsive PEG-p(CL-g-TMC) polymersomes. And the article contained the following:

Polymersomes have gained much interest within the biomedical field as drug delivery systems due to their ability to transport and protect cargo from the harsh environment inside the body. For an improved drug efficacy, control over cargo release is however also an important factor to take into account. An often employed method is to incorporate pH sensitive groups in the vesicle membrane, which induce disassembly and content release when the particles have reached a target site in the body with the appropriate pH, such as the acidic microenvironment of tumor tissue or the endosome. In this paper, biodegradable poly(ethylene glycol)-poly(caprolactone-gradient-trimethylene carbonate)-based polymeric vesicles have been developed with disassembly features at mild acidic conditions. Modifying the polymer backbone with imidazole moieties results in vesicle disassembly upon protonation due to the lowered pH. Furthermore, upon increasing the pH efficient re-assembly into vesicles is observed due to the switchable amphiphilic nature of the polymer. When this re-assembly process is conducted in presence of cargo, enhanced encapsulation is achieved. Furthermore, the potency of the polymeric system for future biomedical applications such as adjuvant delivery is demonstrated. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Category: imidazoles-derivatives

The Article related to polyethylene glycol polycaprolactone gradient trimethylene carbonate polymersome selfassembly, Placeholder for records without volume info and other aspects.Category: imidazoles-derivatives

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Yang, Chaokun; Chen, Yanglin; Qu, Ye; Zhang, Jiaxu; Sun, Jianmin published an article in 2021, the title of the article was Phase-controllable polymerized ionic liquids for CO2 fixation into cyclic carbonates.Electric Literature of 5036-48-6 And the article contains the following content:

A catalyst with activity comparable with homogeneous catalysts and easy separation like heterogeneous catalysts would be attractive for CO2 cycloaddition Here, a series of polymerized bis-imidazolium based ionic liquids (PBIL-m) were synthesized and could act as homogeneous catalysts during the CO2 cycloaddition to epoxide process. They could be separated as heterogeneous catalysts after the cycloaddition reaction. PBIL-m was highly active for the cycloaddition reaction due to functional groups such as the imidazole ring, amino group and Br-. Specifically, the solid-liquid transition behavior endowed the PBIL-m with comparable activity to its homogeneous monomer catalysts (BIL-m). Among these PBIL-m catalysts, poly(1-vinyl imidazole-3-hexyl-1-imidazole-3-aminopropyl)dibromide (PBIL-3) exhibited superior catalytic performance due to the appropriate bridge chain compared with other PBIL-m. Under the conditions of 80 掳C, 1.0 MPa and 24 h, 99% propylene carbonate yield and 99% selectivity were obtained. The PBIL-3 also showed excellent universality and recyclability. A reasonable reaction mechanism was deduced that the imidazole ring, amino group and Br- promoted the cycloaddition reaction under metal-, solvent-, and cocatalyst-free conditions. Therefore, the polymerized bis-imidazolium based ionic liquid with solid-liquid transition behavior is a promising candidate for smooth catalysis of CO2 conversion and utilization. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Electric Literature of 5036-48-6

The Article related to carbon dioxide phase controllable polymerized ionicliquid cyclic carbonate fixation, Placeholder for records without volume info and other aspects.Electric Literature of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On July 15, 2021, Guo, Huijuan; Sun, Weiming; Zhang, Quanli; Wu, Yang; Wu, Di; Liu, Yinghua; Yu, Bo; Yu, Qiangliang; Cai, Meirong published an article.Reference of N-(3-Aminopropyl)-imidazole The title of the article was Imidazolium ionic liquid bearing urea moiety as a new corrosion inhibitor of mild steel. And the article contained the following:

The ureido substituted imidazolium bromides (code M-n) were synthesized and their anti-corrosion performance on A3 steel in 5 M HCl solution was studied by weight loss test, electrochem. impedance spectroscopy (EIS), potentiodynamic polarization. The exptl. results reveal that the inhibitor are efficient mixed type corrosion inhibitors, and their inhibition efficiencies increase with increasing the concentration and alkyl chain. Thermodn. parameters were calculated and discussed, indicating the adsorption of M-n on steel surface obeys the Langmuir adsorption isotherm and spontaneous exothermic process. SEM (SEM), XPS and quantum chem. calculation further confirm the existence of an effective protective film of M-n on A3 steel surface. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Reference of N-(3-Aminopropyl)-imidazole

The Article related to imidazolium ionic liquid bearing corrosion inhibitor density functional theory, Placeholder for records without volume info and other aspects.Reference of N-(3-Aminopropyl)-imidazole

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On May 31, 2021, Safiulina, A. M.; Lizunov, A. V.; Borisova, N. E.; Baulina, T. V.; Goryunov, E. I.; Goryunova, I. B.; Brel� V. K. published an article.Application of 5036-48-6 The title of the article was Extraction Properties of Diphenylposphorylureas with Aliphatic �Nitrogen-Containing Substituents. And the article contained the following:

Extraction of lanthanides and actinides from nitric acid solutions with N-(diphenylphosphoryl)-N�n-propylureas containing imidazolyl, diethylamino, pyrid-2-yl, 2-oxopyrrolidino fragments in the �position of the alkyl substituent has been studied. It has been shown that Ho(III) and Yb(III) related to the yttrium subgroup of lanthanides are extracted much better than La(III) and Nd(III) related to the cerium subgroup. N-(Diphenylphosphoryl)urea containing �(2-oxopyrrolidino)propyl fragment at the terminal nitrogen atom shows the best extraction properties. This dependence has been theor. explained by modeling complexation because the coordination of f-block element ion with amide oxygen atom is more preferable The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Application of 5036-48-6

The Article related to chlorodiphenylphosphine lanthanum uranium extraction distillation distribution, Placeholder for records without volume info and other aspects.Application of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On March 18, 2020, Rees, Kelly; Tran, Michael V.; Massey, Melissa; Kim, Hyungki; Krause, Katherine D.; Algar, W. Russ published an article.Name: N-(3-Aminopropyl)-imidazole The title of the article was Dextran-Functionalized Semiconductor Quantum Dot Bioconjugates for Bioanalysis and Imaging. And the article contained the following:

The prerequisites for maximizing the advantageous optical properties of colloidal semiconductor quantum dots (QDs) in biol. applications are effective surface functionalization and bioconjugation strategies. Functionalization with dextran has been highly successful with some nanoparticle materials, but has had very limited application with QDs. Here, we report the preparation, characterization, and proof-of-concept applications of dextran-functionalized QDs. Multiple approaches to dextran ligands were evaluated, including performance with respect to colloidal stability across a range of pH, nonspecific binding with proteins and cells, and microinjection into cells and viability assays. Multiple bioconjugation strategies were demonstrated and applied, including covalent coupling to develop a simple pH sensor, binding of polyhistidine-tagged peptides to the QD for energy transfer-based proteolytic activity assays, and binding with tetrameric antibody complexes (TACs) to enable a sandwich immunoassay and cell immunolabeling and imaging. Our results show that dextran ligands are highly promising for the functionalization of QDs, and that the design of the ligands is tailorable to help optimally meet the requirements of applications. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Name: N-(3-Aminopropyl)-imidazole

The Article related to sequence dextran semiconductor quantum dot bioconjugates bioanalysis imaging, Placeholder for records without volume info and other aspects.Name: N-(3-Aminopropyl)-imidazole

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On June 22, 2022, Luo, Yi; Clabbers, Max T. B.; Qiao, Jian; Yuan, Zhiqing; Yang, Weimin; Zou, Xiaodong published an article.Product Details of 5036-48-6 The title of the article was Visualizing the Entire Range of Noncovalent Interactions in Nanocrystalline Hybrid Materials Using 3D Electron Diffraction. And the article contained the following:

Noncovalent interactions are essential in the formation and properties of a diverse range of hybrid materials. However, reliably identifying the noncovalent interactions in nanocrystalline materials remains challenging using conventional methods such as X-ray diffraction and spectroscopy. Here, we demonstrate that accurate at. positions including hydrogen atoms can be determined using three-dimensional electron diffraction (3D ED), from which the entire range of noncovalent interactions in a nanocrystalline aluminophosphate hybrid material SCM-34 are directly visualized. The protonation states of both the inorganic and organic components in SCM-34 are determined from the hydrogen positions. All noncovalent interactions, including hydrogen-bonding, electrostatic, ��stacking, and van der Waals interactions, are unambiguously identified, which provides detailed insights into the formation of the material. The 3D ED data also allow us to distinguish different types of covalent bonds based on their bond lengths and to identify an elongated terminal P = O �bond caused by noncovalent interactions. Our results show that 3D ED can be a powerful tool for resolving detailed noncovalent interactions in nanocrystalline materials. This can improve our understanding of hybrid systems and guide the development of novel functional materials. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Product Details of 5036-48-6

The Article related to noncovalent interaction nanocrystalline hybrid material electron diffraction, Placeholder for records without volume info and other aspects.Product Details of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On November 30, 2021, Slassi, Siham; Aarjane, Mohammed; Amine, Amina published an article.Formula: C6H11N3 The title of the article was A novel imidazole-derived Schiff base as selective and sensitive colorimetric chemosensor for fluorescent detection of Cu2+ in methanol with mixed aqueous medium. And the article contained the following:

A highly efficient, selective, sensitive, and colorimetric chemosensor SB for Cu2+ detection with turn-on fluorescence behavior in CH3-water solution was synthesized. A good enhancement of the intensity of fluorescence was detected by the incremental addition of Cu2+ after excitation at 286 nm. The fluorescence quantum yield (æ¡? of SB-Cu2+ was calculated for 0.41. The responsive mechanism of SB to copper ion is involved for on the combined effects of C-N isomerization and intramol. charge transfer (ICT) process and chelation-enhanced fluorescence (CHEF). The detection limit for the fluorescent chemosensor SB toward Cu2+ was 0.6 x 10-6 M. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Formula: C6H11N3

The Article related to imidazole schiff base colorimetric chemosensor fluorescent detection copper, Placeholder for records without volume info and other aspects.Formula: C6H11N3

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On March 31, 2021, Leopoldino, Elder C.; Pinheiro, Gabriela; Alves, Ricardo J.; Gerola, Adriana; Souza, Bruno S. published an article.Electric Literature of 5036-48-6 The title of the article was Post-modified polymer with imidazole groups as an efficient and reusable heterogeneous catalyst for organophosphate degradation. And the article contained the following:

In this work, the com. polymer poly(ethylene-alt-maleic anhydride) was used as a platform for the preparation of an imidazole-rich polymeric catalyst (PEIIm) designed for organophosphate degradation The catalyst was prepared at gram-scale using simple and cost-effective steps and was characterized by 1H NMR, IR, CHN and TGA. PEIIm showed higher activity than the free imidazole towards the degradation of di-Et 2,4-dinitrophenylphosphate, an organophosphate model, and was recovered by centrifugation and reused without loss of activity. Importantly, experiments performed under excess of substrate demonstrate that true catalysis takes place. Solvent kinetic isotope effect indicates that the pendant imidazole groups attack the phosphorus atom to form a phosphorylated polymeric intermediate that is rapidly hydrolyzed, allowing for the catalyst regeneration. PEIIm was also employed in the degradation of toxic pesticide Et paraoxon, resulting in a reduction in its half-life from 780 days to 25 days at 25 掳C, pH 8.0. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Electric Literature of 5036-48-6

The Article related to imidazole group polymer heterogeneous catalyst organophosphate degradation, Placeholder for records without volume info and other aspects.Electric Literature of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Biswas, Sneha; Chowdhury, Tania; Ghosh, Avik; Das, Abhijit K.; Das, Debasis published an article in 2022, the title of the article was Effect of O-substitution in imidazole based Zn(II) dual fluorescent probes in the light of arsenate detection in potable water: a combined experimental and theoretical approach.Computed Properties of 5036-48-6 And the article contains the following content:

Efficient detection of arsenate (AsO43-) from contaminated drinking water extracted from underground has become a matter of utmost necessity and an exquisite challenge owing to the growing public health issue due to arsenicosis. In order to combat this we planned to detect arsenate with the naked eye under UV light using a novel chemosensor material whose structure and functioning as a sensor could be certified mechanistically. Hence we were encouraged to synthesize two differently O-substituted imidazole based homologous ligands: C1 (HL1 = 2-((E)-(3-(1H-imidazole-1-yl)propylimino)methyl)-6-ethoxyphenol) and C2 (HL2 = 2-((E)-(3-(1H-imidazole-1-yl)propylimino)methyl)-6-methoxyphenol). To accomplish the purposeful exploration of the luminescent sensor, we considered Chelation Enhanced Fluorescence (CHEF) and kept on searching for a metal cation that would be able to turn on the fluorescence of the ligands. Considering Zn(II) as the most suitable candidate, luminescent complexes D1 and D2 ({[Zn2(L1)2(I)2](DMF)} and [Zn2(L2)2(I)2](DMF), resp.) were synthesized and characterized by SXRD, UV-Vis, FT-IR, and photoluminescence spectroscopy. In spite of the resemblance in the solid state structures of D1 and D2, the selective response of D1 towards arsenate with high quenching constants (2.13 x 106), unlike D2, has been demonstrated mechanistically with steady state and time resolved fluorescence titration, solution phase ESI-MS spectral anal. and DFT studies. The selectivity and sensitivity of the sensor D1 explicitly make this material a potent candidate for arsenate detection due to its very low detection limit (8.2 ppb), low cost and user friendly characteristics. Real life implementation of this work in a test strip is expected to prove beneficial for public health to identify arsenate polluted water. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Computed Properties of 5036-48-6

The Article related to zinc dual fluorescent probe arsenate detection density functional theory, Placeholder for records without volume info and other aspects.Computed Properties of 5036-48-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

On April 30, 2022, Pham, Julie; Forget, Amelie; Bridonneau, Nathalie; Mattana, Giorgio; Stavrinidou, Eleni; Zrig, Samia; Piro, Benoit; Noel, Vincent published an article.Recommanded Product: N-(3-Aminopropyl)-imidazole The title of the article was In vivo electrochemically-assisted polymerization of conjugated functionalized terthiophenes inside the vascular system of a plant. And the article contained the following:

We investigate the possibility of producing biofuel cell electrode materials in vivo by injecting the reagents directly into plant tissues. We first introduce model electroactive substances Fe(CN)64- and Ru(NH3)63+ into a Nicotiana tabacum leaf. In situ electrochem. measurements make it possible to trace the distribution of these substances. As well as mapping the vascular content, electrochem. can be used to trigger reactions directly inside the plant. The injection of thiophene (T) and ethylenedioxythiophene (E)-based trimers (ETE) anchoring an Os(2,2�bipyridine)2(1-(3-aminopropyl)-imidazole)Cl Os-complex followed by the application of anodic polarization triggers a polymerization reaction in the region of the plant vascular system containing the monomer, showing that it is possible to generate electroactive organic macromols. locally in vivo. The experimental process involved the reaction of N-(3-Aminopropyl)-imidazole(cas: 5036-48-6).Recommanded Product: N-(3-Aminopropyl)-imidazole

The Article related to terthiophene injection anodic polarization plant vascular polymerization, Placeholder for records without volume info and other aspects.Recommanded Product: N-(3-Aminopropyl)-imidazole

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem