Analyzing the synthesis route of Imidazole-2-carboxaldehyde

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10111-08-7, Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 10111-08-7, name is Imidazole-2-carboxaldehyde, This compound has unique chemical properties. The synthetic route is as follows.

A solution of 36 triphenylmethylchloride (640mg, 2.3mmol) in 37 dichloromethane (1mL) was added to a mixture of 2-imidazolecarboxadehyde (200mg, 2.1mmol) and 38 potassium carbonate (1.44g, 10.4mmol) in 39 dimethylformamide (1.5mL). The mixture was stirred at 60C overnight and then cooled down to room temperature. The reaction mixture was extracted with ethyl acetate, the combined extracts were dried over anhydrous sodium sulfate and concentrated in vacuo. The residue was purified by preparative thin layer chromatography eluting with 40% ethyl acetate in 40 hexane to provide 11 9 as a white to light-yellow solid in 32% yield. 1H NMR (300MHz, CDCl3) delta 9.23 (s, 1H), 7.38-7.29 (m, 10H), 7.13-7.10 (m, 6H), 7.02 (s, 1H). The 1H NMR data are consistent with those reported in the literature.17

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Reference:
Article; Patanapongpibul, Manee; Zhang, Changde; Chen, Guanglin; Guo, Shanchun; Zhang, Qiang; Zheng, Shilong; Wang, Guangdi; Chen, Qiao-Hong; Bioorganic and Medicinal Chemistry; vol. 26; 16; (2018); p. 4751 – 4760;,
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem