So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Clark, Howard C.; Shaver, Alan researched the compound: Tricyclohexylphosphonium tetrafluoroborate( cas:58656-04-5 ).SDS of cas: 58656-04-5.They published the article 《Chemistry of metal hydrides. Part XVI. Some reactions of trans-hydridochlorobis(tricyclohexylphosphine)nickel(II), trans-Ni(Cl)(H)[P(C6H11)3]2》 about this compound( cas:58656-04-5 ) in Canadian Journal of Chemistry. Keywords: phosphine tricyclohexyl nickel complex; nickel tricyclohexylphosphine complex; steric hindrance tricyclohexylphosphine nickel complex; nickelacycloheptatriene trifluoromethyl; butyne hexafluoro nickel complex reaction; acetonitrile complexation nickel; pyridine methyl complexation nickel; carbon monoxide complexation nickel. We’ll tell you more about this compound (cas:58656-04-5).
Reactions of the title compound with ligands gave complexes trans-[NiH[P(C6H11)3]2L]BF4 (L = 4-methylpyridine, MeCN). Although the bulky phosphine hinders reaction sterically, with hexafluoro-2-butyne I was obtained. Pyrolysis of I yields hexakis(trifluoromethyl)benzene). A reaction of the nickel hydride also occurs with CO in the presence of TlBF4 to give Ni(CO)3P(C6H11)3 and [P(H)(C6H11)3]BF4. This reaction can be considered to result from the reductive elimination of [P(H)(C6H11)3]Cl.
When you point to this article, it is believed that you are also very interested in this compound(58656-04-5)SDS of cas: 58656-04-5 and due to space limitations, I can only present the most important information.
Reference:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem