Marshall, Checkers R.; Dvorak, Josh P.; Twight, Liam P.; Chen, Lan; Kadota, Kentaro; Andreeva, Anastasia B.; Overland, Alexandra E.; Ericson, Thomas; Cozzolino, Anthony F.; Brozek, Carl K. published the artcile< Size-Dependent Properties of Solution-Processable Conductive MOF Nanocrystals>, Computed Properties of 1003-21-0, the main research area is conductive iron triazolate MOF nanocrystal size property.
The diverse optical, magnetic, and electronic behaviors of most colloidal semiconductor nanocrystals emerge from materials with limited structural and elemental compositions Conductive metal-organic frameworks (MOFs) possess rich compositions with complex architectures but remain unexplored as nanocrystals, hindering their incorporation into scalable devices. Here, we report the controllable synthesis of conductive MOF nanoparticles based on Fe(1,2,3-triazolate)2. Sizes can be tuned to as small as 5.5 nm, ensuring indefinite colloidal stability. These solution-processable MOFs can be analyzed by solution-state spectroscopy and electrochem. and cast into conductive thin films with excellent uniformity. This unprecedented anal. of MOF materials reveals a strong size dependence in optical and electronic behaviors sensitive to the intrinsic porosity and guest-host interactions of MOFs. These results provide a radical departure from typical MOF characterization, enabling insights into phys. properties otherwise impossible with bulk analogs while offering a roadmap for the future of MOF nanoparticle synthesis and device fabrication.
Journal of the American Chemical Society published new progress about Absorptivity. 1003-21-0 belongs to class imidazoles-derivatives, and the molecular formula is C4H5BrN2, Computed Properties of 1003-21-0.
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem