The structures, photoluminescence and photocatalytic properties of two types of iodocuprate hybrids was written by Lin, Chong-Yang;Zhang, Di;Sun, Xin-Yuan;Wei, Li;Xue, Zhen-Zhen;Pan, Jie;Wang, Guo-Ming. And the article was included in Inorganic Chemistry Communications in 2018.Electric Literature of C11H9N5 The following contents are mentioned in the article:
Two new Cu(I)-iodide clusters driven by 3,5-bis(imidazole-1-yl)pyridine (bip), [(H2bip)2Cu5I9] (1) and [H2bip]2[Cu3I7] (2), were prepared via modulating organic/inorganic ratio at room temperature Compound 1 presents a zero-dimensional structure constituting of [Cu4I8]4- and [(H2bip)2CuI2]3+ two different subunits. Compound 2 features a discrete [Cu3I7]4- anionic cluster, which is the 1st isolated iodocuprate cluster with protonated bip as structure-directing agent (SDA). The structural diversity of 1 and 2 mainly stems from the distinct role of bip during the crystallization Meanwhile, the reaction ratio here also plays an essential role on the fabrication of two structures. The solid-state luminescence bands of 1 and 2 were studied between 499 and 78 K. Both of them exhibit yellow luminescence, and their intensities increase gradually upon cooling. What is more, photocatalytic properties of 1 and 2 were studied. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Electric Literature of C11H9N5).
3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Many drugs contain an imidazole ring, such as certain antifungal drugs, the nitroimidazole series of antibiotics, and the sedative midazolam.Electric Literature of C11H9N5
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem