Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 58656-04-5, is researched, SMILESS is F[B-](F)(F)F.[PH+](C1CCCCC1)(C2CCCCC2)C3CCCCC3, Molecular C18H34BF4PJournal, Article, Chemistry – A European Journal called Mobius aromatic [28]hexaphyrin phosphonium adducts, Author is Inoue, Mitsunori; Yoneda, Tomoki; Youfu, Katsuyuki; Aratani, Naoki; Osuka, Atsuhiro, the main research direction is crystal structure hexaphyrin phosphonium aromatic adduct palladium complex preparation; mol structure hexaphyrin phosphonium aromatic adduct palladium complex; hexaphyrin phosphonium Mobius aromatic adduct palladium complex preparation DFT.Computed Properties of C18H34BF4P.
The reaction of [26]hexaphyrin(1.1.1.1.1.1) with tricyclohexylphosphine was examined to investigate the effect of the electron-rich character of the phosphine on the photophys. and aromatic properties of the adduct. [28]Hexaphyrin phosphonium adducts formed from the reaction of [26]hexaphyrin with triphenylphosphine and tricyclohexylphosphine, resp., were confirmed to be Mobius aromatic mols. [26]Hexaphyrin PdII complex was found to undergo a regioselective nucleophilic addition reaction with triphenylphosphine and tricyclohexylphosphine to provide Mobius aromatic [28]hexaphyrin phosphonium adducts with a Huckel-to-Mobius topol. change as well as PdII migration. All adducts were characterized by elemental anal., UV-visible spectroscopy, 1H, 19F, and 31P NMR spectroscopy, mass spectrometry, and single crystal diffraction anal. Harmonic Oscillator Model of Aromaticity (HOMA) value was calculated using CC and CN bond lengths of the geometry-optimized structure based on X-ray crystallog. data.
There is still a lot of research devoted to this compound(SMILES：F[B-](F)(F)F.[PH+](C1CCCCC1)(C2CCCCC2)C3CCCCC3)Computed Properties of C18H34BF4P, and with the development of science, more effects of this compound(58656-04-5) can be discovered.
Reference:
Imidazole – Wikipedia,
Imidazole | C3H4N2 – PubChem