16079-88-2, Name is 1-Bromo-3-chloro-5,5-dimethylimidazolidine-2,4-dione, molecular formula is C5H6BrClN2O2, Recommanded Product: 16079-88-2, belongs to imidazoles-derivatives compound, is a common compound. In a patnet, author is Martorana, Annamaria, once mentioned the new application about 16079-88-2.
Synthesis of 4(5)-phenacyl-imidazoles from isoxazole side-chain rearrangements
A novel base-induced rearrangement of isoxazoles into imidazole derivatives is reported. In the isoxazole series, this represents the first example of a three-atom side-chain rearrangement involving a CNC sequence. The reactions are carried out under nitrogen and produced 2-aryl-4(5)-phenacyl-5(4)-phenyl-imidazoles in high yields. In the presence of oxygen, a cascade rearrangement-oxidation reaction sequence was observed and imidazole derivatives bearing an oxidized side-chain were isolated.
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