Category: 1374155-84-6

The structures, photoluminescence and photocatalytic properties of two types of iodocuprate hybrids was written by Lin, Chong-Yang;Zhang, Di;Sun, Xin-Yuan;Wei, Li;Xue, Zhen-Zhen;Pan, Jie;Wang, Guo-Ming. And the article was included in Inorganic Chemistry Communications in 2018.Electric Literature of C11H9N5 The following contents are mentioned in the article:

Two new Cu(I)-iodide clusters driven by 3,5-bis(imidazole-1-yl)pyridine (bip), [(H₂bip)₂Cu₅I₉] (1) and [H₂bip]₂[Cu₃I₇] (2), were prepared via modulating organic/inorganic ratio at room temperature Compound 1 presents a zero-dimensional structure constituting of [Cu₄I₈]^4- and [(H₂bip)₂CuI₂]³⁺ two different subunits. Compound 2 features a discrete [Cu₃I₇]^4- anionic cluster, which is the 1st isolated iodocuprate cluster with protonated bip as structure-directing agent (SDA). The structural diversity of 1 and 2 mainly stems from the distinct role of bip during the crystallization Meanwhile, the reaction ratio here also plays an essential role on the fabrication of two structures. The solid-state luminescence bands of 1 and 2 were studied between 499 and 78 K. Both of them exhibit yellow luminescence, and their intensities increase gradually upon cooling. What is more, photocatalytic properties of 1 and 2 were studied. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Electric Literature of C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Electric Literature of C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Syntheses, characterizations and luminescence properties of four novel coordination polymers based on 4,4′-(phenylazanediyl)dibenzoic acid with two rigid N-donor imidazol ligand was written by Zhao, Changjiang;Zhao, Lun;Zhang, Min. And the article was included in Inorganica Chimica Acta in 2018.HPLC of Formula: 1374155-84-6 The following contents are mentioned in the article:

Four novel coordination polymers (CPs), namely, [ZnL(bimb)]路DMF (1), [ZnL(bimb)]路6(H₂O)_0.5 (2), [ZnL(bimp)_0.5]路3H₂O (3) and [ZnL(bimp)]路7H₂O (4), (H₂L = 4,4′-(phenylazanediyl)dibenzoic acid, bimb = 1,4-bis(imidazol-1-yl)benzene, bimp = 3,5-bis(1-imidazoly)pyridine), were synthesized under hydrothermal conditions with different solvents and decreased temperature rates. Their structures were determined by single-crystal x-ray diffraction analyses and further characterized by IR spectra (IR), elemental analyses, and thermogravimetric analyses (TGA). 1 Exhibits an infinite 4-fold interpenetrated three-dimensional (3D) framework with (6⁶) topol. 2 Displays the 2-dimensional undulated sheets leading to form a 3-dimensional framework with 蟺-蟺 interactions among layers in ABAB fashion. 3 Exhibits an infinite 2-fold interpenetrated 3-dimensional framework with (4¹²路6³) topol. 4 Exhibited 2-dimensional layer with {4²路6³路8} topol. structure. Photoluminescence properties of 1–4 in solid state at ambient temperature were studied, too. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6HPLC of Formula: 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3鈥揅6) is higher than in water and generally decreases with a Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.HPLC of Formula: 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Isomeric Effect on the anticancer Behavior of two Zinc(II) complexes based on 3,5-bis(1-imidazolyl)pyridine: Experimental and Theoretical Approach was written by Zhu, Mingchang;Song, Da;Liu, Ning;Wang, Kehua;Su, Junqi;Xiong, Meng;Zhang, Xi;Xu, Yuang;Gao, Enjun. And the article was included in Applied Organometallic Chemistry in 2019.Name: 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:

Two isomeric Zinc(II) complexes constructed by 3,5-bis(1-imidazolyl)pyridine has been synthesized and characterized by single crystal x-ray diffraction, elemental analyses and IR spectroscopy. The binding mode and ability of complex 1–2 with CT-DNA were studied by UV and fluorescence spectra. The intrinsic binding constant K_b (K_b1 = 2.305 脳 10⁴ M^-1, K_b2 = 3.095 脳 10⁴ M^-1) and the observed association constant K_obs (K_obs1 = 1.523*10⁶ M^-1, K_obs2 = 2.057*10⁶ M^-1) indicated that the insertion ability of complex 2 with CT-DNA is stronger than complex 1. Gel electrophoresis showed that complexes have a good ability to hydrolyze cleavage pBR322 plasmid DNA. The cytotoxicity and apoptosis studies showed that complexes exhibited excellent cytotoxic activity against HeLa cells, especially complex 2 had better growth inhibition than Cisplatin. Mol. docking study simulated the binding model of complexes with DNA (PDB:4av1), showing an imidazole plane of complex 2 can be inserted into a DNA base pair in relative parallel. Both complexes can be used as potential anticancer agents. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Name: 3,5-Di(1H-imidazol-1-yl)pyridine).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Name: 3,5-Di(1H-imidazol-1-yl)pyridine

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Three d¹⁰ coordination polymers assembled from 3,5-bis(imidazole-1-yl)pyridine and different polycarboxylates: Syntheses, structures and luminescence properties was written by Pan, Jie;Zhang, Di;Xue, Zhen-Zhen;Wei, Li;Han, Song-De;Wang, Guo-Ming. And the article was included in Solid State Sciences in 2017.Electric Literature of C11H9N5 The following contents are mentioned in the article:

Three novel Zn(II)/Cd(II) coordination polymers, [Cd₂(bip)₂(m-bdc)₂(H₂O)₂路3H₂O]_n (1), [Zn₂(bip)₂(p-bdc)₂路2.5H₂O]_n (2) and [Zn(bip) (p-bdc)路3H₂O]_n (3), where bip = 3,5-bis(imidazole-1-yl)pyridine, m-H₂bdc = 1,3-benzenedicarboxylic acid, p-H₂bdc = 1,4-benzenedicarboxylic acid, have been successfully synthesized under solvothermal conditions. The linkage of different ligands with Cd(II) ions in compound 1 affords a (3,5)-connected layer. Furthermore, 2D鈫?D parallel polycatenation occurs wherein the layers are polycatenated with the adjacent two parallel layers to form a 3D framework. In 2 and 3, the polycarboxylates act as pillars to combine the metal-bip chains, yielding the layered structures. These 2D networks are extended to the final 3D supramol. architectures by 蟺-蟺 stacking interactions. The results show that bip can act as a versatile building block for the construction of various coordination polymers. Moreover, the fluorescent properties of 1–3 in the solid state at room temperature have been investigated. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Electric Literature of C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole is a heterocyclic compound with a five-membered planar ring. It is amphoteric and highly polar. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Electric Literature of C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Diverse architectures and luminescence properties of three low-dimensional Zn(II)/Cd(II) coordination polymers based on a pyridine-imidazole ligand was written by Wang, Ji-Ping;Su, Bin;Li, Jin-Hua;Wang, Guo-Ming. And the article was included in Inorganic Chemistry Communications in 2018.COA of Formula: C11H9N5 The following contents are mentioned in the article:

Based on a rigid ligand 3,5-bis(imidazole-1-yl)pyridine (bip), three new low-dimensional Zn(II)/Cd(II) coordination polymers Zn(bip)Cl₂ (1), Zn(bip)Cl₂ (2) and [Cd(bip)(p-bdc)_0.5(NO₃)(H₂O)路H₂O]_n (3) (p-H₂bdc = 1,4-benzenedicarboxylic acid) have been successfully obtained. Compounds 1 and 2 both feature zero-dimensional (0D) structures, whose asym. units are the same. The weak 蟺-蟺 stacking arrangement in 1 and 2 is significantly different in mol. orientation, resulting in two entirely different three-dimensional (3D) supramol. structures. Compound 3 was characterized as an infinite one-dimensional (1D) chain structure formed by the linkage of Cd₂(bip)₂ units and linear p-bdc^2- ligands, and is further extended into a 3D supramol. architecture via weak 蟺-蟺 stacking interactions. It can be observed by careful investigation of the two structures that different packing modes in 1 and 2 can afford different networks. The photoluminescence of compounds 1–3 has been investigated in the solid state at ambient temperature This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6COA of Formula: C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.COA of Formula: C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

A series of hybrids with a framework constructed from {-SiW₁₁-Ln-SiW₁₁-}_n chains and {Cu/bimpy} ribbons was written by Zhou, Wanli;Zhang, Zheyu;Peng, Jun;Wang, Xiang;Shi, Zhenyu;Li, Guangzhe. And the article was included in CrystEngComm in 2014.Synthetic Route of C11H9N5 The following contents are mentioned in the article:

This paper reports the preparation and x-ray single crystal structures of five organic-inorganic hybrid compounds with 3D framework, [Cu_2.5(bimpy)₂(H₂O)₂][Ln(H₂O)₃(伪-SiW₁₁O₃₉)]路xH₂O [Ln = Eu^III and x = 3.5 for (1), Ln = Sm^III and x = 2.5 for (2), Ln = Ho^III and x = 3.5 for (3), Ln = Y^III and x = 3.5 for (4), Ln = Ce^III and x = 3 for (5)] (bimpy = 3,5-bis(1-imidazolyl)pyridine). Compounds 1–5 are isostructural, showing a 3D framework featured by {-SiW₁₁-Ln-SiW₁₁-}_n inorganic chains and {Cu/bimpy} metal-organic ribbons stemmed from Cu²⁺ ions and bimpy ligands. The adjacent {Cu/bimpy} ribbons are connected by two antiparallel {-SiW₁₁-Eu-SiW₁₁-}_n chains to create a 2D layer structure, which is extended to a (3,4,4,4,6)-connected 3D framework with (4路7²)(4路6路7³路8)(4²路5³路7)(4²路7²路9²)(4²路5²路6⁷路8³路10) topol. through the Cu-O covalent bonds. The magnetic and electrochem. properties of compounds 1 and 2 have been studied. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Synthetic Route of C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Synthetic Route of C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

A novel copper(I) metal-organic framework as a highly efficient and ultrasensitive electrochemical platform for detection of Hg(II) ions in aqueous solution was written by Wang, Xiao-Qing;Tang, Jing;Ma, Xuehui;Wu, Dan;Yang, Jie. And the article was included in CrystEngComm in 2021.Name: 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:

The selective detection of toxic Hg(II) ions is of great significance for industrial processing and environmental remediation. Herein, a novel copper(I) metal-organic framework [Cu₃Cl₃(bimpy)₃] (1) (bimpy = 3,5-bis(1-imidazolyl)pyridine) was constructed by a solvothermal method. Single-crystal X-ray anal. shows that complex 1 is a 2-fold interpenetrated three-dimensional structure with a tfj topol., exhibiting high thermal stability and water stability. Complex 1 was used to modify a glassy carbon electrode (GCE) for the determination of Hg(II) in 0.1 M phosphate buffer solution (PBS) at pH = 7.0. However, on account of the poor electron-conductive property of complex 1, acetylene black (AB) was introduced into complex 1 to improve its electrochem. sensing activity. The electrochem. sensing property of AB and the complex 1 modified GCE was investigated by cyclic voltammetry and chronoamperometric tests. Under the optimal conditions, AB/complex 1/GCE exhibits a high sensitivity of 16.85 渭A 渭M^-1 cm^-2 and a low limit of detection of 1.01 nM in the wide linear range from 2.0 渭M to 64 渭M. AB/complex 1/GCE could also be applied for detecting Hg(II) ions in tap water and river water. The aptasensor provides a valuable tool with satisfactory anti-interference, reproducibility, repeatability, simple preparation, and satisfactory applicability for the sensing of Hg(II) ions. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Name: 3,5-Di(1H-imidazol-1-yl)pyridine).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3鈥揅6) is higher than in water and generally decreases with a Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Name: 3,5-Di(1H-imidazol-1-yl)pyridine

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

A turn-on luminescent probe for Fe³⁺ and ascorbic acid with logic gate operation based on a zinc(II)-based metal-organic framework was written by Tang, Jing;Feng, Doudou;Yang, Jie;Ma, Xuehui;Wang, Xiao-Qing. And the article was included in New Journal of Chemistry in 2020.SDS of cas: 1374155-84-6 The following contents are mentioned in the article:

A 2D zinc(II)-based metal-organic framework (Zn-MOF) formulated as [Zn(bimpy)(1,4-ndc)]路H₂O (1, bimpy = 3,5-bis(1-imidazolyl)pyridine and 1,4-ndc = 1,4-naphthalenedicarboxylic acid) was synthesized by solvothermal reaction. Complex 1 exhibits high water and pH-independent stability. It can detect Fe³⁺ and ascorbic acid (AA) as a “turn-off” fluorescence probe and a “turn-on” fluorescence probe in aqueous solution with high sensitivity and selectivity, resp. The detection limits of 1 for Fe³⁺ and AA are about 8.82 x 10^-7 M and 6.12 x 10^-7 M, resp. The fluorescence intensity of the Fe³⁺@1 system can be obviously recovered after adding AA due to the reduction of Fe³⁺, which exhibits a fluorescence “turn-on” signal (turn-off-on) for Fe³⁺@1 toward AA with a low detection limit (3.53 x 10^-7 M). Complex 1 still exhibits good detection of Fe³⁺ and AA after washing and using for five cycles. Addnl., two different multi-input mol. logic gates are established. One is used to distinguish the effect of Fe³⁺ and Fe²⁺ on the fluorescence of complex 1, and the other is to further explain the regulation of Fe³⁺ and AA on the fluorescence of complex 1. This work shows that complex 1 is the first MOF-based “turn-on” fluorescent probe for both Fe³⁺ and AA in aqueous solution This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6SDS of cas: 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.SDS of cas: 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

A ‘two-in-one’ crystal having two different dimensionality in the extended structures: A series of cadmium(II) coordination polymers from V-shaped organic linkers was written by Ramathulasamma, Mukara;Bommakanti, Suresh;Das, Samar K.. And the article was included in Polyhedron in 2021.Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:

Three Cd(II) containing coordination polymers, formulated as {Cd(oba)(biip)}_n路nH₂O (1), {Cd(sdba)(biip)}_n路n5H₂O (2) and {[Cd_1.5(hfipbb)₂(biip)_1.5(H₂O)][Cd(hfipbb)(biip)]}_n路n2H₂O (3), were synthesized by using ditopic V-shaped ligands i.e., H₂oba (4,4′-oxydibenzoic acid), H₂sdba (4,4′-thiodibenzoic acid), H₂hfipbb {4,4′-(perfluoropropane-2,2-diyl)dibenzoic acid} and an auxiliary linker, biip [3,5-di(1H-imidazol-1-yl)pyridine] under solvothermal conditions. Compounds 1–3 are characterized by single crystal X-ray diffraction anal., IR spectroscopy, thermogravimetric (TG) and elemental analyses. Compound 1 contains a 3D framework, formed by the connectivity of {CdO₄N₂} secondary building unit (SBU) with the organic linkers, whereas compound 2 is a 2D coordination polymer. Interestingly, unlike to compounds 1 and 2, compound 3 possesses a distinctive structural feature having two crystallog. independent polymeric motifs (polymers, A and B) having two different dimensionality within the same crystal, i.e., coordination polymer A (CP-A) that forms a one-dimensional motif and coordination polymer B (CP-B), which has a two-dimensional structure. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Rational design of three bifunctional MOFs for photocatalysis degradation and selective adsorption of wastewater organic dyes removal was written by Zhang, Xiaoyin;Zong, Ziao;Zhang, Xia;Zhang, Dongmei;Luo, Qingdan;Bi, Caifeng;Fan, Yuhua. And the article was included in Polyhedron in 2020.Application of 1374155-84-6 The following contents are mentioned in the article:

Three metal-organic frameworks (MOFs) based on transition metals, namely {[Cd(HL)(tib)(H₂O)]·1.5H₂O}_n (1), {[Co₃(L)₂(tib)₂]·4H₂O}_n (2), [Cu(L)(3,5-bibp)]_n (3) (H₃L = 4-(3,5-dicarboxylatobenzyloxy)benzoic, tib = 1,3,5-tris(1-imidazolyl)benzene and 4,4′-bibp = 4,4′-bis(imidazol-1-yl)biphenyl) were designed and successfully synthesized under solvothermal conditions. These three compounds were characterized by single crystal X-ray diffraction, elemental anal., IR spectra, powder X-ray diffraction (PXRD), TGA(TGA) and electrochem. studies. Single crystal X-ray diffraction anal. reveals that compound 1 possesses a 2-nodal (3,5)-connected hms topol. framework with the point symbol (6³·6^9.8), compound 2 unprecedented 3-nodal (8,8,11)-connected 3D framework with a (3⁷·4¹²·5⁹) (3⁸·4¹³·5⁷) (3⁹·4¹⁹·5²³·6⁴) topol., while compound 3 displays a 3D 4-connected sql topol. The electrochem. studies for compound 2 and 3 are discussed. Photocatalytic degradation and adsorption for organic dyes removal from wastewater using three compounds were studied. Significantly, all of the three compounds show good photocatalytic activities for MB and selective adsorption capacity for CR. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Application of 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Application of 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem