Electric Literature of 1072-63-5, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, 1072-63-5, Name is 1-Vinyl-1H-imidazole, SMILES is C=CN1C=CN=C1, belongs to imidazoles-derivatives compound. In a article, author is Xu, Kun, introduce new discover of the category.
Atom-Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes
New Rh- and Pd-catalyzed regiodivergent and stereoselective intermolecular coupling reactions of imidazole derivatives with mono-substituted allenes are herein reported. Using a Rh-I/Josiphos system, perfect regioselectivities and high enantiomeric excess were obtained, while a Pd-II/dppf system gave linear products with high regioselectivities and high E/Z selectivities. This method permits the atom economic synthesis of valuable branched and linear allylic imidazole derivatives.
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