Two- and three-dimensional hybrid zinc phosphites: syntheses, structures and photoluminescence properties was written by Han, Song-De;Zhang, Xiu-Rong;Pan, Jie;Mu, Ying;Li, Jin-Hua;Wang, Guo-Ming. And the article was included in Dalton Transactions in 2018.Synthetic Route of C11H9N5 The following contents are mentioned in the article:
Two zinc-phosphites modified by a rigid amine 3,5-bis(imidazole-1-yl)pyridine (BIP), [Zn2(HPO3)2(BIP)]·H2O (1) and [Zn3(HPO3)3(BIP)(H2O)]·H2O (2), were solvothermally prepared Compound 1 possesses a zincophosphite layer decorated by BIP moieties via coordinating to intralayer Zn(II) ions. Compound 2 features a 3-dimensional frame with a pillar-layer structure, in which the organic BIP pillars the inorganic zincophosphite layer via coordinating to interlayer Zn(II) ions. The structural diversity from a 2-dimensional layer to a 3-dimensional frame was mainly attributable to the different bridging modes of BIP in the process of assembly. Their temperature-dependent photoluminescence properties also were studied. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Synthetic Route of C11H9N5).
3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3–C6) is higher than in water and generally decreases with a Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Synthetic Route of C11H9N5
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem