The intrinsic anodic stability of several anions comprising solvent-free ionic liquids was written by Koch, V. R.;Dominey, L. A.;Nanjundiah, C.;Ondrechen, M. J.. And the article was included in Journal of the Electrochemical Society in 1996.Electric Literature of C8H15F6N2P The following contents are mentioned in the article:
Salts of the form 1,2-dimethyl-3-propylimidazolium X [where X = AsF6–, PF6–, (CF3SO2)2N–, and (CF3SO2)3C–] were prepared and purified. Linear sweep voltammetry was conducted at 80°, a temperature at which all four salts were molten, at Pt, W, and glassy C working electrodes. The intrinsic anodic stability of these anions was in the order (CF3SO2)3C– > (CF3SO2)2N– approx. AsF6– > PF6–. These exptl. solution-phase oxidation potentials correlated well with gas-phase HOMO energies calculated by an ab initio technique. This study involved multiple reactions and reactants, such as 1,2-Dimethyl-3-propyl-1H-imidazol-3-ium hexafluorophosphate(V) (cas: 157310-73-1Electric Literature of C8H15F6N2P).
1,2-Dimethyl-3-propyl-1H-imidazol-3-ium hexafluorophosphate(V) (cas: 157310-73-1) belongs to imidazole derivatives. Imidazole is the basic core of some natural products such as histidine, purine, histamine and DNA based structures, etc. Among the different heterocyclic compounds, imidazole is better known due to its broad range of chemical and biological properties. Imidazole based anticancer drug find applications in cancer chemotherapy. It is used as buffer component for purification of the histidine tagged recombinant proteins in immobilized metal-affinity chromatography (IMAC).Electric Literature of C8H15F6N2P
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem