So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Feng, Jiajing; Wu, Yanan; Yu, Qin; Liu, Yunpeng; Jiang, Wei; Wang, Dong; Wang, Zhaohui researched the compound: Tricyclohexylphosphonium tetrafluoroborate( cas:58656-04-5 ).Synthetic Route of C18H34BF4P.They published the article 《Fuller-rylenes: cross-dimensional molecular carbons》 about this compound( cas:58656-04-5 ) in CCS Chemistry. Keywords: fuller rylenes cross dimensional mol carbon. We’ll tell you more about this compound (cas:58656-04-5).
Fuller-rylenes is a useful model to tailor the properties of cross-dimensional mol. carbons to define their scope for specific applications. Herein we present a straightforward synthetic strategy to hybridize planar rylene dyes and spherical fullerene into esthetic nanostructures containing features from both subunits via one-pot Pd-catalyzed [3 + 2] or [4 + 2] cyclization reactions. Single-crystal X-ray diffraction anal. revealed conclusively the mol. configurations and distinct self-assembly crystal arrangements resulting from the different extension directions of the planar π-systems on the fullerene ball. Our strategy allowed for easy structural and electronic variations; especially, the LUMO (LUMO) and HOMO (HOMO) orbital profiles of the two fuller-rylenes, namely, Fuller-PMI and Fuller-PDI (where PMI refers to as perylene monoamide, and PDI, perylene diimide) mols., determined by combining fullerene with perylene, which featured different edge structures.
In addition to the literature in the link below, there is a lot of literature about this compound(Tricyclohexylphosphonium tetrafluoroborate)Synthetic Route of C18H34BF4P, illustrating the importance and wide applicability of this compound(58656-04-5).
Reference:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem