Wolf, Silke published the artcileRoom-Temperature Synthesis of [BMIm][Sn5O2Cl7] with ∞1(Sn2OCl2) Strands in a Saline [BMIm][SnCl3] Matrix, Application of 3-Butyl-1-methyl-1H-imidazol-3-ium chloride, the publication is Inorganic Chemistry (2022), 61(9), 4018-4023, database is CAplus and MEDLINE.
The novel tin(II) oxychloride [BMIm][Sn5O2Cl7] (BMIm: 1-butyl-3-methylimidazolium) is obtained by room-temperature reaction (25°C) of black SnO and SnCl2 in [BMIm]Cl/SnCl2 as ionic liquid The title compound can be described to be composed of noncharged, infinite inf1(Sn2OCl2) strands, which are embedded in a saline matrix of [BMIm]+ and [SnCl3]–. The inf1(Sn2OCl2) strands consist of a backbone of edge-sharing OSn4/2 tetrahedra, which represent one-dimensional strands cut out of the layer-type structure of SnO. In [BMIm][Sn5O2Cl7] the inf1(Sn2OCl2) strands, which mimic a 1D semiconductor, are terminated by chlorine atoms, whereas they are interconnected by oxygen in the 2D semiconductor SnO. The view of the noncharged inf1(Sn2OCl2) strands in a saline [BMIm][SnCl3] matrix is validated by dissolution experiments Thus, electron microscopy and Raman spectroscopy show a deconstruction of [BMIm][Sn5O2Cl7] single crystals after treatment with CHCl3 with a dissolution of [BMIm][SnCl3], the formation of SnCl2 needles, and tin oxide as a solid remain.
Inorganic Chemistry published new progress about 79917-90-1. 79917-90-1 belongs to imidazoles-derivatives, auxiliary class Ionic Liquid,Ionic Liquid, name is 3-Butyl-1-methyl-1H-imidazol-3-ium chloride, and the molecular formula is C3H9ClOS, Application of 3-Butyl-1-methyl-1H-imidazol-3-ium chloride.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem