A series of hybrids with a framework constructed from {-SiW11-Ln-SiW11-}n chains and {Cu/bimpy} ribbons was written by Zhou, Wanli;Zhang, Zheyu;Peng, Jun;Wang, Xiang;Shi, Zhenyu;Li, Guangzhe. And the article was included in CrystEngComm in 2014.Synthetic Route of C11H9N5 The following contents are mentioned in the article:
This paper reports the preparation and x-ray single crystal structures of five organic-inorganic hybrid compounds with 3D framework, [Cu2.5(bimpy)2(H2O)2][Ln(H2O)3(伪-SiW11O39)]路xH2O [Ln = EuIII and x = 3.5 for (1), Ln = SmIII and x = 2.5 for (2), Ln = HoIII and x = 3.5 for (3), Ln = YIII and x = 3.5 for (4), Ln = CeIII and x = 3 for (5)] (bimpy = 3,5-bis(1-imidazolyl)pyridine). Compounds 1–5 are isostructural, showing a 3D framework featured by {-SiW11-Ln-SiW11-}n inorganic chains and {Cu/bimpy} metal-organic ribbons stemmed from Cu2+ ions and bimpy ligands. The adjacent {Cu/bimpy} ribbons are connected by two antiparallel {-SiW11-Eu-SiW11-}n chains to create a 2D layer structure, which is extended to a (3,4,4,4,6)-connected 3D framework with (4路72)(4路6路73路8)(42路53路7)(42路72路92)(42路52路67路83路10) topol. through the Cu-O covalent bonds. The magnetic and electrochem. properties of compounds 1 and 2 have been studied. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Synthetic Route of C11H9N5).
3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. 1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole. Imidazole also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes.Synthetic Route of C11H9N5
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem