Syntheses, characterizations and luminescence properties of four novel coordination polymers based on 4,4′-(phenylazanediyl)dibenzoic acid with two rigid N-donor imidazol ligand was written by Zhao, Changjiang;Zhao, Lun;Zhang, Min. And the article was included in Inorganica Chimica Acta in 2018.HPLC of Formula: 1374155-84-6 The following contents are mentioned in the article:
Four novel coordination polymers (CPs), namely, [ZnL(bimb)]路DMF (1), [ZnL(bimb)]路6(H2O)0.5 (2), [ZnL(bimp)0.5]路3H2O (3) and [ZnL(bimp)]路7H2O (4), (H2L = 4,4′-(phenylazanediyl)dibenzoic acid, bimb = 1,4-bis(imidazol-1-yl)benzene, bimp = 3,5-bis(1-imidazoly)pyridine), were synthesized under hydrothermal conditions with different solvents and decreased temperature rates. Their structures were determined by single-crystal x-ray diffraction analyses and further characterized by IR spectra (IR), elemental analyses, and thermogravimetric analyses (TGA). 1 Exhibits an infinite 4-fold interpenetrated three-dimensional (3D) framework with (66) topol. 2 Displays the 2-dimensional undulated sheets leading to form a 3-dimensional framework with 蟺-蟺 interactions among layers in ABAB fashion. 3 Exhibits an infinite 2-fold interpenetrated 3-dimensional framework with (412路63) topol. 4 Exhibited 2-dimensional layer with {42路63路8} topol. structure. Photoluminescence properties of 1–4 in solid state at ambient temperature were studied, too. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6HPLC of Formula: 1374155-84-6).
3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. The solubility of imidazoles in ethers is lower than that in alcohols and decreases with increasing chain length of the ethers . In contrast, the solubility of benzimidazoles in alcohols (C3鈥揅6) is higher than in water and generally decreases with a Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division.HPLC of Formula: 1374155-84-6
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem