Category: 1374155-84-6

Highly selective, sensitive and stable three-dimensional luminescent metal-organic framework for detecting and removing of the antibiotic in aqueous solution was written by Wu, Ruixue;Bi, Caifeng;Zhang, Dongmei;Fan, Chuanbin;Wang, Lulu;Zhu, Bin;Liu, Wenbo;Li, Nana;Zhang, Xia;Fan, Yuhua. And the article was included in Microchemical Journal in 2020.Name: 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:

An efficiently selective sensor for aquatic antibiotic detection based on a photoluminescent cadmium metal-organic framework (Cd-MOF) is researched in this work. The novel and simple luminescent MOF that composed from aπ-electron rich ligand bip (3,5-bis(1-imidazol) pyridine) and H₃L (2-nitro-5-(4-carboxy-2-nitrophenoxy) isophthalic) was synthesized in hydrothermal condition and characterized. Single crystal X-ray diffraction anal. demonstrated that it had an uncommon 2-nodal (3,6)-connected 3D framework with a (3²·4)(3⁴·4⁶·5³·6²) topol., which could be formulated as [{[Cd₂(HL)₂(bip)₂]·H₂O}_n]. Benefiting from its unique framework, [{[Cd₂(HL)₂(bip)₂]·H₂O}_n] can not only respond to the trace quantity of chloramphenicol (CHL) via fluorescence quenching but also show good adsorption capability toward CHL in aqueous solution The selective response to CHL reached up to the ppb level with high anti-interference ability in aqueous phase, and the effective detection of antibiotics had been theorized by D. Functional Theory (DFT) calculation for energy bands of H₃L and antibiotics, which revealed that the cooperation influence on photo-induced electron transfer (PET) process and fluorescence inner filter effect (IFE) made CHL show more sensitive luminescence responses than other exptl. antibiotics. Moreover, because of its specific interactions with analytes and relatively high porosity, the pre-enrichment makes the antibiotic fuller contact and interact with the framework, which improves the overall sensing efficiency toward CHL appreciably. Stemming from the abuse, antibiotics have been considered as the great threat to the health of human race and the sustainable development of society. Therefore, it is extremely important to achieve new technol. to detect and absorb antibiotics residues in water. This work proves that metal-organic framework complexes can conform the performance of detecting and removing antibiotic in aqueous environment, that emphasizes the application of luminescent MOFs in contaminant monitoring and removing. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Name: 3,5-Di(1H-imidazol-1-yl)pyridine).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Name: 3,5-Di(1H-imidazol-1-yl)pyridine

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Isopolymolybdate-Based Cobalt/Nickel Coordination Polymers Constructed by V-Type N-Donor Ligands was written by Shi, Ya-Jie;Chen, Lin-Lin;Liu, Ying;Wu, Ying-Ying;Li, Ya-Min;Dang, Dong-Bin;Bai, Yan. And the article was included in Inorganic Chemistry in 2021.Formula: C11H9N5 The following contents are mentioned in the article:

Four novel isopolymolybdate-based coordination polymers (CPs), constructed from 2,6-bis(1,2,4-triazol-1-yl)pyridine (btp), 1,3-bis(4H-1,2,4-triazol-4-yl)benzene (btb), and 3,5-bis(1-imidazolium)pyridine (bip), have been synthesized under a hydrothermal method: {[Co(btp)(H₂O)₂(β-Mo₈O₂₆)_0.5]·3H₂O}_n (1), [Ni(btp)(H₄Mo₆O₂₂)_0.5]_n (2), [Co(btb)(H₂O)(β-Mo₈O₂₆)_0.5]_n (3), and {[Co(Hbip)₂(H₂O)₂(γ-Mo₈O₂₆)]·6H₂O}_n (4). Complex 1 exhibits one 3D framework with an unexpected 3-nodal 2,4,6-c net topol. containing the 1D {β-Mo₈O₂₆}_n chains, 6-connected Co^II centers, and V-type coordinated btp ligands. The neighboring [Mo₆O₂₂]^4- anions of complex 2 are bridged by the Ni^II centers to build one 2D {Ni₂(Mo₆O₂₂)} network, which is arranged into the 3D framework through the weak π···π stacking interactions. In compound 3, one 3D framework is formed by the adjacent 1D {Co₂(btp)₂}_n chains connected by {β-Mo₈O₂₆}_n units, which demonstrates a rare 4,6-c fsc topol. In complex 4, one 2D {Co(Hbip)₂(γ-Mo₈O₂₆)} layer with a (4, 4) network is connected to one 3D hydrogen-bonding framework via N-H···O and O-H···O hydrogen bonds. Magnetic data indicate that complexes 1 and 4 exhibit antiferromagnetic behaviors, whereas complexes 2 and 3 reveal spin-canting magnetic behavior and metamagnetic behavior, resp. In addition, the proton conductivity of complexes 3 and 4 was investigated, showing that compound 4 has good proton conductivity at 85° and a relative humidity of 98% RH. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Formula: C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Formula: C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem