Imidazole Biochem/physiol Actions: Imidazole derivatives have antibacterial, antifungal and anticancer functionality. It interacts with DNA and also binds to protein and stops cell division. 1739-84-0, formula is C5H8N2, Name is 1,2-Dimethyl-1H-imidazole. It also acts as a microtubule destabilizing agents and inhibits topoisomerase and Cytochrome P450 Family 26 Subfamily A Member 1 (CYP26A1) enzymes. Category: imidazoles-derivatives.
Boualavong, Jonathan;Gorski, Christopher A. research published 《 Electrochemically Mediated CO2 Capture Using Aqueous Cu(II)/Cu(I) Imidazole Complexes》, the research content is summarized as follows. A major goal of developing electrochem. CO2 capture technologies is to minimize the energy demand. One strategy for decreasing energy demands of electrochem. capture technologies is increasing the ratio of CO2 mols. captured per transferred electron. Here, we examined an electrochem. capture approach that has the potential to capture up to two CO2 mols. per electron, which is higher than many existing approaches. We used the Cu(II)/Cu(I) redox couple to control the aqueous availability of a CO2 sorbent, 1,2-dimethylimidazole (Me2Im), by transitioning between Cu(Me2Im)4(aq)2+ and Cu(Me2Im)2(aq)+. As expected from equilibrium calculations, a solution containing reduced Cu(I) had a greater CO2 capacity than the oxidized Cu(II) state. In a bench-scale test, the energy demand for CO2 capture was 27 ± 6 kJe/mol C, despite operating at 7-11% energy efficiency due to a high exptl.-set cell voltage. We estimate that under market-ready concentration conditions and the same low energy efficiency, the energy demand will be approx. 65 ± 14 kJe/mol C, although it can only remove 60% of the CO2 from coal power plant flue gas (PCO2 = 0.15 atm) at equilibrium To address this issue, we used an equilibrium model of the relevant chem. reactions to identify how altering the substituent groups on imidazole will influence the CO2 capture capacity and energy demand.
Category: imidazoles-derivatives, 1,2-Dimethylimidazole is used in the synthesis of 1,2-dimethyl-3-n-butylimidazoliumchloride and 1,2-dimethyl-3-n-propylimidazolium chloride. It also can be used in the synthesis of 1-(2-methoxyethyl)-2,3-dimethylimidazolium chloride and hexafluorophosphate salts.
1,2-Dimethylimidazole is a heterocyclic compound that contains nitrogen and carbon. It can be produced by the reaction between glyoxal and fatty acid in the presence of a base. 1,2-Dimethylimidazole has been shown to have biological properties such as an antioxidant effect. It is also used as a chemical intermediate for production of other chemicals such as 2-methylimidazole and 3-methylimidazole. 1,2-Dimethylimidazole has been shown to react with metal carbonyls to produce methylimines, which are useful intermediates in organic synthesis. The reaction mechanism involves hydrogen bonding and steric interactions between the imidazole ring and the metal carbonyl reactant., 1739-84-0.
Referemce:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem