Xu, Yan-Hong published the artcileSelf-assembly of zinc polymers based on a flexible linear ligand at different pH values: Syntheses, structures and fluorescent properties, Application of 4-((1H-Imidazol-1-yl)methyl)benzoic acid, the main research area is zinc imidazolylmethylbenzonitrile imidazolylmethylbenzoate terephthalate complex polymer preparation structure fluorescence; crystal structure zinc imidazolylmethylbenzonitrile imidazolylmethylbenzoate terephthalate complex polymer.
Five novel coordination polymers, [Zn(imbz)2]n (1), {[Zn(imbz)2]·H2O}n (2), [Zn(imbz)(μ2-OH)]n (3), [Zn3(imbt)2(p-bdc)3]n (4), [Zn4(μ3-OH)2(imbt)2(p-bdc)3]n (5), (imbt = 4′-(imidazol-1-ylmethyl)benzonitrile, imbz- = 4′-(imidazol-1-ylmethyl)benzoate and p-bdc = terephthalate) were hydrothermally prepared through systematically changing the pH values of reaction mixture, and structurally characterized by elemental anal., IR spectroscopy and single-crystal x-ray crystallog. Compounds 1 and 2 exhibit similar 2-dimensional (4,4) grid structures, whereas compound 2 contains a right-handed helix along b-axis. Compound 3 has a distorted diamond framework which was constructed via imbz- ligands and μ2-OH groups linking metal atoms. Compound 4 shows a 2-dimensional 6-connected network with trinuclear zinc clusters as secondary building units (SBUs), whereas 5 shows a distorted α-Po with tetranuclear zinc clusters as SBUs, in which p-bdc ligands act as bridges. Also, compounds 1-5 all exhibit strong blue photoluminescence in the solid state at room temperature
Solid State Sciences published new progress about Crystal structure. 94084-75-0 belongs to class imidazoles-derivatives, name is 4-((1H-Imidazol-1-yl)methyl)benzoic acid, and the molecular formula is C11H10N2O2, Application of 4-((1H-Imidazol-1-yl)methyl)benzoic acid.
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem