Ding, Fangwei; Jiang, Yanqiu; Gan, Shaoyan; Bao, Robert Li-Yuan; Lin, Kaifeng; Shi, Lei published an article in 2017, the title of the article was B(C6F5)3-Catalyzed Deoxygenation of Sulfoxides and Amine N-Oxides with Hydrosilanes.Synthetic Route of 73590-85-9 And the article contains the following content:
An efficient strategy for the deoxygenation of sulfoxides and amine N-oxides by using B(C6F5)3 and hydrosilanes was developed. This method provided the corresponding aromatic and aliphatic sulfides/amines in good to high yields and showed good functional-group tolerance under mild conditions. This protocol should be very useful in the future because of its ease of operation, the environmentally friendly reaction conditions and wide scope. The experimental process involved the reaction of 5-Methoxy-2-[[(4-methoxy-3,5-dimethyl-2-pyridyl)methyl]thio]benzimidazole(cas: 73590-85-9).Synthetic Route of 73590-85-9
The Article related to sulfide green preparation, sulfoxide deoxygenation phenylsilane tris pentafluorophenyl borane catalyst, amine green preparation, deoxygenation amine oxide phenylsilane tris pentafluorophenyl borane catalyst and other aspects.Synthetic Route of 73590-85-9
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem