Room-temperature silver-containing liquid metal salts with nitrate anions was written by Schaltin, Stijn;Brooks, Neil R.;Sniekers, Jeroen;Depuydt, Daphne;Van Meervelt, Luc;Binnemans, Koen;Fransaer, Jan. And the article was included in Physical Chemistry Chemical Physics in 2013.Reference of 21252-69-7 This article mentions the following:
The synthesis, structural, thermal and electrochem. properties of F-free Ag-containing ionic liquids are presented. The ionic liquid cations are formed by a Ag(I) ion surrounded by two 1-alkylimidazole ligands, with the counteranions being nitrate ions. Depending on the alkyl chain length, the complexes are liquids at room temperature or melting slightly above this. For the solid compounds it was possible to elucidate the structure by single crystal x-ray anal. The ionic liquids are electroactive, have good mass transport properties and can be used for the electrodeposition of Ag at high current densities. The thermal properties and stability of these compounds were tested by DSC and TGA. The viscosity of the ionic liquids follows a Vogel-Tamman-Fulcher relation as a function of temperature The electrochem. properties of the complexes were tested by cyclic voltammetry and the resulting electrodeposits were examined using SEM and at. force microscopy. In the experiment, the researchers used many compounds, for example, 1-Octyl-1H-imidazole (cas: 21252-69-7Reference of 21252-69-7).
1-Octyl-1H-imidazole (cas: 21252-69-7) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Reference of 21252-69-7
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem