《A Versatile Electrochemical Batch Reactor for Synthetic Organic and Inorganic Transformations and Analytical Electrochemistry》 was written by Stephen, Hamish R.; Schotten, Christiane; Nicholls, Thomas P.; Woodward, Madeleine; Bourne, Richard A.; Kapur, Nikil; Willans, Charlotte E.. Name: 1,3-Dimesityl-1H-imidazol-3-ium chloride And the article was included in Organic Process Research & Development in 2020. The article conveys some information:
A standardized and versatile electrochem. batch reactor that has wide applicability in both organic and inorganic synthesis and anal. electrochem. was developed. A variety of synthetic electrochem. transformations were performed to showcase the versatility and demonstrate the reactor, including the synthesis of five Cu(I)-NHC complexes, two Au(I)-NHC complexes, and one Fe(II)-NHC complex as well as an Fe(III)-salen complex. The reactor is based on a com. available vial with an adapted lid, making it inexpensive and highly flexible. It features a fixed interelectrode distance, which is crucial for reproducibility, along with the ability to accommodate a variety of interchangeable electrode materials. The reactor also was used in conjunction with a parallel plate, allowing rapid screening and optimization of an organic electrochem. transformation. Cyclic voltammetry was performed within the reactor on a range of imidazolium salt analytes using an external potentiostat. The ability to use this reactor for both anal. and synthetic organic and inorganic chem. is enabled by a flexible and characterizable design. In addition to this study using 1,3-Dimesityl-1H-imidazol-3-ium chloride, there are many other studies that have used 1,3-Dimesityl-1H-imidazol-3-ium chloride(cas: 141556-45-8Name: 1,3-Dimesityl-1H-imidazol-3-ium chloride) was used in this study.
1,3-Dimesityl-1H-imidazol-3-ium chloride(cas: 141556-45-8) is a ligand for arylation of aldehydes and for carbene catalyzed intermolecular arylation of C-H bonds. It is used as a phosphine-free ligand in various metal-catalyzed coupling reactions, often with advantageous results in difficult cases.Name: 1,3-Dimesityl-1H-imidazol-3-ium chloride
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem