Zinser, Caroline M. published the artcileA simple synthetic entryway into palladium cross-coupling catalysis, SDS of cas: 258278-25-0, the publication is Chemical Communications (Cambridge, United Kingdom) (2017), 53(57), 7990-7993, database is CAplus and MEDLINE.
Allylpalladium cationic complexes with imidazolylidene NHC ligands were prepared by a simple protocol, comprising synthesis of a family of allylpalladates containing with an imidazolium counterion with subsequent deprotonation with an external base. These “ate” complexes can be easily converted into well-defined palladium-N-heterocyclic carbene (NHC) complexes. The synthetic protocols leading to the “ate” and to the Pd-NHC neutral complexes have been exemplified with various NHC ligands. The palladates prove efficient pre-catalysts enabling Suzuki-Miyaura and Mizoroki-Heck reactions.
Chemical Communications (Cambridge, United Kingdom) published new progress about 258278-25-0. 258278-25-0 belongs to imidazoles-derivatives, auxiliary class Achiral NHCs Ligands, name is 1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazol-3-ium chloride, and the molecular formula is C19H36BNO2Si, SDS of cas: 258278-25-0.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem