EPR and polarography of nitro azoles. 2. Nitroimidazoles was written by Vakul’skaya, T. I.;Larina, L. I.;Nefedova, O. B.;Petukhov, L. P.;Voronkov, M. G.;Lopyrev, V. A.. And the article was included in Khimiya Geterotsiklicheskikh Soedinenii in 1979.Name: 1-Methyl-4-nitroimidazole This article mentions the following:
Polarog. half-wave potentials (E) were determined for I (R = H, Me, Et; R1 = H, Me), II (R = Me, Et; R1 = H, Me), and III (R = H, Me, Et), and ESR parameters were determined for the resulting anion radicals. When R in I, II, and III was H, dianion radicals were formed in a stepwise manner; when R was alkyl, monoanion radicals were formed. The magnitude of aNO2 increased with increasing magnitude of E. In the dianion radicals >60% of the spin d. was concentrated on the NO2 group; in the monoanion radicals this figure was 45-50%. The degree of spin d. transfer to the ring decreased in the order III > II > I. In the experiment, the researchers used many compounds, for example, 1-Methyl-4-nitroimidazole (cas: 3034-41-1Name: 1-Methyl-4-nitroimidazole).
1-Methyl-4-nitroimidazole (cas: 3034-41-1) belongs to imidazole derivatives. Many natural products, especially alkaloids, contain the imidazole ring. These imidazoles share the 1,3-C3N2 ring but feature varied substituents. The pharmacophore of imidazole exists in bioactive compounds including amino acids, plant growth regulators and therapeutic agents.n increase of the alkyl chain length of the alcohols. Name: 1-Methyl-4-nitroimidazole
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem