Little discovery in the laboratory: a new route for 16961-25-4

After consulting a lot of data, we found that this compound(16961-25-4)Recommanded Product: Hydrogen tetrachloroaurate(III) trihydrate can be used in many types of reactions. And in most cases, this compound has more advantages.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called New Insights on the Dynamic Role of the Protecting Agent on the Reactivity of Supported Gold Nanoparticles, published in 2020, which mentions a compound: 16961-25-4, Name is Hydrogen tetrachloroaurate(III) trihydrate, Molecular AuCl4H7O3, Recommanded Product: Hydrogen tetrachloroaurate(III) trihydrate.

A very efficient catalyst (AuCePVA) was prepared by depositing gold colloids on CeO2 and using polyvinyl alc. (PVA) as protective agent. Complete conversion and selectivity in furfural (2-FA) oxidative esterification to methyl-2-furoate (Me-2-F) was obtained without base under conventional heating at 120°C. AuCePVA was compared with Au/CeO2 obtained by deposition-precipitation method, pointing out that along with the size of the Au nanoparticles and the surface sites of the ceria support, also PVA chains played a role during reaction. In situ FTIR spectroscopy measurements of adsorbed mols. at controlled temperature and pressure demonstrated that PVA acted not merely as gold stabilizer, but also as mediator during the 2-FA oxidative esterification, leaving both Au and ceria sites available for catalysis at the reaction temperature In a perspective of process intensification, the microwave-assisted (MW-assisted) 2-FA oxidative esterification was carried out. Depending on the reaction time and temperature, AuCePVA favored the oxidation of the hemiacetal into the ester rather than the re-oxidation of the acetal into the ester, due to the formation of Ce3+ sites under MW irradiation

After consulting a lot of data, we found that this compound(16961-25-4)Recommanded Product: Hydrogen tetrachloroaurate(III) trihydrate can be used in many types of reactions. And in most cases, this compound has more advantages.

Reference:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem