Quality Control of (6-Chloropyridin-2-yl)methanamine. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: (6-Chloropyridin-2-yl)methanamine, is researched, Molecular C6H7ClN2, CAS is 188637-75-4, about Synthesis and Cyclic Voltammetry Studies of Copper Complexes of Bromo- and Alkoxyphenyl-Substituted Derivatives of Tris(2-pyridylmethyl)amine: Influence of Cation-Alkoxy Interactions on Copper Redox Potentials. Author is Chuang, Chang-Lin; dos Santos, Osvaldo; Xu, Xiaodong; Canary, James W..
A combination of host-guest chem. and coordination chem. in the design of electrochem. sensors for alkali metal and ammonium ions is described. The sensor mols. are coordination complexes between a Cu ion and a functionalized tripodal ligand. Upon presentation of the ion to the sensor mol., a shift in the redox potential of the Cu ion occurs. In the study, three new alkoxyphenyl-substituted derivatives of the ligand tris(2-pyridylmethyl)amine (TPA) were prepared and characterized. The synthesis of the new ligands involved the preparation of bromopyridyl-TPA derivatives followed by Suzuki coupling with substituted phenylboronic acids. Cyclic voltammetry studies of Cu complexes of the ligands indicated that steric effects played a dominant role in the overall determination of the Cu redox couple. Studies of the alkoxyphenyl ligands indicated that small but reproducible changes in the Cu redox couple occurred upon presentation of a guest cation that would be expected to form a complex with the Cu-ligand complex.
From this literature《Synthesis and Cyclic Voltammetry Studies of Copper Complexes of Bromo- and Alkoxyphenyl-Substituted Derivatives of Tris(2-pyridylmethyl)amine: Influence of Cation-Alkoxy Interactions on Copper Redox Potentials》,we know some information about this compound(188637-75-4)Quality Control of (6-Chloropyridin-2-yl)methanamine, but this is not all information, there are many literatures related to this compound(188637-75-4).
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Imidazole | C3H4N2 – PubChem