A ‘two-in-one’ crystal having two different dimensionality in the extended structures: A series of cadmium(II) coordination polymers from V-shaped organic linkers was written by Ramathulasamma, Mukara;Bommakanti, Suresh;Das, Samar K.. And the article was included in Polyhedron in 2021.Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine The following contents are mentioned in the article:
Three Cd(II) containing coordination polymers, formulated as {Cd(oba)(biip)}n路nH2O (1), {Cd(sdba)(biip)}n路n5H2O (2) and {[Cd1.5(hfipbb)2(biip)1.5(H2O)][Cd(hfipbb)(biip)]}n路n2H2O (3), were synthesized by using ditopic V-shaped ligands i.e., H2oba (4,4′-oxydibenzoic acid), H2sdba (4,4′-thiodibenzoic acid), H2hfipbb {4,4′-(perfluoropropane-2,2-diyl)dibenzoic acid} and an auxiliary linker, biip [3,5-di(1H-imidazol-1-yl)pyridine] under solvothermal conditions. Compounds 1–3 are characterized by single crystal X-ray diffraction anal., IR spectroscopy, thermogravimetric (TG) and elemental analyses. Compound 1 contains a 3D framework, formed by the connectivity of {CdO4N2} secondary building unit (SBU) with the organic linkers, whereas compound 2 is a 2D coordination polymer. Interestingly, unlike to compounds 1 and 2, compound 3 possesses a distinctive structural feature having two crystallog. independent polymeric motifs (polymers, A and B) having two different dimensionality within the same crystal, i.e., coordination polymer A (CP-A) that forms a one-dimensional motif and coordination polymer B (CP-B), which has a two-dimensional structure. This study involved multiple reactions and reactants, such as 3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine).
3,5-Di(1H-imidazol-1-yl)pyridine (cas: 1374155-84-6) belongs to imidazole derivatives. Imidazole derivatives generally have good solubility in protic solvents. Simple imidazole derivatives, such as 1H-imidazole, 2-methyl-1H-imidazole, and 1,2-dimethylimidazole, have very high solubility in water. Imidazole has been usedin the lysis, wash and elution buffer for the purification of histidine tagged Sonic Hedgehog(shh-N) protein, in elution buffer in stepwise gradient for the purification of histidine tagged aldo keto reductases using nickel affinity chromatography, as a component of homogenization buffer for the purification of phagosomal compartments from dendritic cells.Application In Synthesis of 3,5-Di(1H-imidazol-1-yl)pyridine
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem