Mn(II)/Co(II)-based metal-organic frameworks assembled by 5,5′-(1,4-xylylenediamino) diisophthalic acid and various nitrogen-containing ligands for photocatalytic and magnetic properties was written by Xu, Cungang;Luo, Rong;Zhang, Dongmei;Zhang, Xia;Zong, Ziao;Fan, Chuanbin;Zhu, Bin;Fan, Yuhua. And the article was included in Journal of Solid State Chemistry in 2021.Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:
Three novel Mn(II)/Co(II)-based 3D metal-organic frameworks (MOFs), namely {[Mn2(L)(tib)(H2O)]·3DMA·4H2O}n (1), {[Co2(L)(bipd)2]·3H2O}n (2) and {[Co(L)0.5(bimb)]·3H2O·0.5O2}n (3) (H4L = 5,5′-(1,4-xylylenediamino)diisophthalic acid, tib = 1,3,5-tris(1-imidazolyl)benzene, bipd = 3,5-bis(1-imidazoly)pyridine, and bimb = 1,4-bis(lmidazol)-butane), have been successfully synthesized using the mixed-ligand as functionalized organic linker. The structural characterization revealed that both MOFs 1 and 2 exhibited an unprecedented 4-nodal 3D framework that enriching crystal engineering, while MOF 3 featured a 2-nodal three-interpenetrating bbf topol. framework with a Schlafli symbol of (64·82)(66)2. The title MOFs have been exploited as photocatalysts for degradation of methylene blue (MB), methyl violet (MV) and malachite green (MG). The photocatalytic results demonstrated that MOFs 2 and 3 exhibited efficient photocatalytic abilities to degrade the three aromatic dyes under UV irradiation The possible catalytic mechanism was also explored and discussed in detail. Moreover, the variable-temperature magnetic analyses indicated that MOFs 1–3 exhibited weak antiferromagnetic behavior between Mn(II)/Co(II) ions. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine).
3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem