Experimental and theoretical study of bifunctional electro-catalysts constructed from different Polyoxometalates and Ag-bimpy segments was written by Zheng, Yanping;Zhou, Wanli;Liu, Xuekun;Yuan, Gang;Peng, Jun. And the article was included in Electrochimica Acta in 2021.Application of 1374155-84-6 The following contents are mentioned in the article:
In this work, upon subtle POMs variation, we reported on the assembly and performances of three new bimetallic component organic-inorganic hybrids, [Ag2(bimpy)(VV2O6)](1), [Ag3(bimpy)2(β-MoVI8O26)](2), [Ag4(bimpy)2(H2O)2(α-SiWVI12O40)]â?H2O (3) (bimpy = 3,5-bis(1-imidazoly) pyridine). Compound 1 with 3D framework structure is featured by {-V-O-V-}n helical chains, {Ag3} clusters and {bimpy-Ag-bimpy} units. Compound 2 has a 3,3,6,6-connected 3D architecture with the (43)(43)(42â?9â?â?3)(46â?2â?4â?â?2) topol. Compound 3 has a 3,3,4-connected 2D layer with (62â?)(62â?)(66) topol. The electrochem. and bifunctional electro-catalytic activities of three compounds have been conducted. The exptl. results show that β-[Mo8O26]4- hybrid displays better electrocatalytic performance than [V2O6]2- and Keggin-type hybrids for reduction of nitrite, while [V2O6]2- hybrid exhibits better electrocatalytic activity than β-[Mo8O26]4- and Keggin hybrids towards oxidations of ascorbic acid. Furthermore, the mol. electrostatic potential and frontier MO were performed. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Application of 1374155-84-6).
3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Application of 1374155-84-6
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem