Chen, Hong published the artcileNew efficient copper(II)-catalyzed direct access to primary amide from aldehyde under solvothermal condition and related crystal structure study, Computed Properties of 7467-35-8, the publication is Chinese Journal of Structural Chemistry (2016), 35(5), 796-804, database is CAplus.
Two 1-methyl-1H-benzo[d]imidazole derivatives, C18H14CuN4O4·C4H8O2 (1) and C9H9N3O (2), were synthesized and characterized by NMR, MS, FT-IR, elementary anal. and x-ray single-crystal diffraction. Compound 1 crystallizes in monoclinic, space group P21/n with a = 9.6888(3), b = 7.3772(2), c = 14.3277(4) Å, β = 95.819(3)°, V = 1018.81(5) Å3, Mr = 501.98, Z = 2, Dc = 1.636 g/cm3, F(000) = 518, μ = 1.123 mm-1, MoKα radiation (λ = 0.71073 Å), the final R = 0.0325 and wR = 0.0859 for 1821 observed reflections with I > 2σ(I). Compound 2 crystallizes in monoclinic, space group C2/c with a = 14.2908(14), b = 14.4268(13), c = 8.4802(6) Å, β = 108.513(9)°, V = 1657.9(3) Å3, Mr = 175.19, Z = 8, Dc = 1.404 g/cm3, F(000) = 736, μ = 0.097 mm-1, MoKα radiation (λ = 0.71073 Å), the final R = 0.0563 and wR = 0.1531 for 1231 observed reflections with I > 2σ(I). Intermol. (N-H···N, N-H···O) and intramol. (N-H···N, C-H···O) hydrogen bonds, as well as C-H···π and π-π stacking interactions, help to stabilize the crystal structure of compound 2.
Chinese Journal of Structural Chemistry published new progress about 7467-35-8. 7467-35-8 belongs to imidazoles-derivatives, auxiliary class Benzimidazole,Alcohol, name is (1-Methyl-1H-benzo[d]imidazol-2-yl)methanol, and the molecular formula is C9H10N2O, Computed Properties of 7467-35-8.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem