Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 934-32-7, Name is 1H-Benzo[d]imidazol-2-amine, SMILES is NC1=NC2=CC=CC=C2N1, in an article , author is Trofimov, Boris A., once mentioned of 934-32-7, Category: imidazoles-derivatives.
Reaction of imidazole derivatives with trifluoromethylated arylacetylenes
The nucleophilic addition of imidazole derivatives to trifluoromethylated acetylenes was studied. Unpredictable regioselectivity of the reaction was observed to yield both beta- and alpha-addition products. The reaction is 100% stereoselective to give the corresponding adducts as a Z-isomers only. The observed regioselectivity is discussed in terms of polarization of triple bond using experimental and calculated data. (C) 2016 Elsevier B.V. All rights reserved.
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