Jiang, Li-Ping published the artcileThe dominance of sulfate over two organic ligands in the solvothermal assembly of an undecanuclear cobaltous cluster: crystallography and mass spectrometry, Recommanded Product: (1-Methyl-1H-benzo[d]imidazol-2-yl)methanol, the publication is Dalton Transactions (2020), 49(48), 17683-17688, database is CAplus and MEDLINE.
An unexpected dominance of the coordination affinity of the sulfate anion over those of two organic chelating ligands, (1-methyl-1H-benzo[d]imidazol-2-yl)methanol (Hmbm) and pyridin-2-ylmethanamine (pma), was observed during the study of the solvothermal assembly of [Co11(mbm)6(pma)2(SO4)8(H2O)6(CH3OH)6]·5CH3OH (1), from CoSO4·7H2O at 100°C in methanol. ESI-MS of solutions at different periods of the assembly reveal a hierarchical sequence, [Co1] → [Co2] → [Co3] → [Co4] → [Co5] → [Co9], where the lower nuclearity species are richer in Co2+ and SO42- before the inclusion of more mbm ligands at the last step. Its crystal structure consists of an almost sym. wheel of nine cobalt atoms, [Co9(mbm)6(SO4)8(H2O)6] in edge-sharing octahedral coordination arranged in triangles with two peripheral dangling [Co(pma)(CH3OH)3]. The sulfate ions exhibit three different coordination modes, two in μ6-, two in μ3– and four as μ2-bridging. Its thermal, optical and magnetic properties are also reported.
Dalton Transactions published new progress about 7467-35-8. 7467-35-8 belongs to imidazoles-derivatives, auxiliary class Benzimidazole,Alcohol, name is (1-Methyl-1H-benzo[d]imidazol-2-yl)methanol, and the molecular formula is C9H10N2O, Recommanded Product: (1-Methyl-1H-benzo[d]imidazol-2-yl)methanol.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem