Category: 1374155-84-6

Experimental and theoretical study of bifunctional electro-catalysts constructed from different Polyoxometalates and Ag-bimpy segments was written by Zheng, Yanping;Zhou, Wanli;Liu, Xuekun;Yuan, Gang;Peng, Jun. And the article was included in Electrochimica Acta in 2021.Application of 1374155-84-6 The following contents are mentioned in the article:

In this work, upon subtle POMs variation, we reported on the assembly and performances of three new bimetallic component organic-inorganic hybrids, [Ag₂(bimpy)(V^V₂O₆)](1), [Ag₃(bimpy)₂(β-Mo^VI₈O₂₆)](2), [Ag₄(bimpy)₂(H₂O)₂(α-SiW^VI₁₂O₄₀)]â€?H₂O (3) (bimpy = 3,5-bis(1-imidazoly) pyridine). Compound 1 with 3D framework structure is featured by {-V-O-V-}n helical chains, {Ag₃} clusters and {bimpy-Ag-bimpy} units. Compound 2 has a 3,3,6,6-connected 3D architecture with the (4³)(4³)(4²â€?⁹â€?â€?³)(4⁶â€?²â€?⁴â€?â€?²) topol. Compound 3 has a 3,3,4-connected 2D layer with (6²â€?)(6²â€?)(6⁶) topol. The electrochem. and bifunctional electro-catalytic activities of three compounds have been conducted. The exptl. results show that β-[Mo₈O₂₆]^4- hybrid displays better electrocatalytic performance than [V₂O₆]^2- and Keggin-type hybrids for reduction of nitrite, while [V₂O₆]^2- hybrid exhibits better electrocatalytic activity than β-[Mo₈O₂₆]^4- and Keggin hybrids towards oxidations of ascorbic acid. Furthermore, the mol. electrostatic potential and frontier MO were performed. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Application of 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Application of 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Coordination polymers constructed by diverse metal centers and the rigid ligand 3,5-di(1H-imidazol-1-yl)pyridine. Synthesis, structure and properties was written by Luo, Li;Zhao, Yue;Lu, Yi;Okamura, Taka-aki;Sun, Wei-Yin. And the article was included in Polyhedron in 2012.COA of Formula: C11H9N5 The following contents are mentioned in the article:

Six new coordination polymers, [Cu(L)₂(H₂O)₂](NO₃)₂ (I), [Cu(L)₂](ClO₄)₂ (II), [Cd(L)₂(H₂O)₂](ClO₄)₂ (III), [Cd(L)(OAc)₂(H₂O)] (IV), [Cu₃(L)₄(H₂O)₂(SO₄)](SO₄)₂.30H₂O (V), and [Ni(L)(H₂O)₃(SO₄)] (VI) [L = 3,5-di(1H-imidazol-1-yl)pyridine, OAc^– = MeCOO^–], were prepared and characterized by x-ray diffraction, IR, elemental and thermogravimetric analyses. Complexes I, IV, and VI have different 1D chain structures, while II and III are 2D networks. The chains and layers are further linked together by H-bonds to generate 3D frameworks. Complex V is a (3,4,4)-connected 3D framework with a Point (Schlaefli) symbol of (4.8²)₄(4.8³.10²)₂(4².8².10²). The influences of the coordination modes of the ligand L, metal center as well as the counteranion on the structures of the complexes are discussed. Furthermore, the reversible anion exchange property of III and the photoluminescence properties of III and IV were investigated. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6COA of Formula: C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.COA of Formula: C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Mn(II)/Co(II)-based metal-organic frameworks assembled by 5,5′-(1,4-xylylenediamino) diisophthalic acid and various nitrogen-containing ligands for photocatalytic and magnetic properties was written by Xu, Cungang;Luo, Rong;Zhang, Dongmei;Zhang, Xia;Zong, Ziao;Fan, Chuanbin;Zhu, Bin;Fan, Yuhua. And the article was included in Journal of Solid State Chemistry in 2021.Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:

Three novel Mn(II)/Co(II)-based 3D metal-organic frameworks (MOFs), namely {[Mn₂(L)(tib)(H₂O)]·3DMA·4H₂O}_n (1), {[Co₂(L)(bipd)₂]·3H₂O}_n (2) and {[Co(L)_0.5(bimb)]·3H₂O·0.5O₂}_n (3) (H₄L = 5,5′-(1,4-xylylenediamino)diisophthalic acid, tib = 1,3,5-tris(1-imidazolyl)benzene, bipd = 3,5-bis(1-imidazoly)pyridine, and bimb = 1,4-bis(lmidazol)-butane), have been successfully synthesized using the mixed-ligand as functionalized organic linker. The structural characterization revealed that both MOFs 1 and 2 exhibited an unprecedented 4-nodal 3D framework that enriching crystal engineering, while MOF 3 featured a 2-nodal three-interpenetrating bbf topol. framework with a Schlafli symbol of (6⁴·8²)(6⁶)₂. The title MOFs have been exploited as photocatalysts for degradation of methylene blue (MB), methyl violet (MV) and malachite green (MG). The photocatalytic results demonstrated that MOFs 2 and 3 exhibited efficient photocatalytic abilities to degrade the three aromatic dyes under UV irradiation The possible catalytic mechanism was also explored and discussed in detail. Moreover, the variable-temperature magnetic analyses indicated that MOFs 1–3 exhibited weak antiferromagnetic behavior between Mn(II)/Co(II) ions. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Synthesis, structure and electrochemical properties of metal cobalt complexes with interpenetrating structures was written by Zhao, Changjiang;Liu, Xin;Tian, Li;Zhao, Lun. And the article was included in Gaodeng Xuexiao Huaxue Xuebao in 2018.Quality Control of 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:

Using multidenate 4,4′-(phenylazanediyl)dibenzoic acid (H₂L) and 1,3-bis(imidazol-1-yl)benzene (B), 3,5-bis(imidazol-1-yl)pyridine (bimp) or 1,4-bis(imidazol-1-yl)benzene (B’) as ligands under solvothermal conditions, three new metal-organic frameworks with interpenetrating structure, {[CoLB]·H₂O}_n (1), {[Co₂L₂(bimp)_0.5]·3H₂O}_n (2) and {[Co₂L₂B’₂]·2DMF}_n (3), were synthesized. The complexes were characterized by single-crystal X-ray diffraction (XRD), thermal anal. and powder X-ray diffraction (PXRD). Complexes 1–3 all crystallize in the monoclinic system, with C2/c(complex 1), P2/n(complex 2) and P2₁(complex 3) space group, resp. In complexes 1 and 3, Co²⁺ forms a tetracoordinate geometry, whereas it forms a five-coordinated geometric configuration and exists as a dual-core paddle-shaped structural unit [Co₂(CO₂)₄] in complex 2. Complexes 1 and 2 give a 2-fold interpenetrating three-dimensional (3D) supramol. networks, while complex 3 exhibits a 4-fold interpenetrating 3D framework. The results of electrochem. studies show that complexes 1–3 are electrochem. active substances with good electrochem. reversibility. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Quality Control of 3,5-Di(1H-imidazol-1-yl)pyridine).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Quality Control of 3,5-Di(1H-imidazol-1-yl)pyridine

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Rational design and construction of a serious of highly water-stable coordination polymers with various N,N’-donor linkers: Syntheses, diversity structures, and dye adsorption property was written by Fan, Chuanbin;Xu, Cungang;Zong, Ziao;Zhang, Xiaoyin;Zhu, Bin;Wang, Lulu;Zhang, Xia;Bi, Shuangyu;Fan, Yuhua. And the article was included in Journal of Solid State Chemistry in 2020.Electric Literature of C11H9N5 The following contents are mentioned in the article:

In this study, authors have synthesized six new coordination polymers (CPs), namely {[Cu₆(3,5-bip)₆(H₂O)₁₂(SO₄)₆]·3H₂O}_n (1), [Co(3,5-bip)(H₂O)₃(SO₄)]_n (2), {[Cu(1,3-bit)₂(H₂O)₂]·2(NO₃)}_n (3), {[Cu₂(1,3-bit)₂(1,3-bcbb)₂]·4(H₂O)}_n (4), [Cu(4,4′-bibp) (H₂O)(NO₃)₂]_n (5), [Cu(4,4′-bibp)(4,4′-Hsbdc)]_n (6) via solvothermal methods. The structures of these new CPs have been characterized by elemental anal., FTIR, TG anal., PXRD and single crystal x-ray diffraction techniques. Meanwhile, the title CPs are explored for adsorption of organic dyes, i.e., anionic dyes (congo red (CR), and methyl orange (MO)) and cationic dye (methylene blue (MB)) considered extensively as water colorants pollutants. Worth noting, complex 3 can adsorb anionic dyes (CR and MO) quickly; complex 6 shows great performance in CR adsorption. Kinetic study reveals that the adsorption process is performed via pseudo-second-order reaction. The dye removal investigations of complexes 3 and 6 support that ions exchange and H-bonding interactions between CPs and target organic dyes are significant factors, heavily affecting dye adsorption. They have excellent potential in wastewater treatment. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Electric Literature of C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Electric Literature of C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Zinc(II) and cadmium(II) coordination polymers with various polynuclears spaced by semirigid 4-carboxybenzeneacetate and nitrogen-rich co-ligands: syntheses, structures and properties was written by Ju, Feng-yang;Li, Yun-ping;Li, Gui-lian;Liu, Guang-zhen;Xin, Ling-yun;Li, Xiao-ling. And the article was included in Wuji Huaxue Xuebao in 2016.Electric Literature of C11H9N5 The following contents are mentioned in the article:

A series of four Zn(II)/Cd(II) coordination polymers, {[Zn(cbaa)(bpmp)_0.5(H₂O)]·2H₂O}_n (1), [Zn(cbaa)(bip)]_n (2), [Cd(cbaa)(Hizb)]_n (3) and [Cd₂(cbaa)₂(itmb)(H₂O)]_n (4) have been obtained by the solvothermal reaction of Zn(II)/Cd(II) acetate with semirigid 4-carboxybenzeneacetic acid (H₂cbaa) and co-ligands, 1,4-bis(4-pyridyl-methyl)piperazine (bpmp), 3,5-bis(1-imidazolyl)pyridine (bip), 2-(4-imidazol-l-yl-phenyl)-1H-benzimidazole (Hizb) and 1-(imidazo-1-ly)-4-(1,2,4-triazol-1-yl-methyl)benzene (itmb). The single-crystal x-ray diffraction analyses show that four compounds feature various polynuclears spaced by 4-carboxybenzeneacetate and N-rich co-ligands and display various topol. structures. Two zinc complexes are 1D ladder featuring Zn-carboxylate chains linked further by bpmp co-ligands for 1 and 2D monolayer containing Zn-carboxylate chains cross-linked further by bip co-ligands for 2, resp. And two cadmium complexes exhibit 2D monolayer featuring Cd-O inorganic chains cross-linked further by cbaa carboxylates with Hizb co-ligands acting as pendent arms for 3 and 2D dense bilayer containing Cd-carboxylate open bilayer with itmb co-ligands encapsulated within the cavities for 4, resp. The fluorescent properties and thermal stabilities of all these compounds have been investigated. CCDC: 906895, 1; 1443786, 2; 906897, 3; 906898, 4. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Electric Literature of C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Electric Literature of C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Syntheses, structures and fluorescent properties of cadmium coordination polymers based on 2,3′,5,5′-biphenyl tetracarboxylate and N-donor ancillary ligands was written by Chang, Xin-Hong;Zhao, Ying;Feng, Xun;Ma, Lu-Fang;Wang, Li-Ya. And the article was included in Polyhedron in 2014.Product Details of 1374155-84-6 The following contents are mentioned in the article:

Self-assembly of cadmium(II) salt based on 2,3′,5,5′-biphenyl tetracarboxylate with or without various N-donor ligands affords a series of coordination polymers, namely {[Cd_1.5(Hbptc)(H₂O)_4.5]·2H₂O}_n (1), {[Cd₂(bptc)(2,2′-bipy)₂]·2H₂O}_n (2), {[Cd₂(bptc)(pyp)₂(H₂O)₂]}_n (3), [Cd(H₃bptc)₂(bip)₂]_n (4), and {[Cd₂(bptc)(bpt)(H₂O)]·H₂O}_n (5), where H₄bptc = 2,3′,5,5′-biphenyl tetracarboxylic acid, 2,2′-bipy = 2,2′-bipyridine, pyp = 3-(pyridin-2-yl)pyrazole, bip = 3,5-bis(1-imidazol)pyridine, bpt = 2-[3-(4-pyridinyl)-1H-1,2,4-triazol-5-yl]pyrazine. Their structures were determined by single-crystal x-ray diffraction anal. and further characterized by elemental anal. and IR spectra. Complex 1 shows a 2D helical layer, which is further extended to a 3D supermol. network through inter-layer C-H···O hydrogen bonds and π···π stacking interactions. Complex 2 exhibits a (3,6)-connected (4³)₂(4⁶.6⁶.8³)-kgd topol. Complex 3 possesses a 2D (3,5)-connected (4.5.6)(4.5³.6⁴.7²) net based on 1D tube-like chains. Complex 4 has a 1D polymeric ribbon containing left- and right-handed helical chains, which are further hydrogen bonded to form a 2D supermol. layer. Complex 5 possesses a 3D (4,5,7)-connected framework. Moreover, the fluorescent properties of 1–5 in the solid state have been investigated. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Product Details of 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Product Details of 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

The structural diversity and photoluminescent properties of cadmium thiophenedicarboxylate coordination polymers was written by Xue, Li-Ping;Chang, Xin-Hong;Li, Shi-Hui;Ma, Lu-Fang;Wang, Li-Ya. And the article was included in Dalton Transactions in 2014.Formula: C11H9N5 The following contents are mentioned in the article:

Two series of Cd(II) coordination polymers (CPs), {[Cd(bimm)₂(H₂O)₂][(3,4-tdc)₂][H₂O]₂}_n (1a), [Cd(3,4-tdc)(bimb)]_n (2a), [Cd(3,4-tdc)(bimpy)(H₂O)]_n (3a) and [Cd(2,3-Htdc)₂(bimm)₂]_n (1b), {[Cd(2,3-tdc)(bimb)](H₂O)}_n (2b), [Cd(2,3-tdc)(bimpy)(H₂O)]_n (3b) where H₂tdc = thiophenedicarboxylic acid, bimm = 1,2-bis(imidazol-1′-yl)methane, bimb = 1,2-bis(imidazol-1′-yl)butane and bimpy = 3,5-bis(imidazol-1′-yl)pyridine, have been synthesized by using Cd(II) acetate with H₂tdc and N-donor ligands under hydrothermal conditions. Two related isomeric thiophenedicarboxylic acids were chosen to examine the positional isomeric effect on the construction of these CPs with distinct dimensionality and connectivity. The structure of 1a is a one-dimensional (1D) cationic double chain further forming a two-dimensional (2D) supramol. network via hydrogen-bonding interactions, while 1b exhibits a neutral double chain structure. A three-dimensional (3D) 4-connected cds network for 2a as well as a 1D neutral double chain structure for 2b were obtained in the presence of bimb. When the rigid tripodal bimpy was introduced, isomorphous 3a and 3b with 3D (3,5)-connected (6²·8) (6⁷·8³) nets were constructed. The structural diversity of 1a–2b mainly stems from the positional isomeric effect of thiophenedicarboxylate, while 3a and 3b are well regulated by rigid bimpy. Moreover, the thermal stability and photoluminescence of 1a–3b are investigated. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Formula: C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Formula: C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Large Conjugated Bis/Triimidazolium Derivatives Directed Iodobismuthates(III): Syntheses, Structures, and Visible-Light-Induced Photocatalytic Properties was written by Li, Fu-Ying;Wen, Xuan;Xue, Zhen-Zhen;Pan, Jie;Wei, Qi;Wei, Li. And the article was included in Crystal Growth & Design in 2022.HPLC of Formula: 1374155-84-6 The following contents are mentioned in the article:

Under the direction of large conjugated organic species, a series of novel iodobismuthates(III), [Me₃BIP][BiI₆] (1, Me₃BIP = N,N’,N”-trimethyl-3,5-bis(imidazole-1-yl)pyridine), [Me₃BIP][Bi₂I₉] (2), [Me₃TIP][Bi₂I₉] (3, Me₃TIP = N,N’,N”-trimethyl-tris[4-(1H-imidazole-1-yl)-phenyl]amine), and [Me₃TIB][Bi₂I₉] (4, Me₃TIB = N,N’,N”-trimethyl-1,3,5-tris(1-imidazolyl)benzene), were synthesized via the solvothermal method. These iodobismuthates display two types of structures: 1 contains a [BiI₆]^3- monometallic unit, and 2–4 possess binuclear [Bi₂I₉]^3- clusters, which are formed by two BiI₆ octahedra via face-sharing. The reactants BIP, TIP, and TIB were in situ transformed into [Me₃BIP]³⁺ in 1 and 2, [Me₃TIP]³⁺ in 3, and [Me₃TIB]³⁺ in 4 through the direct N-methylation reaction. UV-visible spectra analyses imply that all compounds possess potential semiconductor properties with narrow band gaps of 2.14, 2.02, 2.09, and 2.07 eV for 1–4, resp. Compound 3 has high visible-light-driven photocatalytic degradation activity and good recyclability to organic pollutants. Radical trapping experiments combined with theor. calculations show that the conjugated organic cations contribute to the narrow band gaps of the semiconductors, which can efficiently restrain the recombination of photogenerated electron-hole pairs, resulting in a good photocatalytic efficiency and stability under visible-light irradiation It is expected that the work will shed useful insights in exploitation of novel halometallates with narrow energy gaps by employing large conjugated organic templates. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6HPLC of Formula: 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.HPLC of Formula: 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Five Mn(II) Coordination Polymers Based on 2,3′,5,5′-Biphenyl Tetracarboxylic Acid: Syntheses, Structures, and Magnetic Properties was written by Zhao, Ying;Chang, Xin-Hong;Liu, Guang-Zhen;Ma, Lu-Fang;Wang, Li-Ya. And the article was included in Crystal Growth & Design in 2015.Category: imidazoles-derivatives The following contents are mentioned in the article:

Five manganese(II) coordination polymers with 2,3′,5,5′-biphenyl tetracarboxylic acid (H₄bptc) and five N-donor ancillary ligands, {[Mn₂(bptc)(2,2′-bipy)₂]·2H₂O}_n (1), {[Mn₂(H₂bptc)₂(phen)₄]·6H₂O} (2), {[Mn₃(Hbptc)₂(4,4′-bipy)₄(H₂O)₄]·4H₂O}_n (3), {[Mn₂(bptc)(1,4-biyb)₂]}_n (4), and {[Mn₃(Hbptc)₂(biip)₂(H₂O)₂]}_n (5) [2,2′-bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline, 4,4′-bipy = 4,4′-bipyridine, 1,4-biyb = 1,4-bis(imidazol-1-ylmethyl)benzene, biip = 3,5-bis(1-imidazol)pyridine], were synthesized under hydrothermal conditions. Complexes 1–5 were structurally characterized by elemental anal., IR spectra, x-ray single-crystal diffraction, and powder X-ray diffraction (PXRD). Complex 1 exhibits a 2D layered structure with a (3,6)-connected (4³)₂(4⁶.6⁶.8³) topol. Complex 2 shows a 0D structure and further stacks via hydrogen-bonding interactions to give a 3D supramol. architecture. Complex 3 possesses a 3D structure with a 4-connected (4.6³.8²)(4⁴.6²)(4³.6³) topol. Complex 4 displays a 3D structure with a (4,5)-connected (4.5².6.7.8)(5.6⁴.7⁴.8)(4.5².6².7⁴.8) topol. Complex 5 features a 3D structure with a (4,5,6)-connected (4².6⁴)(4³.6⁷)(4².6⁸.7³.8²) topol. Magnetic susceptibility measurements indicate weak antiferromagnetic interactions between the Mn(II) ions in 1, 2, and 4. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Category: imidazoles-derivatives).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Category: imidazoles-derivatives

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem