C-N-Cyclometalated Platinum(II) Complexes with Sterically Demanding 1,2-Diarylimidazole Ligands was written by Micksch, Maik;Tenne, Mario;Strassner, Thomas. And the article was included in Organometallics in 2014.Reference of 914306-50-6 The following contents are mentioned in the article:
Authors describe the synthesis, characterization, and photophys. properties of 12 neutral cyclometalated platinum(II) complexes with sterically demanding 1,2-diarylimidazole ligands and β-diketonate ancillary ligands. All complexes are photophys. active emitting in the blue-green to red region (490-590 nm) of the spectrum with quantum yields up to 58%, measured in poly(Me methacrylate) (PMMA) at room temperature The steric demand of the imidazole ligand as well as of the β-diketonate ligand shows a significant effect on the quantum yield but not on the emission wavelength. These can be tuned by changing the substituents at the C-2 Ph group of the imidazole ligand. This study involved multiple reactions and reactants, such as 1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6Reference of 914306-50-6).
1-(2,6-Diisopropylphenyl)-2-phenyl-1H-imidazole (cas: 914306-50-6) belongs to imidazole derivatives. Imidazole is a heterocyclic compound with a five-membered planar ring. It is amphoteric and highly polar. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Reference of 914306-50-6
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem