Recommanded Product: 1-Ethyl-3-methyl-1H-imidazol-3-ium chloride《Influence of Ionic Coordination on the Cathode Reaction Mechanisms of Al/S Batteries》 was published in 2022. The authors were Bhowmik, Arghya;Carrasco-Busturia, David;Jankowski, Piotr;Raccichini, Rinaldo;Garcia-Araez, Nuria;Garcia-Lastra, Juan Maria, and the article was included in《Journal of Physical Chemistry C》. The author mentioned the following in the article:
The lack of knowledge on electrochem. reaction pathways for Al/S batteries prevents the development of practical approaches to mitigate the irreversibility and poor cycling performances of this appealing secondary battery system, which is, in theory, scalable, inexpensive, and energy-dense. Different from the Li/S system, Al/S batteries use ionic liquids (ILs) as electrolytes. The choice of the IL, i.e., whether the IL is based on a conventional EMImCl-based electrolyte or in a deep eutectic mixture of aluminum chloride with urea (or any of its derivatives), strongly affects the electrochem. energy-storage performance of the cell. To shed some light on the Al/S battery chem., here, we present the computational electrochem. research work to determine the most favorable reaction pathways and thermodynamically stable reaction intermediates. We also discuss the effect of the coordination of ionic species (originated from aluminum-containing deep eutectic electrolytes) with polysulfide intermediates, which lead to alterations in the reaction pathway and electrochem. behavior of the Al/S system. The spectroscopic signatures from various reaction intermediates are also reported and validated via comparison with exptl. observations. And 1-Ethyl-3-methyl-1H-imidazol-3-ium chloride (cas: 65039-09-0) was used in the research process.
1-Ethyl-3-methyl-1H-imidazol-3-ium chloride(cas: 65039-09-0) is an imidazolium chloride ionic liquid that can be used as:a starting material for the preparation of 1-ethyl-3-methylimidazolium chloride/tetrafluoroborate (EMI.Cl.BF4) molten salt for electrochemical studies; a solvent as well as catalyst for the depolymerization of oak wood lignin.Recommanded Product: 1-Ethyl-3-methyl-1H-imidazol-3-ium chloride
Reference:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem