Du, Junyi published the artcileA novel manganese(III)-peroxo complex bearing a proline-derived pentadentate aminobenzimidazole ligand, Recommanded Product: 2-(Chloromethyl)-1-methyl-1H-benzo[d]imidazole, the publication is Chinese Chemical Letters (2018), 29(12), 1869-1871, database is CAplus.
Manganese(III)-peroxo complexes are invoked as key intermediates in the enzymic cycles of Mn-containing enzymes, and the synthesis of reactive manganese(III)-peroxo complexes with rationally designed ligand was of great interest in the communities of bioinorganic and biomimetic chem. Herein, the authors designed a novel pentadentate aminobenzimidazole ligand and obtained its manganese(II) complex, which was successfully applied in the synthesis of a reactive manganese(III)-peroxo complex by treatment with hydrogen peroxide in the presence of triethylamine. The manganese(III)-peroxo complex was well characterized with various spectroscopic techniques, including UV-visible spectrophotometry, cold-spray ionization time-of-flight mass spectrometry (CSI-TOF MS), and continuous wave ESR (CW-EPR) spectroscopy. Besides, its reactivity in aldehyde deformylation was studied, demonstrating second-order kinetics in the reaction with 2-phenylpropionaldehyde and affording acetophenone as the sole product.
Chinese Chemical Letters published new progress about 4760-35-4. 4760-35-4 belongs to imidazoles-derivatives, auxiliary class Chloride,Benzimidazole, name is 2-(Chloromethyl)-1-methyl-1H-benzo[d]imidazole, and the molecular formula is C9H9ClN2, Recommanded Product: 2-(Chloromethyl)-1-methyl-1H-benzo[d]imidazole.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem