Li, Gang-Jian’s team published research in Tetrahedron Letters in 60 | CAS: 258278-25-0

Tetrahedron Letters published new progress about 258278-25-0. 258278-25-0 belongs to imidazoles-derivatives, auxiliary class Achiral NHCs Ligands, name is 1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazol-3-ium chloride, and the molecular formula is C27H39ClN2, Related Products of imidazoles-derivatives.

Li, Gang-Jian published the artcileNi/NHC-catalyzed cross-coupling of methyl sulfinates and amines for direct access to sulfinamides, Related Products of imidazoles-derivatives, the publication is Tetrahedron Letters (2019), 60(46), 151260, database is CAplus.

A simple and convenient method was developed for the Ni/NHC-catalyzed cross-coupling of Me sulfinates and amines without an acid/base to afford secondary or tertiary sulfinamides RS(O)NR1R2 [R = Me, c-hexyl, 4-MeC6H4, etc.; R1 = Et, CH2CH=CH2, Bn, etc.; R2 = H, Me, Et, etc.; R1R2 = (CH2)4, (CH2)2O(CH2)2, (CH2)2S(CH2)2, etc.] in moderate to good yields. The method provided the desired products with broad substrate scope, good chemoselectivity and good functional group compatibility.

Tetrahedron Letters published new progress about 258278-25-0. 258278-25-0 belongs to imidazoles-derivatives, auxiliary class Achiral NHCs Ligands, name is 1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazol-3-ium chloride, and the molecular formula is C27H39ClN2, Related Products of imidazoles-derivatives.

Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem