Top Picks: new discover of 58656-04-5

After consulting a lot of data, we found that this compound(58656-04-5)Computed Properties of C18H34BF4P can be used in many types of reactions. And in most cases, this compound has more advantages.

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 58656-04-5, is researched, SMILESS is F[B-](F)(F)F.[PH+](C1CCCCC1)(C2CCCCC2)C3CCCCC3, Molecular C18H34BF4PJournal, Article, Organic Letters called The Use of Phosphine Ligands to Control the Regiochemistry of Pd-Catalyzed Hydrostannations of 1-Alkynes: Synthesis of (E)-1-Tributylstannyl-1-alkenes, Author is Darwish, Alla; Lang, Adam; Kim, Thomas; Chong, J. Michael, the main research direction is phosphine cocatalyst regioselectivity effect palladium catalysis hydrostannation terminal alkyne.Computed Properties of C18H34BF4P.

The regiochem. of Pd-catalyzed hydrostannations of terminal alkynes is dramatically influenced by ligand effects. Use of phosphines such as Cy3P, t-Bu2PCH2t-Bu, and t-Bu3P provides (E)-1-tributylstannyl-1-alkenes with regioselectivities up to >99:<1 for substrates where the commonly used Ph3P shows much lower regioselectivities. For example, a 96:4 ratio of (E)-11-(tributylstannyl)undec-10-en-1-ol (87 % yield) to 10-(tributylstannyl)undec-10-en-1-ol was obtained from HO(CH2)9C2H using 0.5 % Pd2(dba)3, 2 % Cy3PHBF4, and 4 % iPr2NEt in toluene at room temperature after 2 h. After consulting a lot of data, we found that this compound(58656-04-5)Computed Properties of C18H34BF4P can be used in many types of reactions. And in most cases, this compound has more advantages.

Reference:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem