Category: 1374155-84-6

New topological Zn metal organic frameworks as multi-responsive fluorescent sensing materials for detecting Fe³⁺, Cr₂O^2-₇, CrO^2-₄ and tetracycline in aqueous system was written by Fan, Chuanbin;Xu, Cungang;Zhu, Bin;Wang, Lulu;Zong, Ziao;Wu, Ruixue;Zhang, Xia;Fan, Yuhua. And the article was included in Journal of Solid State Chemistry in 2021.Computed Properties of C11H9N5 The following contents are mentioned in the article:

Three new Zn metal organic frameworks (Zn-MOFs), {[Zn₂(L)[H (1,4-bmib)]]·1.5(H₂O)}_n (1), {[Zn₂(HL) (3,5-bip)₂]·(H₂O)}_n (2), and {[Zn₂(HL) (4,4′-bbibp)₂]·4(H₂O)}_n (3), have been first synthesized based on a flexible H₅L ligand with ether functional group (C-O-C) and successfully characterized (semi-flexible H₅L = 3,5-bis(3,5-dicarboxylphenoxy)benzoic acid, flexible 1,4-bmib = 1,4-bis(2-methylimidazol-1-yl)butane, rigid 3,5-bip = 3,5-bis(1-imidazolyl)pyridine, and rigid 4,4′-bbibp = 4,4′-bis(benzoimidazo-1-ly)biphenyl). Zn-MOFs 1-3 are unique topol. networks. As multi-responsive fluorescent sensing materials of 1 and 3, they show excellent response and sensitivity for Fe³⁺, CrO^2-₄ and Cr₂O^2-₇, and tetracycline (TC) in aqueous system. The quenching mechanism is also investigated in detail. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Computed Properties of C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Computed Properties of C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Near-infrared phosphorescence emission of Zn(II) coordination polymer based on 3,5-bis(1-imidazoly)pyridine: Syntheses, structure and photoelectron performance was written by Lu, Xiao-Min;Zhai, Zhi-Min;Liu, Xin-Yi;Li, Fei-Fei;Yang, Xiao-Gang;Li, Jin-Yao;Guo, Yu-Ming;Ma, Lu-Fang. And the article was included in Journal of Solid State Chemistry in 2019.Application of 1374155-84-6 The following contents are mentioned in the article:

Long wavelength of near IR (NIR) room temperature phosphorescence (RTP) emission is a kind of highly desirable materials. With the self-assembly reaction of D-A-D type semi-rigid 3,5-bis(1-imidazoly)pyridine (BMP) organic ligand and Zn(II) ions, one ionic coordination polymer (CP) {[Zn_0.5(BMP)(H₂O)]·(NO₃)} (1) was synthesized and characterized. The as-synthesized 1 exhibits highly prolonged phosphorescence lifetime >6000 times as long as that of the pristine BMP phosphor ligand. Theory calculation indicates that NO₃^– counterions highly affect the electronic structure and energy levels of the cationic CP host. By a facile anionic exchange, Eosin Y (EY) dye guest encapsulated into the CP host can significantly tune the phosphorescence color from yellow to rare example of near IR emission through an efficient phosphorescence energy transfer. The optoelectronic performance of 1 and EY@1 also were studied. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Application of 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Application of 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Syntheses, structures and fluorescent properties of two zinc coordination polymers based on itaconic acid was written by Yin, Wei-dong;Li, Gui-lian;Li, Xiao-ling;Xin, Ling-yun;Ma, Lu-fang;Liu, Guang-zhen. And the article was included in Wuji Huaxue Xuebao in 2016.HPLC of Formula: 1374155-84-6 The following contents are mentioned in the article:

Two Zn coordination polymers {[Zn(ic)(bip)]·2H₂O}_n (1) and [Zn(ic)(bpe)]_n (2) [H₂ic = itaconic acid, bip = 3,5-bis(1-imidazoly)pyridine and bpe = 1,2-bi(4-pyridyl)ethylene] were synthesized hydrothermally and characterized structurally by single-crystal x-ray diffractions and elemental anal. Both complexes 1 and 2 displayed 2-dimensional (4,4) grid layers containing 1-dimensional metal-carboxylate chains. Thermogravimetric Analyses (TGA), powder x-ray diffractions (PXRD) and fluorescence properties for compounds 1 and 2 were also studied. The solid state fluorescence spectra indicated that the emission spectrum of complex 1 showed obvious blue shift (-78 nm) compared to free bip co-ligand due to the ligand-to-metal charge-transfer (LMCT) effect. The compound 2 showed similar emission spectrum to the free bpe ligand, but the slight red shift might be attributed to the complexation effect between the bpe mol. and Zn atoms. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6HPLC of Formula: 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. HPLC of Formula: 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Metal-organic frameworks constructed from tetradentate carboxylic acids: Structural diversity, Fluorescence (Fe³⁺ detection) and Dye adsorption properties was written by Wang, Zhexin;Zhao, Lun;Han, Yue;Song, GuanYing;Jing, Hongwei;Guo, Guanlin;Wang, Ziyun;Li, Jiayu. And the article was included in Journal of Molecular Structure in 2022.Recommanded Product: 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:

Four new coordination polymers (CPs), namely, [Co(L)_0.5(bibp)_0.5]·DMF (1), [Cd(L)_0.5(bimp)]·2DMF (2),[Mn(L)_0.5(bibp)_0.5]·DMF (3), [Cu₂(L)(bimp)]·2DMF (4),(H₄L = 5-bis(4-carbonylbenzyl)aminoisophtalic acid, bibp = 3,5-bis(1-imidazolyl)pyridine, bimp = 1,3,5,-tris(1-imidazolyl)benzene), has been synthesized under solvothermal conditions. Compounds 1, 2 , 3 and 4 were characterized by FR IR spectroscopy, elemental anal., TGA thermogravimetric anal., and XRD resp. In addition, compounds 1, 3 are three-dimensional structures, compounds 2, 4 are two-dimensional structures. Compound 1 shows good dye adsorption capacity, compound 2 can be used as Fe³⁺ Ion detection probe. Therefore, compounds 1 and 2 will be strong candidates for dye adsorption and ion detection probes. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Recommanded Product: 3,5-Di(1H-imidazol-1-yl)pyridine).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Recommanded Product: 3,5-Di(1H-imidazol-1-yl)pyridine

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Crystal structure of 3,5-bis(imidazole-1-yl)pyridine, C₁₁H₉N₅ was written by Zhou, Hongyan. And the article was included in Zeitschrift fuer Kristallographie – New Crystal Structures in 2015.Related Products of 1374155-84-6 The following contents are mentioned in the article:

C₁₁H₉N₅, monoclinic, P2₁/c (number 14), a = 14.15(1) Å, b = 3.783(3) Å, c = 18.09(2) Å, β = 92.28(2)°, V = 968.0 ų, Z = 4, R_gt(F) = 0.0517, wR_ref(F²) = 0.1504, T = 296 K. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Related Products of 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. This ring system is present in important biological building blocks, such as histidine and the related hormone histamine.Related Products of 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Crystal structure of a diaqua-bis(3,5-di(1H-imidazol-1-yl)pyridine-κN)-bis(2-(4-carboxy-phenyl)acetato-κO]manganese(II), C₄₀H₃₆MnN₁₀O₁₀ was written by Ju, Feng-Yang;Guo, Wen-Bo;Li, Yun-Ping. And the article was included in Zeitschrift fuer Kristallographie – New Crystal Structures in 2017.Electric Literature of C11H9N5 The following contents are mentioned in the article:

C₄₀H₃₆MnN₁₀O₁₀, monoclinic, P2₁/c (number 14), a = 21.8966(12) Å, b = 7.2586(4) Å, c = 12.2346(6) Å, β = 98.232(1)°, V = 1924.52(18) ų, Z = 2, R_gt(F) = 0.0327, wR_ref(F²) = 0.0847, T = 296(2) K. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Electric Literature of C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Electric Literature of C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Coordination Frameworks based on 3,5-Bis(imidazole-1-yl)pyridine and Aromatic Dicarboxylate Ligands: Synthesis, Crystal Structures, and Photoluminescent Properties was written by Xu, Jiakun;Sun, Xiaochun;Yang, Lirong;Yan, Xincheng;Bi, Caifeng;Sun, Mi. And the article was included in Zeitschrift fuer Anorganische und Allgemeine Chemie in 2014.Name: 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:

Three metal coordination polymers [Zn(bdc)(L)(H₂O)]n (1), [Co(pta)(L)(H₂O)₂]n (2), and [Cd(tda)(L)(H₂O)]n (3) [H₂bdc = 1,2-benzene dicarboxylate acid, H₂pta = terephthalic acid, H₂tda = 2, 5-thiophenedicarboxylic acid, L = 3,5-bis(imidazole-1-yl)pyridine] were synthesized and structurally characterized by IR spectroscopy, elemental anal., x-ray powder diffraction, and X-ray single crystal diffraction. Complex 1 shows a three-dimensional (3D) structure with cco topol. with the symbol 6⁵路8, whereas complex 2 features a 3-dimensional structure with cds topol. with the symbol 6⁵路8. Complex 3 has a 2-dimensional network constructed by the cadmium atoms bridged through the ligands tda and L. Their x-ray powder diffraction patterns were compared with the simulated ones. Also, their luminescent properties were studied in the solid state at room temperature, and the thermogravimetric analyses were carried out to study the thermal stability of the 3-dimensional networks. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Name: 3,5-Di(1H-imidazol-1-yl)pyridine).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole is incorporated into many important biological compounds. The most pervasive is the amino acid histidine, which has an imidazole side-chain. Histidine is present in many proteins and enzymes, e.g. by binding metal cofactors, as seen in hemoglobin.Name: 3,5-Di(1H-imidazol-1-yl)pyridine

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Four structural diversity MOF-photocatalysts readily prepared for the degradation of the methyl violet dye under UV-visible light was written by Lu, Lu;Wang, Jun;Shi, Chuncheng;Sun, Yanchun;Wu, Weiping;Pan, Ying;Muddassir, Mohd.. And the article was included in New Journal of Chemistry in 2021.Application of 1374155-84-6 The following contents are mentioned in the article:

Four new metal-organic frameworks based on transition metals, namely [Mn₂(渭₂-H₂O)₂(H₂L)₂(CH₃CN)₂] (1), [Mn(L)_0.5 phen)路_0.5H₂O] (2), [Co(H₂O)₂(L)_0.5(bip)路H₂O] (3) and [Co₂(L)(bb)₂路HbbBr] (4), where (H₄L = 5,5鈥?(1,4-phenylenebis(methyleneoxy))diisophthalic acid, bip = 3,5-bis(1-imidazoly)pyridine, phen = 1,10-phenanthroline, bb = 4,4鈥?bis(imidazolyl)biphenyl), have been successfully synthesized under solvothermal conditions. 1 showed a 2D layer featuring a polythreaded network with alternate left-and right-handed 21 helical chains. 2 possessed a 1D [Mn(H₂L)]n chain that was further expanded into a 2D layer through O-H路路路O hydrogen bonds. 3 exhibited a 3D threefold interpenetrating network with a point symbol of (64路82)(66)2. 4 had a 3D 3-fold interpenetrated motif with 2-nodal 4,4-c connectivity. The photocatalytic results demonstrated that all of them could exhibit efficient photocatalytic abilities towards the degradation of methyl violet (MV) under UV irradiation The mechanism of the photocatalytic performance was explored and discussed. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Application of 1374155-84-6).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Application of 1374155-84-6

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Two Mn^II, Cu^II complexes derived from 3,5-bis(1-imidazolyl)pyridine: Synthesis, DNA binding, Molecular docking and cytotoxicity studies was written by Zhu, Mingchang;Liu, Jiaxing;Su, Junqi;Meng, Bo;Feng, Yunhui;Jia, Bing;Peng, Tingting;Qi, Zhenzhen;Gao, Enjun. And the article was included in Applied Organometallic Chemistry in 2019.COA of Formula: C11H9N5 The following contents are mentioned in the article:

Two complexes [MnL₂(H₂O)₂]路2ClO₄ (complex 1) and [CuL(H₂O)₃]路2NO₃ (complex 2) (L = 3,5-bis(1-imidazolyl)pyridine) were designed and synthesized. The structures of the complexes were characterized by x-ray crystallog., elemental analyses, and IR spectra. The interaction capacity of the complexes with calf thymus DNA was studied by UV and fluorescence spectroscopy. Gel electrophoresis assay demonstrated the ability of the complexes to cleave the pBR322 plasmid DNA. Efficient binding properties of DNA were established by UV-visible, fluorescence, and gel electrophoresis. The intrinsic binding constants (K_b) are 0.1524 and 0.1041 for complexes 1 and 2, resp. The two complexes exhibited a higher cytotoxicity against HeLa cell lines and lower cytotoxicity toward normal cell lines. Flow cytometry demonstrated the cancer cell inhibitory rate of the two complexes. Computer-aided mol. docking studies were performed to visualize the binding mode of the drug candidate at the mol. level. Complex 1 exhibited a significant higher cancer cell inhibitory rate than cisplatin and other complexes. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6COA of Formula: C11H9N5).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole is incorporated into many important biological compounds. The most pervasive is the amino acid histidine, which has an imidazole side-chain. Histidine is present in many proteins and enzymes, e.g. by binding metal cofactors, as seen in hemoglobin.COA of Formula: C11H9N5

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem

Three Coordination Polymers based on 3,5-Bis(imidazol-1-yl)pyridine and Benzoic Acid: Synthesis, Crystal Structures and Photoluminescent Properties was written by Xu, Jiakun;Yan, Xingchen;Sun, Xiaochun;Sun, Guolong;Bi, Caifeng;Sun, Mi. And the article was included in Zeitschrift fuer Anorganische und Allgemeine Chemie in 2014.Quality Control of 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:

Three metal coordination polymers {[Co(L)₂(H₂O)₂]²⁺路2NO₃^–}_n (1), {[Mn(L)₂(H₂O)₂]²⁺路2Cl^–路3H₂O}_n (2), and [ZnL(ba)₂]_n (3) [L = 3,5-bis(imidazol-1-yl)pyridine and Hba = benzoic acid] were synthesized and structurally characterized by IR spectroscopy, elemental anal., x-ray powder diffraction, and X-ray single crystal diffraction. Complex 1 shows a one-dimensional (1D) chain structure. Adjacent chains are connected by hydrogen bonding and nitrate groups to form a 3D network. Complex 2 features a 2D layer structure. A three-dimensional network is constructed through the cluster consisting of two chloride ions and three water mols. Complex 3 shows a 1D zigzag chain structure that further twists together to form a 3D network. The x-ray powder diffraction patterns were compared with the simulated ones. Also, the luminescent properties of 1–3 were investigated in the solid state at room temperature, and the thermogravimetric analyses were carried out to study the thermal stability of the three complexes. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Quality Control of 3,5-Di(1H-imidazol-1-yl)pyridine).

3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Quality Control of 3,5-Di(1H-imidazol-1-yl)pyridine

Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem