On November 15, 2013, Dai, Wen; Li, Jun; Chen, Bo; Li, Guosong; Lv, Ying; Wang, Lianyue; Gao, Shuang published an article.Related Products of 73590-85-9 The title of the article was Asymmetric Oxidation Catalysis by a Porphyrin-Inspired Manganese Complex: Highly Enantioselective Sulfoxidation with a Wide Substrate Scope. And the article contained the following:
The first genuinely promising porphyrin-inspired manganese-catalyzed asym. sulfoxidation method using hydrogen peroxide has been successfully developed, allowing for rapidly oxidation (0.5-1.0 h) of a wide variety of sulfides in high yields with excellent enantioselectivities (up to >99% ee). E.g., in presence of Mn(OTf)2, AcOH, and the porphyrin-inspired ligand (I), asym. oxidation of 3-ClC6H4SMe by hydrogen peroxide gave 82% sulfoxide (II, 97% ee). The experimental process involved the reaction of 5-Methoxy-2-[[(4-methoxy-3,5-dimethyl-2-pyridyl)methyl]thio]benzimidazole(cas: 73590-85-9).Related Products of 73590-85-9
The Article related to manganese ligand catalyst asym oxidation sulfide, enantioselective synthesis sulfoxide, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Sulfoxides and Sulfones and other aspects.Related Products of 73590-85-9
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem