Category: 33529-02-1

Related Products of 33529-02-1, In the chemical reaction process, reaction time, type of solvent, can easily affect the result of the reaction, thereby determining the yield and properties of the reaction product. An updated downstream synthesis route of 33529-02-1 as follows.

In einem Autoklaven wurden 0,25 Mol 1-Decylimidazol, welches durch die Radziszewski-Reaktion aus Glyoxal, Formaldehyd, Ammoniak und 1-Decylamin zugaenglich ist (siehe Ullmann’s Encyclopedia of Industrial Chemistry, 6th edition, 2000 electronic release, Chapter “IMIDAZOLE AND DERIVATIVES – Production), und 0,3 Mol Dimethylcarbonat in 100 ml Methanol zusammen mit 1,5 g Kaliumcarbonat und 0,1 g 18-Krone-6 12 Stunden auf 135C erhitzt. Nach dem Abkuehlen wurde der Reaktionsaustrag filtriert und mit 150 ml 50%iger waessriger Tetrafluoroborsaeure (Fa. Acros) versetzt. Nun wurde fuer eine Stunde unter Ruehren auf 50C erwaermt und anschliebetaend die waessrige Phase abgetrennt. Die verbleibende organische Phase wurde erneut mit 100 ml 50 %iger waessriger Tetrafluoroborsaeure versetzt, fuer eine weitere Stunde unter Ruehren auf 50C erwaermt und die waessrige Phase abgetrennt. Der organische Rueckstand wurde nun zweimal mit Cyclohexan extrahiert und danach im Vakuum bei 80C von Loesungsmittelresten befreit. Es wurden 0,16 Mol 1-Decyl-3-methylimidazolium-tetrafluoroborat erhalten, was einer Ausbeute von 64 % entspricht.

According to the analysis of related databases, 33529-02-1, the application of this compound in the production field has become more and more popular.

Reference:
Patent; BASF AKTIENGESELLSCHAFT; EP1398318; (2004); A1;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Synthetic Route of 33529-02-1, Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 33529-02-1, name is 1-Decyl-1H-imidazole, This compound has unique chemical properties. The synthetic route is as follows.

1-Decylimidazole was synthesized according to previous literature. 1-Decylimidazole (5.49 g, 26.3 mmol) and 3-bromopropene (3.1 g, 26.3 mmol) were added to a 100 mL round-bottom flask containing 30 mL ethanol with condenser. The reaction mixture was stirred for 24 h. Solvent was then removed under reduced pressure. The crude product was washed three times with ether and dried in a vacuum oven at 50 C for 24 h to give the 1-allyl-3-decylimidazolium bromide (ADIm). 1-Allyl-3-decylimidazolium bromide: This compound was obtained in 97% as a yellow viscous oil. 1H NMR (DMSO-d6, 400 MHz): delta 9.30 (s, 1H, -N-CH-N-), 7.87 (s, 1H, -N-CH-CH-N-), 7.78 (s, 1H, -N-CH-CH-N-), 6.07 (m, 1H, -CH=CH2), 5.32 (dd, 2H, =CH2), 4.87 (d, 2H, -CH2-CH=CH2), 4.19 (t, 2H, -N-CH2-), 1.79 (m, 2H, -CH2-CH2-), 1.24 (broad, 14H, -CH2-CH3), 0.85 (t, 3H, -CH3).

The chemical industry reduces the impact on the environment during synthesis 1-Decyl-1H-imidazole. I believe this compound will play a more active role in future production and life.

Reference:
Article; Zhou, Chuan; Li, Yi-He; Jiang, Zhen-Hua; Ahn, Kwang-Duk; Hu, Tian-Jiao; Wang, Qing-Hua; Wang, Chun-Hua; Chinese Chemical Letters; vol. 27; 5; (2016); p. 685 – 688;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Synthetic Route of 33529-02-1, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. 33529-02-1, name is 1-Decyl-1H-imidazole belongs to imidazoles-derivatives compound, it is a common compound, a new synthetic route is introduced below.

General procedure: Briefly, a mixture of alkylimidazoles such as 1-methyl-1H-imidazole (MIM), 1-hexyl-1H-imidazole(HIM), 1-octyl-1H-imidazole (OIM), and 1-decyl-1H-imidazole (DIM) (1 mmol), as well as cinnamylchloride (1 mmol) solvent-free were microwaved to 200 MW at 80 C for 5 min (optimumreaction condition). Reaction completion was marked by separation of dense IL. Products suchas 1-methyl-3-cinnamylimidazolium chloride [CMIM]Cl, 1-hexyl-3-cinnamylimidazolium chloride[CHIM]Cl, 1-octyl-3-cinnamylimidazolium chloride [COIM]Cl, and 1-decyl-3-cinnamylimidazolium chloride [CDIM]Cl were isolated by decanting toluene to remove any unreacted starting materialsand solvents. Subsequently, ILs were rinsed with diethyl ether (4 10 mL) separating afterward thislatter layer by decantation. In each case, ILs were finally dried under reduced pressure to get rid of thevolatile organic compounds.

The synthetic route of 1-Decyl-1H-imidazole has been constantly updated, and we look forward to future research findings.

Reference:
Article; Doria, Oscar Forero; Castro, Ricardo; Gutierrez, Margarita; Valenzuela, Diego Gonzalez; Santos, Leonardo; Ramirez, David; Guzman, Luis; Molecules; vol. 23; 9; (2018);,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Synthetic Route of 33529-02-1, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. 33529-02-1, name is 1-Decyl-1H-imidazole belongs to imidazoles-derivatives compound, it is a common compound, a new synthetic route is introduced below.

General procedure: Briefly, a mixture of alkylimidazoles such as 1-methyl-1H-imidazole (MIM), 1-hexyl-1H-imidazole(HIM), 1-octyl-1H-imidazole (OIM), and 1-decyl-1H-imidazole (DIM) (1 mmol), as well as cinnamylchloride (1 mmol) solvent-free were microwaved to 200 MW at 80 C for 5 min (optimumreaction condition). Reaction completion was marked by separation of dense IL. Products suchas 1-methyl-3-cinnamylimidazolium chloride [CMIM]Cl, 1-hexyl-3-cinnamylimidazolium chloride[CHIM]Cl, 1-octyl-3-cinnamylimidazolium chloride [COIM]Cl, and 1-decyl-3-cinnamylimidazolium chloride [CDIM]Cl were isolated by decanting toluene to remove any unreacted starting materialsand solvents. Subsequently, ILs were rinsed with diethyl ether (4 10 mL) separating afterward thislatter layer by decantation. In each case, ILs were finally dried under reduced pressure to get rid of thevolatile organic compounds.

The synthetic route of 1-Decyl-1H-imidazole has been constantly updated, and we look forward to future research findings.

Reference:
Article; Doria, Oscar Forero; Castro, Ricardo; Gutierrez, Margarita; Valenzuela, Diego Gonzalez; Santos, Leonardo; Ramirez, David; Guzman, Luis; Molecules; vol. 23; 9; (2018);,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Researchers who often do experiments know that organic synthesis is a process of preparing more complex target molecules from simple raw materials through one or more chemical reactions. Generally, it requires fewer steps, and cheap raw materials. 33529-02-1, name is 1-Decyl-1H-imidazole, A new synthetic method of this compound is introduced below., HPLC of Formula: C13H24N2

(2) Add 50 mL of ethanol to a four-neck round bottom flask.Further added 19.35 g (0.05 mol) of N,N-dimethyl(1-bromopropyl)decyl ammonium bromide, 10.42 g (0.05 mol)N-decylimidazole and1 g of tetrabutylammonium bromide,The mixture was heated to 70 C with stirring, and the reaction was stirred for 36 hours, and then ethanol was distilled off under reduced pressure.The solid was washed three times with chloroform.The filter cake was vacuum dried at 60 C for 5 hours to obtain a crude product;The crude product is recrystallized three times in acetone to obtain the product.1-(N,N-dimethylammonium alkylammonium) propyl-3-hydrazinium imidazolium dibromide,The yield was 85.8%.

The synthetic route of 33529-02-1 has been constantly updated, and we look forward to future research findings.

Reference:
Patent; Zhengzhou University of Light Industry; Yang Xuzhao; Wang Jun; Li Yakun; Ping Dan; Zhang Yingying; Wu Shide; (8 pag.)CN109970657; (2019); A;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Synthetic Route of 33529-02-1, In the chemical reaction process, reaction time, type of solvent, can easily affect the result of the reaction, thereby determining the yield and properties of the reaction product. An updated downstream synthesis route of 33529-02-1 as follows.

In einem Autoklaven wurden 0,25 Mol 1-Decylimidazol, welches durch die Radziszewski-Reaktion aus Glyoxal, Formaldehyd, Ammoniak und 1-Decylamin zugaenglich ist (siehe Ullmann’s Encyclopedia of Industrial Chemistry, 6th edition, 2000 electronic release, Chapter “IMIDAZOLE AND DERIVATIVES – Production), und 0,3 Mol Dimethylcarbonat in 100 ml Methanol zusammen mit 1,5 g Kaliumcarbonat und 0,1 g 18-Krone-6 12 Stunden auf 135C erhitzt. Nach dem Abkuehlen wurde der Reaktionsaustrag filtriert und mit 150 ml 50%iger waessriger Tetrafluoroborsaeure (Fa. Acros) versetzt. Nun wurde fuer eine Stunde unter Ruehren auf 50C erwaermt und anschliebetaend die waessrige Phase abgetrennt. Die verbleibende organische Phase wurde erneut mit 100 ml 50 %iger waessriger Tetrafluoroborsaeure versetzt, fuer eine weitere Stunde unter Ruehren auf 50C erwaermt und die waessrige Phase abgetrennt. Der organische Rueckstand wurde nun zweimal mit Cyclohexan extrahiert und danach im Vakuum bei 80C von Loesungsmittelresten befreit. Es wurden 0,16 Mol 1-Decyl-3-methylimidazolium-tetrafluoroborat erhalten, was einer Ausbeute von 64 % entspricht.

According to the analysis of related databases, 33529-02-1, the application of this compound in the production field has become more and more popular.

Reference:
Patent; BASF AKTIENGESELLSCHAFT; EP1398318; (2004); A1;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Researchers who often do experiments know that organic synthesis is a process of preparing more complex target molecules from simple raw materials through one or more chemical reactions. Generally, it requires fewer steps, and cheap raw materials. 33529-02-1, name is 1-Decyl-1H-imidazole, A new synthetic method of this compound is introduced below., Quality Control of 1-Decyl-1H-imidazole

General procedure: A solution of 1,3-propane sultone (1.34 g, 0.011 mol) in acetone (12 mL) was slowly added to the flask containing the akyl imidazole (0.012 mol) at 0 C. The reaction mixture was heated to the room temperature and, then, stirred for 5 days. After that, the reaction solution was filtrated giving the product as a solid. The solid was washed two times with a mixture of 1:1 hexane/dichloromethane and driedunder vacuum, giving the zwitterionic surfactant in 51% yield. The given product was characterized by 1H-NMR in CDCl3.

The basis of chemical reaction formula synthesis, the synthesis route is composed of some specific reactions and combined according to certain logical thinking. We look forward to the emergence of more reaction modes in the future.

Reference:
Article; Modenez, Iago A.; Sastre, Diego E.; Moares, Fernando C.; Marques Netto, Caterina G.C.; Molecules; vol. 23; 9; (2018);,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Electric Literature of 33529-02-1, These common heterocyclic compound, 33529-02-1, name is 1-Decyl-1H-imidazole, its traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route.

General procedure: In a 250 mL two-neck round bottom flask equipped with a condenser linked to the vacuum-argon line, N-butylimidazole (title 99% w/w, Alfa Aesar) (4.2 g, 33.4 mmol) was charged and after degassing with three vacuum/argon cycles, 1H,1H,2H,2H-perfluorooctyliodide 96% w/w, Aldrich) (23.8 g, 50.1 mmol) was added. After three more vacuum/argon cycles the temperature of the oil bath was increased from 25 C to 120 C in 10 min. After heating for 6 h, NMR analysis of the crude reaction mixture (Fig. 6S, ESI) showed that the reaction went to completion and the occurrence, together with the target molecule C4-I, of the by-products N-butyl-imidazolium iodide and 1H,1H,2H-perfluoro-1-octene ( Scheme 1 ) typical of a Hofmann elimination of the imidazolium salts [29-31]. By cooling the presence of two phases was observed: a viscous red liquid (containing C4-I, N-butyl-imidazolium iodide and C6F13CH = CH2) at the top and a pale yellow liquid (the unreacted 1H,1H,2H,2H-perfluorooctyl iodide with C6F13CH = CH2) at the bottom. The phases were separated by decantation and the viscous red liquid washed three times with petroleum ether (3 * 50 mL) and three times with diethyl ether (3 * 50 mL). The solvent and the volatile by-product C6F13CH = CH2 (bp = 102-104) were eliminated under vacuum (30 C/53 Pa). After the work-up 1H NMR of the red oil showed peaks of C4-I (75%) and of N-butyl-imidazolium iodide (25%). The raw product (20 g) was dissolved in 20 mL of dichloromethane and filtered under argon on anhydrous celite (40 g) previously wetted with 200 mL of dichloromethane. The filtration was repeated two times. Celite was then washed with 80 mL of dichloromethane. Evaporation of the solvent (30 C/53 Pa) gives a red sticky wax with a yield of 75.1% (15.0 g, 25 mmol).

Statistics shows that 1-Decyl-1H-imidazole is playing an increasingly important role. we look forward to future research findings about 33529-02-1.

Reference:
Article; Zama, Isabella; Gorni, Giacomo; Borzatta, Valerio; Cassani, Maria Cristina; Crupi, Cristina; Di Marco, Gaetano; Journal of Molecular Liquids; vol. 223; (2016); p. 749 – 753;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Researchers who often do experiments know that organic synthesis is a process of preparing more complex target molecules from simple raw materials through one or more chemical reactions. Generally, it requires fewer steps, and cheap raw materials. 33529-02-1, name is 1-Decyl-1H-imidazole, A new synthetic method of this compound is introduced below., Safety of 1-Decyl-1H-imidazole

Equipped with a stirrer, a thermometer, a three-necked flask was added 1.67 g (8.0 mmol) N- decyl-imidazole, 0.56 g (4.4 mmol) 1,3- dichloro-2-propanol, at 115 ~ 125 C The reaction was stirred after, TLC tracking progress of the reaction, the reaction of about 8 ~ 12 h, the crude product was mixed with chloroform and ethyl acetate solvent was recrystallized to give a white powdery solid 1,1′-didecyl-3,3 ‘- (2- hydroxy-1,3-propylene) imidazole hydrochloride 1.42 g, yield 65.2%.

The basis of chemical reaction formula synthesis, the synthesis route is composed of some specific reactions and combined according to certain logical thinking. We look forward to the emergence of more reaction modes in the future.

Reference:
Patent; Qiqihar university; Wang, LiYan; Deng, QiGang; Zheng, YongJie; Huo, shichao; Liu, Jia; Sun, zhu; (10 pag.)CN103951702; (2016); B;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

33529-02-1, name is 1-Decyl-1H-imidazole, belongs to imidazoles-derivatives compound, is considered to be a conventional heterocyclic compound, which is widely used in drug synthesis. The chemical synthesis route is as follows. category: imidazoles-derivatives

4-Vinylbenzyl chloride (1.00 g, 6.55 mmol) and 1-decylimidazole (1.50 g, 7.20 mmol) were stirred in acetonitrile (40 mL) at reflux for 18 h. Upon cooling, the reaction mixture was concentrated to form a yellow viscous oil and washed with Et2O (3 ¡Á 40 mL). The resulting oil was then dissolved in H2O (40 mL). LiTf2N (2.26 g, 7.87 mmol) was added, and then the resulting mixture stirred at room temperature for 12 h. A yellow oil was then extracted from this aqueous mixture with CH2Cl2 (3 ¡Á 50 mL). The CH2Cl2 layer was then washed with H2O (3 ¡Á 100 mL), dried over anhydrous MgSO4, filtered, and concentrated to give monomer 2c as a light yellow oil (yield: 3.49 g, 88%). 1H NMR (300 MHz, CDCl3): delta8.88 (s, 1H), 7.44 (d, J = 8.2 Hz, 2H), 7.33 (d, J = 8.2 Hz, 2H), 7.24 (dt, J = 12.0, 2.0 Hz, 2H), 6.69 (dd, J = 17.6, 10.9 Hz, 1H), 5.78 (d, J = 17.6, 1H), 5.31 (d, J = 10.8, 1H), 5.31 (s, 2H), 4.16 (t, J = 7.4 Hz, 2H), 1.93-1.76 (m, 2H), 1.39-1.17 (m, 14H), 0.87 (t, J = 7.0 Hz, 3H). 13C NMR (75 MHz, CDCl3): delta139.19, 135.83, 135.58, 131.69, 129.29, 127.41, 122.45, 122.24, 122.08, 117.82, 115.76, 53.46, 50.49, 31.95, 30.18, 29.51, 29.40, 29.34, 28.96, 26.24, 22.77, 14.21. IR (neat): 3146.88, 2927.24, 2856.85, 1560.77, 1456.43, 1348.21, 1182.03, 1133.87, 1053.89, 990.02, 914.86, 830.80, 788.70, 739.55, 653.29. HRMS (ES) calcd. for C24H33F6N3O4S2 (M+ Tf2N-): 605.1817; observed: 605.2435. Since imidazolium-based ionic liquid compounds are known in the literature to have combustion issues for C, H, and N elemental analysis [34], the 1H and 13C NMR spectra for isolated 2c are provided in the Supplementary Data to help confirm its purity.

The synthetic route of 33529-02-1 has been constantly updated, and we look forward to future research findings.

Reference:
Article; Shi, Zhangxing; Newell, Brian S.; Bailey, Travis S.; Gin, Douglas L.; Polymer; vol. 55; 26; (2014); p. 6664 – 6671;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem