Category: 35487-17-3

Collagen/cellulose hydrogel beads reconstituted from ionic liquid solution for Cu(II) adsorption was written by Wang, Jilei;Wei, Ligang;Ma, Yingchong;Li, Kunlan;Li, Minghui;Yu, Yachen;Wang, Lei;Qiu, Huihui. And the article was included in Carbohydrate Polymers in 2013.Recommanded Product: 35487-17-3 This article mentions the following:

A novel adsorbent, biodegradable collagen/cellulose hydrogel beads (CCHBs), was prepared by reconstitution from a 1-Bu, 3-methylimidazolium chloride ([C₄mim]Cl) solution The adsorption properties of the CCHBs for Cu(II) ion removal from aqueous solutions were investigated and compared with those of cellulose hydrogel beads (CHBs). The CCHBs have a three-dimensional macroporous structure whose amino groups are believed to be the main active binding sites of Cu(II) ions. The equilibrium adsorption capacity (q_e) of the CCHBs is greatly influenced by the collagen/cellulose mass ratio, and steeply increases until the collagen/cellulose mass ratio exceeds 2/1. The maximum adsorption is obtained at pH 6. The q_e of Cu(II) ions increases with increased initial concentration of the solution Based on Langmuir isotherms, the maximum adsorption capacity (q_m) of CCHB3 (collagen/cellulose mass ratio of 3/1) is 1.06 mmol/g. The CCHBs maintain good adsorption properties after the fourth cycle of adsorption-desorption. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Recommanded Product: 35487-17-3).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3鈥揅6) is higher than in water and generally decreases with a Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.Recommanded Product: 35487-17-3

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Layered organic-inorganic hybrid materials based on ionic liquid and lead chloride: Insights into the structure and properties was written by Balachandran, Nisha;Suseeladevi, Asha;Periya, Vijayalakshmi Kunduchi;Robert, Temina Mary;Soundiraraju, Bhuvaneswari;Cyriac, Jobin;Mathew, Dona. And the article was included in Journal of Molecular Liquids in 2020.Safety of 1-Methyl-1H-imidazol-3-ium chloride This article mentions the following:

Layered organic-inorganic hybrid materials are an emerging class of materials with excellent stability and outstanding optoelectronic properties. Here, we report the synthesis, characterization and optical properties of hybrid materials formed from lead chloride (PbCl₂)-methylimidazolium chloride (MimCl) and PbCl₂-alkyl methylimidazolium chlorides (AmimCl) of varying alkyl chain lengths viz. Et (C₂mimCl), Bu (C₄mimCl) and hexyl (C₆mimCl). The molar ratio of PbCl₂ to MimCl and AmimCl had a profound influence on the formation and properties of two-dimensional (2D) hybrid materials. The conformations and structural aspects of the synthesized materials with varying substitutions were extensively evaluated and correlated using computational studies. MimCl-PbCl₂, C₂mimCl-PbCl₂ and C₆mimCl-PbCl₂ forms 2D structures while C₄mimCl-PbCl₂ was forming 2D and 1D structures as evident from topog. and morphol. evaluations through at. force microscopy (AFM) and transmission electron microscopy (TEM). The materials synthesized were non-hygroscopic and exhibited excellent thermal stability. The AmimCl-PbCl₂ shows absorption in the UV region with the onset extends to the visible range and exhibits good photoluminescence at 532 nm. These hybrid materials showed a charge carrier lifetimes (10-40 ns) and a photoresponse (photocurrent of the order microamperes) which make them a potential candidate for optoelectronic devices. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Safety of 1-Methyl-1H-imidazol-3-ium chloride).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has become an important synthon in the development of new drugs. Imidazole is incorporated into many important biological compounds. The most pervasive is the amino acid histidine, which has an imidazole side-chain. Histidine is present in many proteins and enzymes, e.g. by binding metal cofactors, as seen in hemoglobin.Safety of 1-Methyl-1H-imidazol-3-ium chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Environmentally Friendly Recycling of Fuel-Cell Membrane Electrode Assemblies by Using Ionic Liquids was written by Balva, Maxime;Legeai, Sophie;Leclerc, Nathalie;Billy, Emmanuel;Meux, Eric. And the article was included in ChemSusChem in 2017.Name: 1-Methyl-1H-imidazol-3-ium chloride This article mentions the following:

The Pt nanoparticles used as the catalyst in proton exchange membrane fuel cells (PEMFCs) represent 鈭?6% of the total price of the cells for a large-scale production, and this is one of the barriers to their commercialization. Therefore, the recycling of the Pt catalyst could be the best alternative to limit the production costs of PEMFCs. The usual recovery routes for spent catalysts containing Pt are pyro-hydrometallurgical processes in which a calcination step is followed by aqua regia treatment, and these processes generate fumes and NO_x emissions, resp. The electrochem. recovery route proposed here is more environmentally friendly, performed under soft temperature conditions, and does not result in any gas emissions. It consists of the coupling of the electrochem. leaching of Pt in chloride-based ionic liquids (ILs), followed by its electrodeposition. The leaching of Pt was studied in pure ILs and in ionic-liquid melts at different temperatures and with different chloride contents. Through the modulation of the composition of the ionic-liquid melts, it is possible to leach and electrodeposit the Pt from fuel-cell electrodes in a single-cell process under an inert or ambient atm. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Name: 1-Methyl-1H-imidazol-3-ium chloride).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Name: 1-Methyl-1H-imidazol-3-ium chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Process based screening method and systems analysis for pre-combustion carbon capture using ionic liquids was written by Basha, Omar M.. And the article was included in Computer-Aided Chemical Engineering in 2019.Related Products of 35487-17-3 This article mentions the following:

Despite extensive exptl. work investigating CO2 solubility in many Ionic Liquids (IL), identifying the most appropriate IL for pre-combustion CO2 capture from a techno-economic perspective, remains highly iterative, due to the significant importance of parameters such as mass transfer efficiency and ease of solvent separation, which are often overlooked during exptl. investigations. In this work, a process-based screening method has been developed based on the phys. properties of the ILs, the screening method has four main criteria, namely: 1. Mass transfer, 2. Ease of solvent regeneration, 3. CO2 solubility and 4. H2S solubility Correlations have been developed for each of the four criteria to allow for direct comparison of ILs, and the screening method was used to identify the seven most promising ILs from a database of 295 ILs. The seven ILs where then compared in AspenPlus using a conceptual process containing one absorption, three separation and one compression stage, and a systems anal. was subsequently conducted to compare the ILs using two main criteria, the net power requirement and the cost of CO2 capture. The IL [bmim][NfO] was determined to have the lowest power requirement and lowest CO2 capture cost, whereas [hmim][bti] had the highest values. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Related Products of 35487-17-3).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Related Products of 35487-17-3

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Evaluations of imidazolium ionic liquids as novel skin permeation enhancers for drug transdermal delivery was written by Zhang, Ding;Wang, Huai-Ji;Cui, Xiu-Ming;Wang, Cheng-Xiao. And the article was included in Pharmaceutical Development and Technology in 2017.Category: imidazoles-derivatives This article mentions the following:

In this work, imidazolium ionic liquids (imidazolium ILs) were employed as the novel chem. permeation enhancers (CPEs) and their performances and mechanisms of action were deeply investigated. Testosterone was used as a model drug to investigate the transdermal delivery enhancement of twenty imdidazolium ILs. The results suggested that the promotion activity connected to the structure and composition of the ILs. The quant. structure-activity relationship (QSAR) model revealed a good linearity between the electronic properties of ILs and their enhancements. Furthermore, the transepidermal water loss (TEWL) and scanning laser confocal microscope (CLSM) examinations showed the strong improvement of ILs on skin barrier permeability, which were well correlated with the drug penetration profiles. The total reflection-Fourier transform IR spectroscopy (ATR-FTIR) and at. force microscope (AFM) evaluations of skins indicated that the ILs can disrupt the regular and compact arrangements of the corneocytes, change the surface properties of stratum corneum, and make the skin structure more permeable. Our work demonstrated the significant skin permeation promotion profiles of the imidazolium ILs, which are of great potential in transdermal drug delivery systems. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Category: imidazoles-derivatives).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Category: imidazoles-derivatives

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Pd/[C₂NH₂mim][Br] Thin Film Versus Pd/[C₈mim][Cl] or Pd/[C₈mim][BF₄]: Catalytic Applications in Electrooxidation of Methanol, p-Nitrophenol Reduction and C-C Coupling Reaction was written by Gheitasi Zarooni, Mahtab;Hoseini, S. Jafar;Bahrami, Mehrangiz;Roushani, Mahmoud;Nabavizadeh, S. Masoud. And the article was included in Journal of Inorganic and Organometallic Polymers and Materials in 2020.Quality Control of 1-Methyl-1H-imidazol-3-ium chloride This article mentions the following:

In this study, different ionic liquids including 1-aminoethyl-3-methyl-imidazolium bromide [C₂NH₂mim][Br] (1), 1-methyl-3-octylimidazolium chloride [C₈mim][Cl] (2) and 1-methyl-3-octylimidazolium tetrafluoroborate [C₈mim][BF₄] (3) were applied to stabilize Pd nanoparticles (NPs) at toluene/water interface as thin films. Field emission-SEM (FE-SEM) images showed puckered chains of ionic liquid (1) around the Pd NPs as flower nanostructures. Transmission electron microscopy (TEM) image of Pd/1 showed clearly core-shell nanostructures. Furthermore, applications of Pd/1, Pd/2 and Pd/3 were investigated in the Suzuki-Miyaura C-C coupling reaction in the presence and absence of ultrasonic waves, hydrogenation catalysis of p-nitrophenol reduction and methanol oxidation reaction. Interestingly, J_f (forwarding c.d. due to methanol oxidation) was observed only for Pd/1. We believe that interactions of -NH₂ and imidazolium groups of ionic liquid 1 with Pd particles are very important in producing of puckered shells around the Pd NPs. Injection of electron d. from -NH₂ group and Br^– of ionic liquid 1 to Pd content tends to Pd be softer than other ionic liquids (2 or 3). This effect weakens the strength of Pd-O and facilitates the intermol. reductive elimination between Pd-O and Pd-C鈮僌 in rate-determining step of methanol oxidation to produce CO₂ product. However, electron releasing group accelerates the increasement in neg. charge d. of metal accelerates intramol. or intermol. reduction elimination. Graphic Abstract: Stabilization of Pd nanoparticles from organometallic precursor in the presence of various ionic liquids is investigated. The obtained Pd/ionic liquid thin films were applied in catalytic reactions such as Suzuki-Miyaura C-C coupling reaction, p-nitrophenol reduction and methanol oxidation process for fuel cells. In spite of Pd nanoparticle thin films used for methanol oxidation reaction that exhibit no considerable methanol oxidation, these catalysts exhibit good electrocatalytic activity. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Quality Control of 1-Methyl-1H-imidazol-3-ium chloride).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Quality Control of 1-Methyl-1H-imidazol-3-ium chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

An efficient process for pretreatment of lignocelluloses in functional ionic liquids was written by Dong, Shi-Jia;Zhang, Bi-Xian;Gao, Yun-Fei;Hu, Xiao-Mei. And the article was included in International Journal of Polymer Science in 2015.Safety of 1-Methyl-1H-imidazol-3-ium chloride This article mentions the following:

The complex structure of the lignocelluloses is the main obstacle in the conversion of lignocellulosic biomass into valuable products. Ionic liquids provide the opportunities for their efficient pretreatment for biomass. Therefore, in this work, pretreatment of corn stalk was carried out in ultrasonic-assisted ionic liquid including 1-butyl-3-methylimidazolium chloride [BMIM]Cl, 1-H-3-methylimidazolium chloride [HMIM]Cl, and 1-(1-propylsulfonic)-3-imidazolium chloride [HSO₃-pMIM]Cl at 70掳C for 2 h.We compared the pretreatments by ionic liquid with and without the addition of deionized water. Fourier transform IR spectroscopy (FTIR) and SEM were employed to analyze the chem. characteristics of regenerated cellulose-rich materials. [HMIM]Cl and [HSO₃-pMIM]Cl were effective in lignin extraction to obtain cellulose-rich materials. FTIR anal. and SEM anal. indicated the effective lignin removal and the reduced crystallinity of cellulose-rich materials. Enzymic hydrolysis of cellulose-rich materials was performed efficiently. High yields of reducing sugar and glucose were obtained when the corn stalk was pretreated by [HMIM]Cl and [HSO₃-pMIM]Cl. Ionic liquids provided the ideal environment for lignin extraction and enzymic hydrolysis of corn stalk and [HMIM]Cl and [HSO₃-pMIM]Cl proved the most efficient ionic liquids This simple and environmentally acceptable method has a great potential for the preparation of bioethanol for industrial production In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Safety of 1-Methyl-1H-imidazol-3-ium chloride).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has become an important synthon in the development of new drugs. This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Safety of 1-Methyl-1H-imidazol-3-ium chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

An efficient approach for the deprotection of esters using ionic liquid as nucleophile was written by Wei, Benmei;Zhang, Zhiyong;Dai, Zhiqun;Guan, Jintao. And the article was included in Asian Journal of Chemistry in 2013.Name: 1-Methyl-1H-imidazol-3-ium chloride This article mentions the following:

An efficient approach for the deprotection of esters was developed using ionic liquid as nucleophile in the presence of protic acid. Using Me benzoate as a model compound, the best result was obtained by the combination of 1-methylimidazolium bromide and methane sulfonic acid with a conversion of 96% after 2 h at 120掳. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Name: 1-Methyl-1H-imidazol-3-ium chloride).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Name: 1-Methyl-1H-imidazol-3-ium chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

An efficient approach for the deprotection of esters using ionic liquid as nucleophile was written by Wei, Benmei;Zhang, Zhiyong;Dai, Zhiqun;Guan, Jintao. And the article was included in Asian Journal of Chemistry in 2013.Name: 1-Methyl-1H-imidazol-3-ium chloride This article mentions the following:

An efficient approach for the deprotection of esters was developed using ionic liquid as nucleophile in the presence of protic acid. Using Me benzoate as a model compound, the best result was obtained by the combination of 1-methylimidazolium bromide and methane sulfonic acid with a conversion of 96% after 2 h at 120°. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Name: 1-Methyl-1H-imidazol-3-ium chloride).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Name: 1-Methyl-1H-imidazol-3-ium chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Pretreatment of yellow pine in an acidic ionic liquid: Extraction of hemicellulose and lignin to facilitate enzymatic digestion was written by Cox, Blair J.;Ekerdt, John G.. And the article was included in Bioresource Technology in 2013.Recommanded Product: 1-Methyl-1H-imidazol-3-ium chloride This article mentions the following:

The acidic ionic liquid 1-H-3-methylimidazolium chloride can effectively pretreat yellow pine wood chips under mild conditions for enzymic saccharification. Wood samples were treated at temperatures between 110 and 150 °C for up to 5 h in the ionic liquid and three fractions collected; a cellulose rich fraction, lignin, and an aqueous fraction. This treatment caused the hemicellulose and the lignin to be degraded and dissolved from the cell walls of the pine wood. The lignin was depolymerized and subsequently dissolved in the ionic liquid This process occurred more quickly at higher temperatures, although at the highest temperatures tested, significant cellulose degradation also occurred. The cellulose rich fraction was saccharified using cellulase from Trichoderma viride, with longer pretreatment times at 130 °C resulting in higher glucose yields. In the experiment, the researchers used many compounds, for example, 1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3Recommanded Product: 1-Methyl-1H-imidazol-3-ium chloride).

1-Methyl-1H-imidazol-3-ium chloride (cas: 35487-17-3) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Recommanded Product: 1-Methyl-1H-imidazol-3-ium chloride

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem