Mondal, Ejabul published the artcile1,2-diphenylbenzimidazole-triarylamine hybrided bipolar host materials employing fluorene as bridge for RYB and white electrophosphorescent devices, Product Details of C19H14N2, the publication is Organic Electronics (2016), 115-125, database is CAplus.
Four novel bipolar hosts (DTAFNBI, m-DTAFNBI, DTAFCBI and m-DTAFCBI) comprising a hole-transport ditolylphenylamino donor and an electron-transport 1,2-diphenylbenzimidazole acceptor connected via a fluorene spacer were synthesized and characterized. Through the different linkage topologies of phenylbenzimidazole, the thermal, photophys., and electrochem. properties can be fine-tuned. The saturated fluorene spacer along with the ditolylphenylamino donor and the phenylbenzimidazole acceptor endowed high triplet energies (ET = 2.47-2.62 eV, recorded in neat film at 20 K) and bipolar transporting abilities. Furthermore, the tetragonal geometry given by the sp3-hybridized C9 of fluorene encumbered intermol. packing and led to excellent thermal and morphol. stabilities (Td = 379-392 °C, corresponding 5% weight loss; Tg = 148-162 °C). As a result, these bipolar materials were utilized as universal hosts for red, yellow, and blue (RYB) phosphorescent OLEDs, showing maximum external quantum efficiencies (ηext) of 9.6%, 14.7%, and 18.9% for blue (FIrpic), yellow (m-(Tpm)2Ir(acac) and red [Os(bpftz)2(PPhMe2)2, OS1], resp. In addition, white organic light-emitting diodes combining a blue emitter (FIrpic) and yellow emitter m-(Tpm)2Ir(acac) and a red emitter (OS1) within a single emitting layer were also fabricated which also exhibited good efficiencies (9.5-13.7%, 15.1-23.5 cd A-1, 13.3-23.9 lm W-1) with relatively low efficiency roll off.
Organic Electronics published new progress about 2622-67-5. 2622-67-5 belongs to imidazoles-derivatives, auxiliary class Benzimidazole,Benzene,Benzimidazole, name is 1,2-Diphenyl-1H-benzo[d]imidazole, and the molecular formula is C19H14N2, Product Details of C19H14N2.
Referemce:
https://en.wikipedia.org/wiki/Imidazole,
Imidazole | C3H4N2 – PubChem