Category: 174501-65-6

The author of 《The effect of nanoconfinement on the glass transition temperature of ionic liquids》 were Zuo, Yuchen; Zhang, Yuanzhong; Huang, Rundong; Min, Younjin. And the article was published in Physical Chemistry Chemical Physics in 2019. Safety of 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate The author mentioned the following in the article:

This work is concerned with investigating the glass transition behavior of ionic liquids as a function of nanoconfinement. The glass transition temperature was found to increase with a decrease in confinement length, below a critical confinement of 40-50 nm and 80-90 nm for 1-butyl-3-methylimidazolium tetrafluoro-borate and 1-methyl-3-octylimidazolium tetrafluoro-borate between alumina surfaces, resp. In the experimental materials used by the author, we found 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6Safety of 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate)

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. Actually, lonic liquids as innovative fluids have received wide attention only during the past two decades. The number of SCI papers published on lonic liquids has exponentially increased from a few in 1996 to >5000 in 2016, exceeding the annual growth rates of other popular scientific areas. Safety of 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

The author of 《Effects of water on ionic liquid electrochemical microsensor for oxygen sensing》 were Liu, Xiaojun; Chen, Xiaoyu; Xu, Yong; Chen, Tongtong; Zeng, Xiangqun. And the article was published in Sensors and Actuators, B: Chemical in 2019. COA of Formula: C8H15BF4N2 The author mentioned the following in the article:

The effect of water on ionic liquid (IL) planar electrochem. microsensor was studied in the case of sensing oxygen. This study compared the key anal. performances of the IL based electrochem. microsensor devices using an IL BmimBF4 direct from the vendor and ‘wet’ BmimBF4 containing different amount of water as electrolytes. The electrochem. properties in [Bmim][BF4] with or without oxygen using a planar microsensor device were characterized by cyclic voltammetry (CV) and electrochem. impedance spectroscopy (EIS). With the increasing of water concentrations in the IL, a pos. shift of redox potential of O2 and a higher reduction current of oxygen in CV measurement were observed The constant potential chronoamperometry measurements were conducted to assess the sensitivity, reproducibility and stability of microsensor at varying O2 concentration using these wet ILs as electrolytes. The short term and long-term stability evaluation of these IL microsensor for sensing oxygen was performed. Our results show that the electrochem. planar microsensor device demonstrates a good sensitivity, reproducibility and stability for sensing oxygen even though the ‘wet’ ILs were used as electrolytes. A remarkable stability of sensor was observed in stability test using as an electrolyte. In the experiment, the researchers used many compounds, for example, 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6COA of Formula: C8H15BF4N2)

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. Actually, lonic liquids as innovative fluids have received wide attention only during the past two decades. The number of SCI papers published on lonic liquids has exponentially increased from a few in 1996 to >5000 in 2016, exceeding the annual growth rates of other popular scientific areas. COA of Formula: C8H15BF4N2

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Chang, Tsun-Mei; Billeck, Stephanie E. published an article in 2021. The article was titled 《Structure, Molecular Interactions, and Dynamics of Aqueous [BMIM][BF4] Mixtures: A Molecular Dynamics Study》, and you may find the article in Journal of Physical Chemistry B.Electric Literature of C8H15BF4N2 The information in the text is summarized as follows:

Mol. dynamics simulations with many-body polarizable force fields were carried out to investigate the thermodn., structural, and dynamic properties of aqueous solutions of 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]). The radial distribution functions exhibit well-defined features, revealing favored structural correlations between [bmim]+, [BF4]-, and H2O. The addition of water is shown to alter ionic liquid structural organizations by replacing counterions in the coordination shells and disrupt the cation-anion network. At low water concentration, the majority of water mols. are isolated from each other and have lower average dipole moment than that in pure water. With increasing hydration level, while [bmim][BF4] ionic network breaks up and becomes isolated ion pairs or free ions in the dilute limit, water begins to form clusters of increasing sizes and eventually forms a percolating network. As a result, the average water dipole moment increases and approaches its bulk value. Water is also observed to have a substantial influence on the dynamics of ionic liquids At low water content, the cation and anion have similar diffusion coefficients due to the correlated ionic motion of long-lived ion pairs. As the water concentration increases, both ions exhibit greater mobility and faster rotations from the breakup of ionic network. Consequently, the ionic conductivity of [bmim][BF4] aqueous solutions rises with increasing water composition In the experiment, the researchers used many compounds, for example, 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6Electric Literature of C8H15BF4N2)

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. Actually, lonic liquids as innovative fluids have received wide attention only during the past two decades. The number of SCI papers published on lonic liquids has exponentially increased from a few in 1996 to >5000 in 2016, exceeding the annual growth rates of other popular scientific areas. Electric Literature of C8H15BF4N2

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

In 2019,Journal of Molecular Liquids included an article by Yoshimura, Yukihiro; Mori, Takahiro; Kaneko, Kazuyoshi; Nogami, Koji; Takekiyo, Takahiro; Masuda, Yuichi; Shimizu, Akio. Recommanded Product: 174501-65-6. The article was titled 《Confirmation of local water structure confined in ionic liquids using H/D exchange》. The information in the text is summarized as follows:

We investigated the local structure of water mols. confined inside ionic liquid (IL) nanodomain structures of 1-butyl-3-methylimidazolium tetrafluoroborate, (abbreviated as [bmim][BF4]) using NMR and Raman spectroscopy to monitor H/D exchange reaction between H2O and D2O water mols. The results showed that fewer than 5 water mols. were probably present in the water domain of the IL nanospace at less than ∼60 water mol%, where the translational motion of water mols. was inhibited and proton exchange rate was highly restricted. These phenomena were attributed to the absence of bulk hydrogen-bonded network structures in the water domain. The H atoms of the HDO mol. tended to interact with BF-4 anions, whereas the D atoms of HDO interacted with the C2 atoms of the bmim+ cation. As a result, water mols. became trapped inside the IL framework, which is likely to be the main cause of the reduction in H/D exchange rate among water mols. in the mixture3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6Recommanded Product: 174501-65-6) was used in this study.

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. A multidisciplinary study on lonic liquids is emerging, including chemistry, materials science, chemical engineering, and environmental science. More specifically, some important fundamental viewpoints are now different from the original concepts, as insights into the nature of lonic liquids become deeper. For example, the physicochemical properties of lonic liquids are now recognized as ranging broadly from the oft quoted “nonvolatile, non-flammable, and air and water stable” to those that are distinctly volatile, flammable, and unstable. Recommanded Product: 174501-65-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

《Role of image charges in ionic liquid confined between metallic interfaces》 was published in Physical Chemistry Chemical Physics in 2020. These research results belong to Ntim, Samuel; Sulpizi, Marialore. Category: imidazoles-derivatives The article mentions the following:

The peculiar properties of ionic liquids in confinement have not only become essential for energy storage, catalysis and tribol., but still pose fundamental questions. Recently, an anomalous liquid-solid phase transition has been observed in at. force microscopy experiments for 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]), the transition being more pronounced for metallic surfaces. Image charges have been suggested as the key element driving the anomalous freezing. Using atomistic mol. dynamics simulations, we investigate the impact of image charges on structure, dynamics and thermodn. of [BMIM][BF4] confined between gold electrodes. Our results not only unveil a minor role played by the metal polarisation, but also provide a novel description of the interfacial layer. Although no diffuse layer can be defined in terms of the electrostatic potential, long range effects are clearly visible in the dynamical properties up to 10 nm away from the surface, and are expected to influence viscous forces in the experiments In the experiment, the researchers used many compounds, for example, 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6Category: imidazoles-derivatives)

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. A multidisciplinary study on lonic liquids is emerging, including chemistry, materials science, chemical engineering, and environmental science. More specifically, some important fundamental viewpoints are now different from the original concepts, as insights into the nature of lonic liquids become deeper. For example, the physicochemical properties of lonic liquids are now recognized as ranging broadly from the oft quoted “nonvolatile, non-flammable, and air and water stable” to those that are distinctly volatile, flammable, and unstable. Category: imidazoles-derivatives

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

In 2022,Bottari, Cettina; Almasy, Laszlo; Rossi, Barbara; Bracco, Brenda; Paolantoni, Marco; Mele, Andrea published an article in Journal of Physical Chemistry B. The title of the article was 《Interfacial Water and Microheterogeneity in Aqueous Solutions of Ionic Liquids》.SDS of cas: 174501-65-6 The author mentioned the following in the article:

In this work, aqueous solutions of two prototypical ionic liquids (ILs), [BMIM][BF4] and [BMIM][TfO], were investigated by UV Raman spectroscopy and small-angle neutron scattering (SANS) in the water-rich domain, where strong heterogeneities at mesoscopic length scales (microheterogeneity) were expected. Analyzing Raman data by a differential method, the solute-correlated (SC) spectrum was extracted from the OH stretching profiles, emphasizing specific hydration features of the anions. SC-UV Raman spectra pointed out the mol. structuring of the interfacial water in these microheterogeneous IL/water mixtures, in which IL aggregates coexist with bulk water domains. The organization of the interfacial water differs for the [BMIM][BF4] and [BMIM][TfO] solutions, being affected by specific anion-water interactions. In particular, in the case of [BMIM][BF4], which forms weaker H-bonds with water, the aggregation properties clearly depend on concentration, as reflected by local changes in the interfacial water. On the other hand, stronger water-anion hydrogen bonds and more persistent hydration layers were observed for [BMIM][TfO], which likely prevent changes in IL aggregates. The modeling of SANS profiles, extended to [BPy][BF4] and [BPy][TfO], evidences the occurrence of significant concentration fluctuations for all of the systems: this appears as a rather general phenomenon that can be ascribed to the presence of IL aggregation, mainly induced by (cation-driven) hydrophobic interactions. Nevertheless, larger concentration fluctuations were observed for [BMIM][BF4], suggesting that anion-water interactions are relevant in modulating the microheterogeneity of the mixture In the experiment, the researchers used 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6SDS of cas: 174501-65-6)

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. Actually, lonic liquids as innovative fluids have received wide attention only during the past two decades. The number of SCI papers published on lonic liquids has exponentially increased from a few in 1996 to >5000 in 2016, exceeding the annual growth rates of other popular scientific areas. SDS of cas: 174501-65-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

The author of 《Fluorescent probe dependence of the solvation dynamics in ionic liquid BmimBF4 and propylene carbonate mixtures: a time-resolved fluorescence and quantum chemistry study》 were Smortsova, Yevheniia; Miannay, Francois-Alexandre; Koverga, Volodymyr; Dubois, Julien; Kalugin, Oleg; Idrissi, Abdenacer. And the article was published in Journal of Molecular Liquids in 2019. Recommanded Product: 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate The author mentioned the following in the article:

In this work, steady-state and time-resolved fluorescence experiments on solvation of C153, C102, 4-ANMP and PRODAN fluorescent probes in BmimBF4 and BmimBF4/PC mixtures with a molar fraction of ionic liquid equal to 0.65 and 0.85 are reported. Quantum Chem. calculations were performed to complete the exptl. data interpretation. All the four studied probes exhibit similar solvation dynamics, with their average solvation times following the trend 4-ANMP < C153 ≡ C102 < PRODAN. A specific interactions hypothesis was put forward to explain the slight divergence of 4-ANMP and PRODAN spectra shift. The C153 mol., showing a big change in dipole moment (8.7 D) upon the photoexcitation, little geometry relaxation upon the excitation due to its rigid structure, small change in dipole moment orientation and relatively small hydrogen bonding ability is thus proved to be the most adequate for use in the study of the solvation dynamics in various environments, including ionic liquids and ionic liquid/mol. solvent mixtures The results came from multiple reactions, including the reaction of 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6Recommanded Product: 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate)

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. A multidisciplinary study on lonic liquids is emerging, including chemistry, materials science, chemical engineering, and environmental science. More specifically, some important fundamental viewpoints are now different from the original concepts, as insights into the nature of lonic liquids become deeper. For example, the physicochemical properties of lonic liquids are now recognized as ranging broadly from the oft quoted “nonvolatile, non-flammable, and air and water stable” to those that are distinctly volatile, flammable, and unstable. Recommanded Product: 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

《The effect of nanoscale friction of mesoporous carbon supported ionic liquids on the mass transfer of CO2 adsorption》 was published in Physical Chemistry Chemical Physics in 2020. These research results belong to Fan, Pengpeng; Qiu, Xiuhua; Shah, Faiz Ullah; Ji, Qingmin; An, Rong. SDS of cas: 174501-65-6 The article mentions the following:

Supported ionic liquids (ILs) are attractive alternatives for CO2 capture and the thickness of supported IL films plays a critical role in the CO2 mass transfer rate. However, the dependence of CO2 uptake on the IL film thickness differs as the system varies. In this work, at. force microscopy (AFM) is employed to probe the ‘nanofriction coefficient’ to characterize the mobility of ILs at the solid interface, in which, the smaller the nanofriction coefficient, the faster are the ionic mobility and CO2 mass transfer. A monotonic and almost linear relationship for supported IL films is obtained between the resistance of CO2 mass transfer (1/k) and the nanofriction coefficient (μ), avoiding the controversy over the effect of supported IL film thickness on CO2 adsorption. The enhanced mass transfer of CO2 adsorption at IL-solid interfaces is observed at smaller resistance 1/k and friction coefficient μ. The low-friction driven local mobility (diffusion) of ILs at solid interfaces is enhanced, promoting the exchange mixing of the ILs adsorbing CO2 with the ‘blank-clean’ ions of the ILs, and thus accelerating the CO2 mass transfer. The proposed correlation links the nanoscale friction with the mass transfer of CO2 adsorption, providing a fresh view on the design of ultra-low frictional supported ILs for enhanced CO2 capture and separation processes. In the experimental materials used by the author, we found 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6SDS of cas: 174501-65-6)

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. A multidisciplinary study on lonic liquids is emerging, including chemistry, materials science, chemical engineering, and environmental science. More specifically, some important fundamental viewpoints are now different from the original concepts, as insights into the nature of lonic liquids become deeper. For example, the physicochemical properties of lonic liquids are now recognized as ranging broadly from the oft quoted “nonvolatile, non-flammable, and air and water stable” to those that are distinctly volatile, flammable, and unstable. SDS of cas: 174501-65-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

The author of 《Molecular Mobility in a Set of Imidazolium-Based Ionic Liquids [bmim]+A- by the NMR-Relaxation Method》 were Bystrov, Sergei S.; Matveev, Vladimir V.; Chernyshev, Yurii S.; Balevicius, Vytautas; Chizhik, Vladimir I.. And the article was published in Journal of Physical Chemistry B in 2019. Application In Synthesis of 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate The author mentioned the following in the article:

The detailed investigation of the local mobility in a set of dried imidazolium-based ionic liquids (1-butyl-3-methylimidazolium) in a wide temperature range and varying anions (BF4-, I-, Cl-, Br-, NO3-, TfO-) is presented. The measurements of temperature dependencies of the spin-lattice relaxation times of 1H and 13C nuclei are motivated by the need to obtain a fundamental characterization of mol. mobility of the substances under study, namely, to estimate the correlation times, τc, for the motion of individual mol. groups. In particular, it follows from obtained results that the mobility of the hydrocarbon “”tail”” is higher (smaller τc) than that of the imidazole ring, and this expected tendency is quantified. The effect of the influence of an anion type on the cation mobility is also analyzed. In the part of experimental materials, we found many familiar compounds, such as 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6Application In Synthesis of 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate)

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. Actually, lonic liquids as innovative fluids have received wide attention only during the past two decades. The number of SCI papers published on lonic liquids has exponentially increased from a few in 1996 to >5000 in 2016, exceeding the annual growth rates of other popular scientific areas. Application In Synthesis of 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Related Products of 174501-65-6In 2019 ,《Understanding the Properties of Ionic Liquids: Electrostatics, Structure Factors, and Their Sum Rules》 appeared in Journal of Physical Chemistry B. The author of the article were McDaniel, Jesse G.; Yethiraj, Arun. The article conveys some information:

The properties of room-temperature ionic liquids (ILs) may be viewed as resulting from a balance of electrostatic interactions that can be tuned at short range but constrained to satisfy universal, asymptotic screening conditions. Short-range interactions and ion packing provide ample opportunity for chem. tunability, while asymptotic sum rules dictate that the long-range structure and charge oscillation be similar to those of molten alkali halide salts. In this work, we study the structure factors and long-range electrostatic interactions in six ILs. The cation in all cases is 1-butyl-3-methylimidazolium (BMIM+), and we study six anions, namely, tetrafluoroborate (BF4-), hexafluorophosphate (PF6-), nitrate (NO3-), triflate (CF3SO3-), bisfluorosulfonylimide [(FSO2)2N-], and bistriflimide [(CF3SO2)2N-]. To gain insight, we perform similar computer simulations of a primitive molten salt model with and without electronic polarization. We emphasize universal similarities among ionic liquids and molten salts in the long-range ion ordering and the influence of electronic polarization on the screening conditions while also characterizing important differences in the short-range electrostatic interactions. We show that polarization systematically reduces charge oscillations by as much as ∼0.5-1 ion per radial shell, which we argue is general to all room-temperature ILs as well as molten salts. We suggest that a fundamentally important distinction among BMIM-based ionic liquids (with different anions) is the nature of the midrange, ∼1 Å-1 peak in the charge-correlation structure factor; while this correlation is straightforward to analyze in computer simulations, it may often be hidden in x-ray and/or neutron scattering structure factors. The experimental process involved the reaction of 3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6Related Products of 174501-65-6)

3-Butyl-1-methyl-1H-imidazol-3-ium tetrafluoroborate(cas: 174501-65-6) is a member of lonic liquids. Actually, lonic liquids as innovative fluids have received wide attention only during the past two decades. The number of SCI papers published on lonic liquids has exponentially increased from a few in 1996 to >5000 in 2016, exceeding the annual growth rates of other popular scientific areas. Related Products of 174501-65-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem