Elterman, V. A. published the artcileFeatures of aluminum electrodeposition from 1,3-dialkylimidazolium chloride chloroaluminate ionic liquids, Formula: C8H15ClN2, the publication is Journal of Molecular Liquids (2022), 118693, database is CAplus.
The mechanism of aluminum electrodeposition from acidic 1-butyl-3-methylimidazolium chloride chloroaluminate ionic liquids ([BMIm]Cl ILs) is studied over a wide range of the molar ratio of AlCl3 to [BMIm]Cl (N) at 30°C. The findings for AlCl3-[BMIm]Cl and AlCl3-1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) are analyzed and compared in order to identify dependences common for 1,3-dialkylimidazolium chloride ILs. Limiting currents were detected on the cathodic polarization curves at the aluminum | ionic liquid interface. Limiting currents are caused by the Al2Cl–7 anions diffusion to the electrode surface. The limiting c.d. values for AlCl3-[BMIm]Cl are lower (ilim, 1.1 ≤ N leq 2.0 = 1.17 – 12.36 mA•cm-2) than for AlCl3-[EMIm]Cl (ilim, 1.1 ≤ N leq 2.0 = 1.81 – 25.37 mA·cm-2). It is shown that anion AlCl-4 can be reduced to metallic aluminum at cathodic overpotentials above 1.5 V. The diffusion coefficient of Al2Cl-7 in AlCl3-[BMIm]Cl (7.4•10-7 cm2•s-1) is lower than in AlCl3-[EMIm]Cl (9.3•10-7 cm2•s-1) and is unaffected by aluminum chloride concentration in either system.
Journal of Molecular Liquids published new progress about 79917-90-1. 79917-90-1 belongs to imidazoles-derivatives, auxiliary class Ionic Liquid,Ionic Liquid, name is 3-Butyl-1-methyl-1H-imidazol-3-ium chloride, and the molecular formula is C8H15ClN2, Formula: C8H15ClN2.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem