《Simple Synthetic Routes to Carbene-M-Amido (M = Cu, Ag, Au) Complexes for Luminescence and Photocatalysis Applications》 was written by Tzouras, Nikolaos V.; Martynova, Ekaterina A.; Ma, Xinyuan; Scattolin, Thomas; Hupp, Benjamin; Busen, Hendrik; Saab, Marina; Zhang, Ziyun; Falivene, Laura; Pisano, Gianmarco; Van Hecke, Kristof; Cavallo, Luigi; Cazin, Catherine S. J.; Steffen, Andreas; Nolan, Steven P.. Recommanded Product: Chloro{1,3-bis[2,6-bis(1-methylethyl)phenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) And the article was included in Chemistry – A European Journal on August 16 ,2021. The article conveys some information:
The development of novel and operationally simple synthetic routes to carbene-metal-amido (CMA) complexes [(NHC)M(Cbz)] (NHC = substituted 2-imidazolylidene; HCbz = 9H-carbazole; M = Cu, Ag, Au) of copper, silver and gold relevant for photonic applications are reported. A mild base and sustainable solvents allow all reactions to be conducted in air and at room temperature, leading to high yields of the targeted compounds even on multigram scales. The effect of various mild bases on the N-H metalation was studied in silico and exptl., while a mechanochem., solvent-free synthetic approach was also developed. Our photophys. studies on [M(NHC)(Cbz)] indicate that the occurrence of fluorescent or phosphorescent states is determined primarily by the metal, providing control over the excited state properties. Consequently, we demonstrate the potential of the new CMAs beyond luminescence applications by employing a selected CMA as a photocatalyst. The exemplified synthetic ease is expected to accelerate the applications of CMAs in photocatalysis and materials chem. After reading the article, we found that the author used Chloro{1,3-bis[2,6-bis(1-methylethyl)phenyl]-4,5-dihydroimidazol-2-ylidene}gold(I)(cas: 852445-84-2Recommanded Product: Chloro{1,3-bis[2,6-bis(1-methylethyl)phenyl]-4,5-dihydroimidazol-2-ylidene}gold(I))
Chloro{1,3-bis[2,6-bis(1-methylethyl)phenyl]-4,5-dihydroimidazol-2-ylidene}gold(I)(cas: 852445-84-2) belongs to imidazoles.Imidazole rings are part of unnatural cyclic peptides and are used as ester isosteres in peptidomimetic studies.
However, the application of imidazoles is not limited to the field of peptides and peptidomimetics. Recommanded Product: Chloro{1,3-bis[2,6-bis(1-methylethyl)phenyl]-4,5-dihydroimidazol-2-ylidene}gold(I)
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem